Barium Sodium Niobate Powders and Thin Films: Preparation and Ferroelectric Behavior

Powders and thin films of barium sodium niobate, Ba₄Na₂Nb₁₀O₃₀, of filled tungsten bronze type ferroelectric were processed by a sol-gel route using barium metal, niobium ethoxide and sodium methoxide as precursors. Polycrystalline powder resulted after heat treating the gel powder at or above 650°C. Thin films of Ba₄Na₂Nb₁₀O₃₀ showed no preferred orientation on Si(100), Pt/Si(100) and sapphire substrates. Hysteresis measurements at 1 kHz for the thin films annealed at 750°C, obtained using a prehydrolyzed precursor solution, and gave remanent polarization of 17.34 µC/cm² and coercive field of 62.5 kV/cm. Microstructural investigation of surface morphology of these films revealed grains about 0.3 µm in size. Prehydrolysis of the precursor solution was found to be necessary to achieve dense films with ferroelectric properties.     

污水处理中膜污染控制的研究

膜的污染主要由沉淀、吸附、生物污染造成。笔者对这三种污染形成的原因进行了分析，并且提出了相应的控制方法。     

670矿床多期成矿作用特征及控矿因素研究

670矿床是典型的火山岩型富铀矿床,具有多期成矿特征。主要成矿期可分为两期。早成矿期矿化主要和红化有关,成矿溶液主要由大气降水组成,其中铀主要以UO_2(CO_3)_2~(2-)形式存在(99.6%),矿化温度133℃(平均值),成矿时代131Ma;晚成矿期成矿溶液主要为岩浆水,铀以UO_2(CO_3)~(2-)(89.4%)和UO_2(SO_4)_2~(2-)(9.2%)形式存在,矿化温度239℃(平均值),成矿时代为106.3±2.1Ma.670富铀矿床的形成是两期成矿作用叠加、多种因素复合作用的结果。     

The preparation of nanophase tungsten carbide powder with zeolite-X catalysts

The reduction–carburization of tungsten trioxide (WO₃) under carbon monoxide flow was studied in the temperature range of 300–750 °C. The reduction–carburization of WO₃ was improved by mechanically mixing with zeolite-HX, -NaX and -KX. The interaction between cation in zeolite-X and oxygen in WO₃ affected the improvement of the reduction–carburization of WO₃ to WC. Moreover, the improved reduction–carburization of WO₃ could lead to the decrease of reaction temperature. Because the particle size of WC is in contact with a reaction temperature, the nanophase WC can be prepared at low temperature. In particular, the particle size of WC was controlled by reaction temperature. The particle sizes of produced WC at 550, 650 and 700 °C were 25, 50 and 100 nm respectively.     

黄金坪金矿成因矿物学研究及其找矿评价

黄金坪金矿系典型碲—金建造。该文对主要组成矿物(包括碲金银系列矿物)的成因矿物学研究,通过系统分析典型矿物的结晶形貌、微量元素、晶胞参数、热电效应、显微硬度、反射率颜色指数、红外吸收、热发光性、稀土组成等标型特征,帮助确定矿床的成因类型并预测矿床的产出规模、矿石建造与矿石质量、深部远景及外围矿化带的评价诸方面。