Effect of Particle Size and Capping on Photoluminescence Quantum Efficiency of 1,3,5-Triphenyl-2-pyrazoline Nanocrystals

Organic nanocrystals of 1,3,5-triphenyl-2-pyrazoline(TPP) with a series of sizes were synthesized by reprecipitation method.The luminescence quantum efficiency of TPP nanocrystals increases from 24.2% for the nanocrystals with an average size of 300nm to 34.6% for those with an average size of 20nm.Surface capping by polyvinyl pyrrolidone(PVP) will improve the quantum efficiency of TPP nanocrystals.The size-dependence and capping-induced variation of the luminescence quantum efficiency was elucidated in viewpoint of aggregation quenching and the equilibrium between the TPP monomers and the aggregates in TPP nanocrystals.     

Developments on carbon dioxide reduction: Their promise,achievements, and challenges

CO₂ reduction processes continue to be developed for electrosynthesis, energy storage applications, and environmental remediation. A number of promising materials have shown high activity and selectivity to target reduction products. However, the progress has been mainly at a small laboratory scale, and the technical challenges of large scale CO₂ reduction have not been considered adequately. This review covers recent advancements in catalyst materials and cell designs. The leading materials for CO₂ reduction to a number of useful products are presented with their corresponding cell and reactor designs. The latest efforts to progress to industrially relevant scales are discussed, along with the challenges that must be met for carbon dioxide reduction to be a viable route for mass scale production.     

Efficiency in integral facility design problems

An example of design might be a warehouse floor (represented by a setS) of areaA, with unspecified shape. Givenm warehouse users, we suppose that useri has a known disutility functionf _isuch thatH _i(S), the integral off _iover the setS (for example, total travel distance), defines the disutility of the designS to useri. For the vectorH(S) with entriesH _i(S), we study the vector minimization problem over the set {H(S) :S a design} and call a design efficient if and only if it solves this problem. Assuming a mild regularity condition, we give necessary and sufficient conditions for a design to be efficient, as well as verifiable conditions for the regularity condition to hold. For the case wheref _iis thel _p-distance from warehouse docki, with 1<p<, a design is efficient if and only if it is essentially the same as a contour set of some Steiner-Weber functionf =₁ f ₁++ _m f _m ,when the _i are nonnegative constants, not all zero.This research was supported in part by the Interuniversity College for PhD Studies in Management Sciences (CIM), Brussels, Belgium; by the Army Research Office, Triangle Park, North Carolina; by a National Academy of Sciences-National Research Council Postdoctorate Associateship; and by the Operations Research Division, National Bureau of Standards, Washington, D.C. The authors would like to thank R. E. Wendell for calling Ref. 16 to their attention.     

超临界CO2法制备头孢唑啉钠脂质体

采用超临界CO2(scCO2)流体代替有机溶剂一步法制备了头孢唑啉钠药物载体脂质体. 研究了该脂质体的尺寸、稳定性和药物的包封率. 结果表明, 脂质体的尺寸和稳定性依赖于制备压力, 脂质体对头孢唑啉钠的包封率与乙醇和脂浓度有关, 采用超临界CO2法制备脂质体的药物包封率比采用薄膜分散法(Bangham method)制备的包封率高.     

An investigation of heparinase immobilization

A systematic investigation of the parameters that affect the efficiency of immobilizing heparinase onto cyanogen bromide activated crosslinked 8% agarose beads was conducted. Two experimental measures, the “fraction bound” and the “fraction retained,” were used to monitor the coupling efficiency. The fraction bound is the portion of the total initial enzyme that is bound to the agarose gel. The fraction retained is the fraction of bound enzyme that is active. The product of the two measures indicates the coupling efficiency. The activity of the immobilized heparinase was measured under conditions free of both internal and external mass transfer limitations, and thus, the fraction retained represents the true immobilized enzyme activity. Increasing the degree of activation of the beads results in an increase in the fraction bound, the fraction retained, and consequently, the coupling efficiency. As the ratio of enzyme solution to gel volume increases from 1.5 to 2.2, the fraction bound remains constant but the fraction retained decreases (heparinase concentration; 0.15 mg/mL and degree of activation; 9.5 μmol of cyanate esters/g of gel). At volume ratios greater than 2.2, both the fraction bound and the fraction retained decline continuously. Changing the heparinase concentration in the coupling solution changes the coupling efficiency in a manner similar to that of the volume ratio change. When heparin is added during the coupling process, the fraction bound declines as the heparin concentration increases, whereas the fraction retained increases up to a heparin concentration of 12 mg/mL and decreases thereafter. When arginine, lysine, and glycine are used to block the unreacted cyanate ester groups after the coupling process, the immobilized heparinase shows different pH optima of 6.5, 6.9, and 7.2, respectively. Based upon these findings, a protocol to optimize heparinase immobilization is developed.     

