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171.
172.
Chimera Spectrum Diagnostics for Peptides Using Two-Dimensional Partial Covariance Mass Spectrometry
Taran Driver Nikhil Bachhawat Leszek J. Frasinski Jonathan P. Marangos Vitali Averbukh Marina Edelson-Averbukh 《Molecules (Basel, Switzerland)》2021,26(12)
The rate of successful identification of peptide sequences by tandem mass spectrometry (MS/MS) is adversely affected by the common occurrence of co-isolation and co-fragmentation of two or more isobaric or isomeric parent ions. This results in so-called `chimera spectra’, which feature peaks of the fragment ions from more than a single precursor ion. The totality of the fragment ion peaks in chimera spectra cannot be assigned to a single peptide sequence, which contradicts a fundamental assumption of the standard automated MS/MS spectra analysis tools, such as protein database search engines. This calls for a diagnostic method able to identify chimera spectra to single out the cases where this assumption is not valid. Here, we demonstrate that, within the recently developed two-dimensional partial covariance mass spectrometry (2D-PC-MS), it is possible to reliably identify chimera spectra directly from the two-dimensional fragment ion spectrum, irrespective of whether the co-isolated peptide ions are isobaric up to a finite mass accuracy or isomeric. We introduce ‘3-57 chimera tag’ technique for chimera spectrum diagnostics based on 2D-PC-MS and perform numerical simulations to examine its efficiency. We experimentally demonstrate the detection of a mixture of two isomeric parent ions, even under conditions when one isomeric peptide is at one five-hundredth of the molar concentration of the second isomer. 相似文献
173.
In two-dimensional electrides, anionic electrons are spatially confined in interlayer regions with high density, comparable to metals, and they are highly mobile, just as free electrons, resembling hyperbolic metamaterials with metal-dielectric multilayered structures. In this work, two-dimensional electride materials MgONa and CaONa are proposed as good natural hyperbolic materials. By using the first-principles calculations based on density functional theory (DFT), the electronic structures, stabilities, and optical properties of two-dimensional electride materials XONa (X=Mg, Ca) are investigated. Our results show that they are stable in 1-monolayer (1-ML) structures as well as in bulk states. They exhibit hyperbolic dispersions from visible to near infrared spectral range with high qualities up to about 700, which is two orders-of-magnitude larger than the preceding bulk hyperbolic materials. Numerical results reveal that they exhibit negative refraction with low losses. Their high-quality hyperbolic responses over a wide spectral range pave the way of broad photonic applications as natural hyperbolic materials. 相似文献
174.
Tomasz Ligor Joanna Zawadzka Grzegorz Strczyski Rosa M. Gonzlez Paredes Anna Wenda-Piesik Ileana Andreea Ratiu Marek Muszytowski 《Molecules (Basel, Switzerland)》2021,26(7)
Volatile organic compounds (VOCs) exiting in urine are potential biomarkers of chronic kidney diseases. Headspace solid phase microextraction (HS-SPME) was applied for extraction VOCs over the urine samples. Volatile metabolites were separated and identified by means of two-dimensional gas chromatography and time of flight mass spectrometry (GC × GC TOF MS). Patients with glomerular diseases (n = 27) and healthy controls (n = 20) were recruited in the study. Different VOCs profiles were obtained from patients and control. Developed methodology offers the opportunity to examine the metabolic profile associated with glomerulopathy. Four compounds found in elevated amounts in the patients group, i.e., methyl hexadecanoate; 9-hexadecen-1-ol; 6,10-dimethyl-5,9-undecadien-2-one and 2-pentanone were proposed as markers of glomerular diseases. 相似文献
175.
水资源匮乏是现代化发展中面临的全球性问题,太阳能界面水汽转换(Interfacial Solar Steam Generation, ISSG)是一种高效、绿色、低成本进行海水淡化和废水处理的方法。ISSG使用绿色的太阳能作为热源,通过光热转换并将热限制在水气界面上以高效产生蒸气,然后经过冷凝收集获得清洁水。设计和构筑具有强光吸收的光热转换材料是ISSG的技术核心。Ti3C2-MXene是一种新型二维碳化钛材料,具有比表面积大、水分散性好和光热转换效率高等优点,在ISSG领域具有巨大的应用潜力。本文介绍了ISSG技术和MXene,总结了光热转换材料的设计原则,论述了Ti3C2-MXene复合材料在ISSG领域的研究进展,其中包括二维MXene薄膜、三维MXene气凝胶和水凝胶、生物基-MXene复合材料的构筑和性能等,并分析了Ti3C2-MXene所面临的挑战和发展前景。 相似文献
176.
基于V-BLAST的多载波直接序列扩频CDMA系统上行链路性能分析 总被引:1,自引:0,他引:1
提出了一种应用多输入多输出(MIMO)的垂直分层空时(V-BLAST)检测算法的多载波直接序列扩频CDMA(MC-DS-CDMA)的系统结构,对系统上行链路的误码率性能进行了理论分析,推导出了接收天线数大于发射天线数条件下系统误码率的理论表达式,并通过计算机仿真进行了验证,数值结果表明,收发天线数对系统性能具有较大的影响,相对于传统MC-DS-CDMA系统,减少发射天线数或增加接收天线数均可使基于V—BLAST算法的MC-DS-CDMA系统的性能和容量有不同程度的改善. 相似文献
177.
In light of the generator polynomials of constacyclic codes over finite chain rings, the depth spectrum of constacyclic codes can be determined if (n,p)=1. 相似文献
178.
A q‐ary code of length n, size M, and minimum distance d is called an code. An code with is said to be maximum distance separable (MDS). Here one‐error‐correcting () MDS codes are classified for small alphabets. In particular, it is shown that there are unique (5, 53, 3)5 and (5, 73, 3)7 codes and equivalence classes of (5, 83, 3)8 codes. The codes are equivalent to certain pairs of mutually orthogonal Latin cubes of order q, called Graeco‐Latin cubes. 相似文献
179.
180.
Nanxi Wang Dr. Yue Li Dr. Wei Niu Dr. Ming Sun Dr. Ronald Cerny Prof. Qingsheng Li Prof. Jiantao Guo 《Angewandte Chemie (International ed. in English)》2014,53(19):4867-4871
A safe and effective vaccine against human immunodeficiency virus type 1 (HIV‐1) is urgently needed to combat the worldwide AIDS pandemic, but still remains elusive. The fact that uncontrolled replication of an attenuated vaccine can lead to regaining of its virulence creates safety concerns precluding many vaccines from clinical application. We introduce a novel approach to control HIV‐1 replication, which entails the manipulation of essential HIV‐1 protein biosynthesis through unnatural amino acid (UAA*)‐mediated suppression of genome‐encoded blank codon. We successfully demonstrate that HIV‐1 replication can be precisely turned on and off in vitro. 相似文献