浙西北晚侏罗世火山期后交代蚀变作用及铀的活化转移

浙西北晚侏罗世火山岩历经四次火山喷发旋回,经受了多次热事件。岩石遭受的火山期后热液交代蚀变,在酸性岩区主要发育钠长石化和绢云母化。这种面型分布的交代蚀变使火山岩中以多种形式赋存的铀发生成岩后的初始活化。尔后,成矿期热液在运移中又将已经活化了的铀从围岩中浸取出来,以补充热液中的铀,并在沿断裂发育的蚀变环境中沉淀成矿。     

贵东岩体花岗岩中晶质铀矿的特征及其找矿意义

本文系统地研究了贵东岩体产铀矿与非产铀矿花岗岩中晶质铀矿的标型特征。据研究结果,贫钍晶质铀矿的含量高是产铀矿花岗岩的基本特征,其晶质铀矿的强烈溶蚀现象是铀活化转移的直接证据,可以将其作为寻找铀矿的标志之一。     

N—正辛基己内酰胺从硝酸介质中萃取铀（Ⅵ）的动力学研究

采用上升单液滴法研究了Ｎ－正辛基己内酰胺从硝酸介质中萃取铀（Ⅵ）的动力学，得出Ｕ（Ⅵ）的萃取速率与水相中铀浓度的１次方成正比，与温度（１０－４５℃）无关；萃合物向有机相的扩散为萃取过程的速控步骤。     

磷酸基多孔芳香骨架材料用于提取铀离子

采用联苯为建筑基元，合成了价格低廉、操作简便、易于工业化的多孔芳香骨架材料PAF-45.通过后修饰方法，制备了带有磷酸基团的多孔芳香材料（PAF-45-PG）.通过FTIR（傅里叶变换红外光谱），TGA（热重分析），PXRD（多晶粉末X射线衍射），SEM（扫描电子显微镜），TEM（透射电子显微镜）以及N₂吸附实验，对PAF-45-PG的结构及孔道性质进行了系统的表征.由于骨架中引入了磷酸基团，PAF-45-PG具有优良的铀离子吸附性能，在pH=6的条件下可以达到100 mg·g^-1.另外，该材料成本低廉，具有可观的工业化前景，为多孔材料在能源方面的应用提供了广阔前景.     

A kinetic study of the oxidation of uranium dioxide

Summary A kinetic model for the oxidation of a UO₂ pellet is suggested by considering the mass transfer and the diffusion of oxygen molecules. The kinetic parameters were estimated by a fitting of the experimental data. The activation energies for the chemical reaction and the product layer diffusion were calculated from the kinetic model. The suggested model explains well the oxidation behavior of UO₂.     

Performance for PAN-3 chelate fiber for adsorbing and separating trace uranium—determination by ICP-OES

An ICP-OES method is established for polyacrylamidoxime-carboxylic acid chelate fiber (PAN-3) adsorbing and separating trace uranium in waste water. The conditions for quantitative enrichment and desorption uranyl ions are investigated. The stability and the reuse performance of the chelate fiber are discussed. The interference of co-existent ions on uranyl ions as well as the analyses of samples are performed with satisfactory results. The lowest concentration of uranium determined by ICP-OES is 5 g/l, its RSD is 2.6%.     

An improved laser fluorimeter for the detection of traces of uranium

An improved laser fluorimeter and its application for the determination of ultratrace concentrations of uranium are described. The system developed uses a collecting lens-filter system, by which the density of laser radiation on the sample is increased greatly and the interfering stray light can be reduced to a great degree. In addition, both laser and lamp sources are joined together in the instrument. A strong green phosphor from uranium-doped sodium metaphosphate (NaPO₃: U) has been found suitable and has been used for the determination of ultratraces of uranium. A detection limit (3) of 0.36 pg of uranium (in 30 mg NaH₂PO₄ per pellet) was obtained. In the case of peak-to-background intensity ratios relative standard deviations (RSD) are 6.4% and the linear dynamic range extends from 1 pg to 10³ ng of uranium.     

Detection of Gas Bubble by SIMS in Irradiated Nuclear Fuel

The formation of gas bubbles is a key issue for nuclear fuel behaviour. The first measurements of xenon during a depth profile in irradiated nuclear fuel evidenced some peaks over a non-zero baseline. In comparison with EPMA mappings of xenon and SEM image of the sputtered surface, it is proven that the peaks correspond to bubbles while the baseline corresponds to xenon included in the UO₂ matrix.