粘弹性材料摩擦特性试验研究与应用前景

对ＰＴＦＥ基导轨材料的防爬机理和粘弹性材料的防爬性能作了理论探讨和试验研究，指出了提高运动平稳性的导轨材料的发展方向。     

Rheological and thermal properties of agarose aqueous solutions and hydrogels

In this article, we report on the rheological properties of agarose aqueous solutions and gels. Viscosity curves were determined for homogeneous agarose aqueous solutions at different temperatures (from 68 to 38 °C) to study the viscosity behavior as the systems undergo gelation. The gelation phenomenon of agarose solutions was also investigated by shear oscillation experiments and differential scanning calorimetry. The gelation and melting temperature as a function of agarose concentration were determined together with the gelation and melting enthalpies. The results obtained were interpreted using the two‐step model describing the gelation of agarose in water. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 322–328, 2008     

Vibration and dissipative heating of a layered rectangular viscoelastic prism under harmonic shear loading

The vibration and vibrational heating of a rectangular prism with copper and polyethylene layers is studied by solving numerically a coupled problem of thermoelasticity. The cases of kinematic and mechanical harmonic shear loads on a section of the prism surface are examined. Local heating regions are revealed. They are due to the stress fields in the neighborhood of the points at which the type of boundary conditions changes. The temperature–time curves have preresonance, resonant, and postresonance sections. The heating process reaches a steady thermal state under kinematic loading and may become avalanche-like (which is typical of thermal instability) under mechanical loading Translated from Prikladnaya Mekhanika, Vol. 45, No. 2, pp. 70–78, February 2009.     

Viscoelastic properties of nanosilica‐filled epoxy composites investigated by dynamic nanoindentation

The viscoelastic properties of the epoxy filled with silica nanoparicles have been investigated by dynamic nanoindentation and characterized by the storage modulus and loss tangent. The materials studied are neat epoxy and silica/epoxy composites with silica volume fraction of 1, 3, 6, 10, and 14 vol %, respectively. The silica nanoparticles with an average diameter of 25 nm are found to disperse homogeneously in the epoxy matrix. The effect of the particle content, force frequency, and penetration load on the viscoelastic behavior is studied and discussed. The comparison with traditional testing methods such as tension, bending, and DMTA is made. Besides, theoretical results by using micromechanics models are also obtained and compared with the experimental results. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 1030–1038, 2009     

AFM nanoindentation of viscoelastic materials with large end‐radius probes

We used atomic force microscopy (AFM) nanoindentation to measure mechanical properties of polymers. Although AFM is generally acknowledged as a high‐resolution imaging tool, accurate quantification of AFM nanoindentation results is challenging. Two main challenges are determination of the projected area for objects as small as AFM tips and use of appropriate analysis methods for viscoelastic materials. We report significant accuracy improvements for modulus measurements when large end‐radius tips with appropriate cantilever stiffnesses are used for indentation. Using this approach, the instantaneous elastic modulus of four polymers we studied was measured within 30 to 40% of Dynamic Mechanical Analysis (DMA) results. The probes can, despite their size and very high stiffnesses, be used for imaging of very small domains in heterogeneous materials. For viscoelastic materials, we developed an AFM creep test to determine the instantaneous elastic modulus. The AFM method allows application of a nearly perfect stepload that facilitates data analysis based on hereditary integrals. Results for three polymers suggest that the observed creep in the materials has a strong plastic flow component even at small loads. In this respect, the spherical indenter tips behave like “sharp” indenters used in indentation studies with instrumented indenters. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 1573–1587, 2009     

Synthesis and thiol–ene photopolymerization of allyl‐ether functionalized dendrimers

Well‐defined, allyl‐ether functional, first‐generation dendrimers have been synthesized. The convergent growth approach was utilized, using the anhydride of the allyl‐ether terminated building block. Three different core moieties were used: trimethylolpropane, trisphenol, and ditrimethylolpropane. The coupling reactions proceeded in good yields and all compounds were characterized by NMR, MALDI‐TOF, and SEC. The allyl‐terminated dendrimers were crosslinked by thiol–ene chemistry, using a multifunctional thiol, TriThiol, to give clear and smooth films. The photopolymerization was conducted in the presence of a photoinitiator, Irgacure 651, and no traces of either allyl‐ether groups or thiols were observed by FT‐Raman after cure. All crosslinked films were characterized with respect to mechanical (DMA) and thermal (DSC) properties. It was found that homogeneous networks were formed and that the core functionality and structure had little effect on the network properties. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1339–1348, 2008     

Metachronal propulsion of non-Newtonian viscoelastic mucus in an axisymmetric tube with ciliated walls

