双水杨醛缩1,6-己二胺Schiff碱铜配合物改性UHMWPE新型耐磨材料的研究

分别对含不同质量分数(2.5wt％、5wt％、10wt％、15wt％)的双水杨醛缩二胺型Schiff碱Cu(Ⅱ)配合物的改性UHMWPE与45#钢配副进行了干摩擦条件下的销-盘摩擦磨损试验,并采用SEM观察试样磨损表面形貌,采用EDS分析销试样未磨损及磨损表面的主要元素组成,探讨其磨损机理.结果表明:在15wt％质量分数范围内,随着双水杨醛缩1,6-己二胺Schiff碱铜配合物添加量的增加,改性UHMWPE与钢配副的摩擦系数逐步降低,耐磨性逐步提高,其中磨损最轻的是含10wt％双水杨醛缩1,6-己二胺Schiff碱Cu(Ⅱ)配合物的改性UHMWPE;磨损机制均为磨粒磨损,并发现Schiff碱Cu(Ⅱ)配合物添加剂中的Cu元素发生了选择性转移效应.     

Porosity and permeability evolution and evaluation in anisotropic porosity multiscale-multiphase-multicomponent structure

Based on the hybrid hypersingular integral equation-lattice Boltzmann methods (HHIE-LBM), the porosity and permeability evolution and evaluation process in anisotropic saturated porosity multiscale-multiphase-multicomponent (ASP-MS-MP-MC) structures under ultra high temperature and pressure conditions was analyzed on parallel CPU and GPU platforms. First, virtual physical models at multi-spatial scales (2 μm, 5 μm and 10 μm) were restructured by computerized microtomography technology and data. Second, using HHIE-LBM methods, the anisotropic porosity and permeability tensor at core level and pore level under ultra high temperature and pressure conditions were calculated. Third, the evolution and evaluation process of the porosity and permeability as a function of multi temporal spatial scales was investigated. Finally, the relationship between porosity and permeability and ASP-MS-MP-MC structures (micro-meso-macro-scale) was explored.     

热处理参数对超高强铝合金硬度的影响

采用热处理、硬度测试、显微组织观察等方法,分析不同的时效温度、固溶时间、时效时间对超高强铝合金硬度的影响,并利用正交方差分析对最佳的热处理工艺参数进行优选.结果表明：在固溶温度为460℃,固溶时间为400、60、200 min,时效温度为130、150、170℃,时效时间为10、15、20 h的条件下,各参数对硬度影响...     

Ultra Rapid Approaches to Mild Macromolecular Conjugation

In light of the increasing demand for ultra rapid and mild conjugation chemistries for use in macromolecular chemistry, the present Feature Article provides a critical overview of the very latest developments in this field. The principal aim, therefore, is the provision of a quick selection guide to aid in the formulation of a design strategy for novel functional materials and to provide recommendations for future developments in the chemistries discussed.

     

光纤耦合器的理论、设计及进展

系统总结了光纤耦合器的发展历程,归纳提炼出各个阶段的标志性事件;详细阐述了光纤耦合器的耦合类型、制作方法、性能参数;详细评述了光纤耦合器的理论分析方法;全面分析了X型、星型、光栅型、混合型等各种典型光纤耦合器的基本结构、工作原理及耦合特性;指出并展望了光纤耦合器的发展方向和应用前景。作者率先提出并设计了超长周期光纤光栅耦合器,实验上实现了两个超长周期光纤光栅之间的有效耦合。     

二次序列闪光高速照相系统研究

首次提出二次序列闪光高速照相系统结构。利用二次序列闪光激光光源在CCD相机曝光时间内两次发出超短激光脉冲,实现在一幅图像中捕获两个不同位置处高速运动目标图像。此系统可实现在一个照相站内两次成像,相当于实现两个照相站的功能,在现代弹道测量中有广泛的应用前景。     

表面质量检测系统中超高速图像数据采集与处理平台的设计与实现

以钢板表面检测图像数据采集与处理的应用为背景,设计了3GSPS（Giga Samples Per Second）超高速数据采集与处理平台。采用时钟双边沿采样的方式提高采样率,使得系统最高采样率达到3GSPS,采用FPGA芯片解决了ADC采样后高速数据的采集与存储的难题。该平台的通用性以及灵活性较强,可在钢板表面检测图像系统中得到广泛的应用。     

Detection of 13 mycotoxins in feed using modified QuEChERS with dispersive magnetic materials and UHPLC–MS/MS

An analytical method for the simultaneous determination of 13 mycotoxins in feed by magnetic dispersive solid‐phase extraction combined with ultra‐high performance liquid chromatography and tandem mass spectrometry was developed. The samples were extracted with acetonitrile/water (80:20, v/v, containing 3% acetic acid), and separated by centrifugation after salting‐out, and then treated with magnetic adsorbents to remove interferences. The separation of target mycotoxins was performed on an ACQUITY UPLC HSS T3 column using a mobile phase consisting of 1 mmol/L ammonium acetate with 0.1% formic acid and methanol by gradient elution. Good linearities for the 13 mycotoxins were achieved with correlation coefficients over 0.99, and the recoveries of mycotoxins were in the range of 89.3–112.6% at spiking at levels of 5, 20, and 100 μg/kg, with relative standard deviations of 0.9–10.4%. Based on the functional magnetic materials (MDN@Fe₃O₄, PSA@Fe₃O₄, ZrO_2@Fe₃O₄) applied in dispersive solid‐phase extraction, the pretreatment process is more convenient and it is beneficial to reduce the experimental cost by reusing the recycled magnetic materials. It is a simple, rapid, and environmentally friendly analytical method for the determination of mycotoxins in feed.     

Evaluation of the influence of salt processing on pharmacokinetics of psoralen and isopsoralen in Psoralea corylifolia L.

A sensitive, specific and rapid ultra‐high‐pressure liquid chromatography tandem mass spectrometry (UHPLC‐MS/MS) method has been developed to investigate pharmacokinetic properties of psoralen and isopsoralen, two compounds isolated from raw/salt‐processed fruit of Psoralea corylifolia L. UHPLC‐MS/MS was used with positive ion electrospray. The mobile phase was composed of acetonitrile and 0.1% formic acid aqueous solution and a gradient elution program at flow rate of 0.3 mL/min was applied. Multiple reaction monitoring mode was used for the quantification of psoralen, isopsoralen ([M + H]⁺ m/z 187.0 → m/z 131.0) and scoparone (m/z 207.0 → m/z 151.1). Scoparone served as an internal standard. The method was fully validated for its sensitivity, selectivity, stability, matrix effect and extraction recovery. The obtained results showed that salt‐processed Buguzhi significantly promoted the absorption of psoralen and isopsoralen, and increased the bioavailability of these compounds. Copyright © 2015 John Wiley & Sons, Ltd.     

关于氦氖激光器声光调制锁模的实验研究

本实验中,将声光调制锁模器放置在氦氖激光器中的谐振腔里,控制谐振腔中的增益,使声波的频率调制与激光器固有频率间隔一致,从而达既可以到锁模的效果,又可以增加增益,减少能量损耗。通过功率计与示波器检测出激光脉宽、脉冲周、纵模间隔等物理量,与理论值进行比较,判断激光锁模实验的效果。本实验使用的氦氖激光器腔长大于1.55m,是双面全反射腔,可以利用激光锁模技术得到纵模进行比较,从而获得单色性好的超短脉冲激光。