Synthesis of tungsten carbide nanocrystals and their electrochemical properties

Tungsten carbide (WC) nanocrystals have been prepared by a solvothermal method with Mg as the reductant and WO₃ and anhydrous ethanol as the precursors. The effects of time and temperature on the synthesis of WC were investigated and a probable formation mechanism was discussed. The obtained WC nanocrystals were characterized by X-ray diffraction, transmission electron microscopy, energy dispersive spectroscopy and electrochemical methods. Hexagonal closepacked WC was successfully synthesized when the temperature was as low as 500°C. The content of carbon was more than that of W, indicating that the composition of the treated sample was C and WC only. The diameters of WC nanocrystals were ranged from 40 nm to 70 nm and the nanocrystals were dispersed on carbon films. The electrochemical measurements reveal that WC nanocrystals obviously promote Pt/C electrocatalytic ability for the oxygen reduction reaction. __________ Translated from Chinese Journal of Catalysis, 2008, 29(7) (in Chinese)     

新疆北山地区金矿的 X 射线荧光找矿标志

文章探讨了在新疆北山地区特殊地质环境下，采用现场Ｘ射线荧光测量找金的方法技术问题。提出适合于该区快速找金的Ｘ射线荧光找矿最佳指示元素为铁、铜、砷，铁和铜的Ｘ射线荧光异常出现在垂直于金矿（化）体走向的两侧，砷的Ｘ射线荧光在金矿（化）体上呈现异常。     

AACVD of WO3 thin films from W(O)(OPri)3[O(CH2)nNMe2] (n = 2, 3)

Monomeric tungsten oxo‐aminoalkoxides W(O)(OPrⁱ)₃(L) [L = O(CH₂)_nNMe₂; n = 2 (dmae, 1) and 3 (dmap, 2 )] were synthesized by alcohol exchange with [W(O)(OPrⁱ)₄]₂ and characterized spectroscopically. 1, 2 and [W(O)(OPrⁱ)₄]₂ were used as precursors for the aerosol‐assisted chemical vapour deposition of WO₃ thin films, which were characterized by glancing angle X‐ray diffraction, SEM and transmission‐reflectance measurements. Copyright © 2008 John Wiley & Sons, Ltd.     

半自动定容定位氢化装置及应用

研制半自动定容试液，半自动定位恒速注入KBK4，整个氢化过程不串空气，可用压力全方位喷射冲洗反应室。该装置定容定位准确，操作简便快速，适用于大批量样品分析。通过对8个GSD标准参考物质的分析，分析结果与参考值基本一致，RSD＜6％。     

三维变异函数的稳健统计学计算方法及其应用

在应用地质统计学进行矿床建模工作中，变异函数的计算和拟合占有非常重要的地位，其结果的好坏将直接影响建模效果．针对传统变异函数计算及拟合方法的缺陷，运用稳健统计学理论，讨论了三维情况下实验变异函数的计算以及拟合方法．矿床建模实践表明，采取上述技术取得了良好的效果．     

A comparative study on aldol‐type condensation reactions of cyclic,acyclic and substituted cyclic ketones by the W(CO)6/CCl4/UV system

Aldol‐type condensation reactions of a number of cyclic, acyclic and substituted cyclic ketones were investigated using the W(CO)₆/CCl₄/UV system. The progress of the reactions was followed by IR and GC‐MS techniques. The cyclic ketone derivatives with β‐ and γ‐substituent gave the expected condensation products. However, the α‐substituted cyclic, acyclic and unsubstituted cyclic ketones with rings larger than six did not. Formation of [W]–ketone complexes with all of the ketones used was observed by FTIR. With respect to our studies, a mechanism involving an intermediate seven‐coordinate tungsten complex has been proposed. Copyright © 2005 John Wiley & Sons, Ltd.     

浅析新洲背斜的构造演化与成矿机理

地应力的作用使新洲背斜发生隆起,在浅表形成相应的劈裂、滑移及挤压区,地应力的不平衡,使辉绿岩岩浆侵入,其析出的含金、锑热液形成锑→金分带性产出,并受地层及构造控制。根据其成因分析,在新洲背斜东部核心区的周边成矿条件较为优越,存在发现新矿床的前景。     

超大型矿床研究中某些问题的讨论及找矿

超大型矿床，一般指单个矿床中规模达超大型者。若将矿田内多个矿床，合称超大型矿床，则与矿床和矿田定义不符，应研究统一术语。超大型矿床划分标准，应便于全球对比和简单易行。提出一个以Ｐ．Ｌａｚｎｉｃｋａ和涂光炽的划分标准为基础的综合方案，在统一标准以前供同行研究时参考。超大型矿床分布形式，分点式、带式及首领式。后者为找矿重点。关于超大型矿床成矿流体特征、控矿因素和找矿问题，以某些金矿为例作了初步研究。未发现任何独特的成矿流体。这类矿床的形成受多因素控制，具多因复成矿床特点。综合运用多种找矿方法与手段，但有侧重，是适宜的。