Cilia-induced flow of viscoelastic mucus through an idealized two-dimensional model of the human trachea is presented.The cilia motion is simulated by a metachronal wave pattern which enables the mobilization of highly viscous mucus even at nonzero Reynolds numbers.The viscoelastic mucus is analyzed with the upper convected Maxwell viscoelastic formulation which features a relaxation time and accurately captures normal stress generation in shear flows.The governing equations are transformed from fixed to wave(laboratory)frame with appropriate variables and resulting differential equations are perturbed about wave number.The trachea is treated as an axisymmetric ciliated tube.Radial and axial distributions in axial velocity are calculated via the regular perturbation method and pressure rise is computed with numerical integration using symbolic software MATHEMATICA^‘TM’.The influence of selected parameters which is cilia length,and Maxwell viscoelastic material parameter i.e.relaxation time for prescribed values of wave number are visualized graphically.Pressure rise is observed to increase considerably with elevation in both cilia length and relaxation time whereas the axial velocity is markedly decelerated.The simulations provide some insight into viscous-dominated cilia propulsion of rheological mucus and also serve as a benchmark for more advanced modeling.     

带有嵌件充模过程中熔接线形成的数值实验研究

采用基于同位网格的有限体积方法耦合Level Set方法,求解了黏弹性流体具有相变的气-液两相充填模型;模拟出了黏弹性流体在带有嵌件的型腔充模过程中熔接线区域以及壁面凝固层的形成过程;得到了充填过程中熔接线区域的界面运动情况,得到了充模结束时型腔内压力、应力等物理量的分布,得到了与实验结果一致的应力集中以及应力双折射现象;并讨论了注射速度、熔体温度对熔接线区域厚度的影响。研究发现:注射速度越高,熔接线区域越薄;熔体温度越高,熔接线区域越薄,所以提高注射速度、熔体温度可以使熔接线区域变薄或消失。     

Le jet libre immergé d'un fluide viscoélastique

Résumé Les auteurs étudient le jet libre laminaire bidimensionnel d'un fluide viscoélastique obéissant à une loi de comportement semiempirique. Ils appliquent la méthode de raccordement des développements asymptotiques afin de déterminer le profil de vitesses à l'intérieur du jet, et l'entraînement du fluide extérieur. Les résultats obtenus illustrent l'influence de l'élasticité sur le champ de vitesse et la présence d'un gradient de pression à l'intérieur du jet. Les lignes de courant obtenues montrent que le fluide externe est aspiré vers l'axe du jet.

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Summary A two-dimensional laminar free jet of a viscoelastic fluid following a semiempiric constitutive equation is studied. The method of matching asymptotic expansions is applied to determine the velocity profiles inside the jet and the entrainment of the external fluid. The results thus obtained highlight the influence of elasticity on the velocity field and the presence of a pressure gradient inside the jet. The streamlines obtained show that the external fluid is sucked in towards the axis of the jet.

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Zusammenfassung Es wird der laminare zweidimensionale Freistrahl einer viskoelastischen Flüssigkeit, die einem halbempirischen Stoffgesetz folgt, untersucht. Asymptotische Entwicklungen werden aneinandergefügt, um die Geschwindigkeitsverteilung in der Strahlströmung und die Ansaugkraft der äußeren Flüssigkeit zu bestimmen. Die erzielten Ergebnisse zeigen den Einfluß der Elastizität auf die Geschwindigkeitsverteilung und das Bestehen eines Druckgradienten innerhalb der Strahlströmung. Die abgeleiteten Stromlinien zeigen weiter, daß die äußere Flüssigkeit zur Strahlachse hin angesaugt wird.

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A ₁;A ₂;A ₃ tenseurs de Rivlin-Ericksen - A constante définie par [27] - D domaine d'écoulement - f ₁();f ₀() fonctions définies par la transformation [20] - I tenseur unité - J nombre adimensionnel [12] - L longueur de référence - M flux total d'impulsion [19]m: µ/ - N _Re nombre de Reynolds - N _w nombre de Weissenberg - n indice de comportement - p pression - s indice de comportement «élastique» - T tenseur des contraintes - U ₀ vitesse de référence - u, v composantes du vecteur vitesse - x, y coordonnées cartésiennes - Y coordonnée de «couche limite» [9] - Z variable complexe - angle entre les parois de la fente - paramètre de perturbation - variable affine [20] - () fonction définie par [2c] - coefficient d'élasticité - fonction de viscosité [2a] - µ indice de consistance - masse volumique - ; fonctions de courant - fonction définie par [2b] - 2ème invariant principal du tenseurA ₁ Avec 7 figures     

Dissipative Heating of a Viscoelastic Cylinder under a Load Steadily Moving over Its Surface

The Fourier method is used to find the analytical solutions to two-dimensional quasistatic problems of stationary polyharmonic vibrations and dissipative heating of a linearly viscoelastic cylinder. The influence of the cylinder thickness and the width of the loading area on the thermomechanical state of the cylinder is studied based on numerical data__________Translated from Prikladnaya Mekhanika, Vol. 41, No. 2, pp. 23–32, February 2005.