三芳基咪唑类化合物的合成及其双光子吸收性能研究

双光子吸收是指物质分子或原子在强激光激发下同时吸收两个光子,从基态跃迁到两倍光子能量激发态的过程。目前,双光子吸收材料已广泛地应用到双光子激发显微[1]、频率上转换激射[2-3]、光学限幅、三维光信息存储[4]以及光生物学等领域。但在已报道的双光子诱导上转换荧光的有机     

程序涂渍柱“柱效能程序效应”的研究

本文从理论上给出程序柱“柱效能程序效应”的概念并导出了函数关系式,通过计算机可计算柱效能程序效应与柱内各变量之间的关系,实践证明实验数据的变化趋势与理论数据相符。     

Thermal and thermoxidative degradations of starch and thermosensitive starch-g-BAM copolymers

Summary Thermal degradation under N₂atmosphere and thermoxidative degradation under air atmosphere of increasingly grafting efficiency values (i.e. GE%=0.0 to 35.5) for starch and starch grafted with N-tert-butylacrylamide thermosensitive copolymers (starch-g-BAM) by Ozawa and Kissinger methods using thermogravimetric analysis (TG) and differential scanning calorimetry techniques (DSC) at 10, 30 and 50% mass losses respectively have been studied. Influence of physical inter and intra molecular interactions on grafting and consequently on activation energy of degradation (E_a,d) was investigated using Ozawa's method, whereas linear dependence of E_a,don GE% by scaling relations using Kissinger's method was determined. Furthermore, the thermoxidative degradation induces the possibility of molecular rearrangement, cyclization and partial crosslinking that is deduced from the activation energy of degradation (E_a,d) and residual mass of TG profile. Thermal stability of starch does not alter as a result of different grafting efficiency percentages.     

Structural Efficiency and Microstructural Modeling of Wet Gels and Aerogels

We present a microstructural model of aerogels that includes the effect of particle necks, tortuosity and dangling ends on the scaling of elastic moduli with density. Relative neck radii can be determined for sintering series of silica aerogels and for Resorcinol Formaldehyde (RF) aerogels produced with different catalyst concentrations. The density of elastically ineffective dangling ends and the tortuosity can be estimated using information from thermal conductivity and elastic modulus measurements in silica aerogels. Typical values for the load bearing mass range from >50% for high density and heat treated aerogels to <10% of the total mass for low density wet-gels.     

Practical limitations of capillary gas chromatography

Glass capillary gas chromatography is a high resolution separation method which allows the qualitative and quantitative analysis of even complex mixtures, which may contain many components–also isomeric–in a wide range of volatilities, polarities and concentrations. The principal limitation of gas chromatographic application is given by an insufficient volatility of the species to be separated. Elevated temperatures have to be applied if the application range is to be extended and to achieve steep peak profiles, i.e. low detection limits at high resolution. The use of elevated temperatures is limited, of course, by the temperature stability of both the solvent (stationary liquid and support) and the solutes. The problems of trace analysis for low volatility compounds at high resolution and its limitational parameters regarding sampling, separation and detection are discussed. The applicability of glass capillary columns in this field is influenced by the following parameters: tailing behaviour; irreversible adsorption of polar and decomposition of unstable solutes; thermal stability of stationary liquid (including the support deactivation); separation efficiency and sample capacity (film thickness). Multidimensional gas chromatography using capillary columns coupled either with a packed or another capilllary column for preseparations may be applied with advantage in the analysis of complex mixtures.