Trace Detection of Mercury(II) Using Gold Ultra‐Microelectrode Arrays

The electroanalytical detection of trace mercury(II) at gold ultra‐microelectrode arrays is reported. The arrays consist of 256 gold microelectrodes of 5 μm in diameter in cubic arrangements which are separated from their nearest neighbor by 100 μm. The array was utilized in nitric acid using linear sweep voltammetry where a linear response from mercury additions over the range 10 μg L^?1?200 μg L^?1 (10^?8?10^?6 M) was observed with a sensitivity and detection limit of 0.11 nC/μg L^?1 and 3.2 μg L^?1 (16 nM) respectively from using a deposition time of 30 s at ?0.2 V (vs. SCE). This methodology was explored in 0.1 and 1 M chloride media over the mercury range 10 μg L^?1?200 μg L^?1 (5×10^?8?10^?6 M) where similar sensitivities of 0.087 nC/μg L^?1 and 0.078 nC/μg L^?1 were observed with an identical detection limit. The protocol is demonstrated to be useful for the determination of mercury for analysis of environmental water samples.     

无机阴离子的毛细管电泳分析

本文研究了常见无机阴离子的毛细管电泳规律，考察了分离电压、电解质熔液组成、浓度、ｐＨ值等对分离的影响，建立了高效、快速的无机阴离子毛细管电泳分析方法。在选定的实验条件下，各种常见无机阴离子在５ｍｉｎ内达到完全分离，对Ｂｒ＾－和Ｃｌ＾－的分离柱效每米可达７６万理论板数。迁移时间的相对标准偏差小于１％，峰面积的相对标准偏差小于５％，各离子的最低检测浓度为０．０５￣０．５μｇ／ｍｌ。     

分散固相萃取净化-超高效液相色谱-串联质谱法同时测定鱼和虾中抗生素及三苯甲烷类兽药残留

建立了分散固相萃取净化-超高效液相色谱-串联质谱法快速测定鱼和虾中3类（磺胺类、喹诺酮类、氯霉素类）18种抗生素及2种三苯甲烷类（孔雀石绿、隐色孔雀石绿）兽药残留。样品经磷酸氢二钾溶液水解分散，乙腈提取，提取液经氯化钠脱水、盐析后取乙腈层，经旋转蒸发仪浓缩至近干，残留物用甲醇定容至1.0 mL，C18和PSA（N-丙基乙二胺）填料分散固相萃取净化，过滤膜后经ZORBAX C18色谱柱（50 mm×2.1 mm，1.8 μm）分离，正、负离子多反应监测模式采集数据，同位素内标法定量。实验结果表明，20种兽药在0.2~300 μg/L范围内具有良好的线性关系，检出限为0.1~0.6 μg/kg，定量限为0.3~1.8 μg/kg，相关系数均大于0.99。在1、5和20倍定量限加标浓度水平下，平均回收率为72.5%~118%，相对标准偏差（RSD）为1.9%~9.8%。该方法具有前处理简单、检测效率高、成本低等优点，适用于鱼和虾中多类兽药残留的同时测定。     

Application of HPLC to measure vanadium in environmental,biological and clinical matrices

Vanadate and vanadium compounds exist in many environmental, biological and clinical matrices, and despite the need only limited progress has been made on the analysis of vanadium compounds. The vanadium coordination chemistry of different oxidation states is known, and the result of the characterization and speciation analysis depends on the subsequent chemistry and the methods of analysis. Many studies have used a range of methods for the characterization and determination of metal ions in a variety of materials. One successful technique is high performance liquid chromatography (HPLC) that has been used mainly for measuring total vanadium level and metal speciation. Some cases have been reported where complexes of different oxidation states of vanadium have been separated by HPLC. Specifically reversed phase (RP) HPLC has frequently been used for the measurement of vanadium. Other HPLC methods such as normal phase, anion-exchange, cation-exchange, size exclusion and other RP-HPLC modes such as, ion-pair and micellar have been used to separate selected vanadium compounds. We will present a review that summarizes and critically analyzes the reported methods for analysis of vanadium salts and vanadium compounds in different sample matrices. We will compare various HPLC methods and modes including sample preparation, chelating reagents, mobile phase and detection methods. The comparison will allow us to identify the best analytical HPLC method and mode for measuring vanadium levels and what information such methods provide with regard to speciation and quantitation of the vanadium compounds.     

实现小型超宽带天线的新方法

提出一种实现小型超宽带天线的新方法，通过分析一个柱面类螺旋天线初步证实了该方法的正确性。     

一种便携式GIS局放检测装置的设计

为解决现有的GIS绝缘检测装置存在的体积大、不易实现在线检测、受周围环境影响,测量精度不高等问题,笔者采用时差计算法,对局部放电源进行定位,并通过由高通滤波器、宽带放大器、检波器、电/光变换器和光/电变换器组成的两个通道,分别接收和处理两个来自不同位置检测到的局放信号,从而使检测精度大大提高。实验结果表明,该系统具有重量轻、携带方便、灵敏度高,可实现局放源定位等特点。     

一类超抛物型极限方程的非线性反应扩散问题

讨论了一类具有超抛物型极限方程的非线性奇摄动反应扩散问题.利用比较定理,研究了问题解的存在唯一性及其渐近性态.     

基于梯度的帧内自适应深度决策算法

提出了一种基于梯度的帧内候选模式裁剪算法,通过自适应深度划分并利用空间信息来简化帧内预测过程,大大减少了计算复杂度.实验结果显示,所提出的算法对比HM16.7,可以减少35.25%的计算复杂度,且只有极小的编码效率损失.     

一种超宽带反射型极化转换超表面设计

提出了一种超宽带、反射型极化转换超表面,该极化转换超表面由"H"形周期金属贴片结构,介质板和金属底板组成。通过改变单元结构尺寸,可以使反射波2种交叉线极化分量的幅度相同,相位差接近±π/2。仿真与实测结果表明,该极化变换超表面在6.40~15.40GHz,17.49~18.14GHz频带内能将线极化入射波转换为轴比小于3dB的圆极化反射波;在15.81~17.26GHz频带内能将线极化入射波转换为极化转化率大于80%的交叉线极化反射波。该结构具有单元尺寸小,工作频带宽,能量损耗低的特点,可以在有限的平面内加载更多的单元结构。该极化变换超表面在电磁波调控、新型天线设计等方面具有一定的应用价值。     

超亲水薄膜表面接触角的高精度测量

 作为极端润湿表面的一种,超亲水薄膜表面由于具有自清洁、防雾、防腐蚀等特性,成为现代工业、城市建设等领域的研究重点之一。界定极端润湿表面的一种方法为接触角的测量,因此获得更高精度的接触角对极端润湿表面工程具有重要意义。讨论了在超亲水薄膜表面提高接触角精度的3种算法,包括量高法、圆拟合法及椭圆拟合法,结果显示接触角在接近0°时通过圆拟合算法能够提高计算精度。