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101.
Thermotropic copolyester fibers of oxynaphthoate and oxybenzoate have been subjected to conditions that promote solid-state polymerization as well as annealing. The annealing process causes the crystals to perfect with a simultaneous increase in heat of fusion and melting temperature. Solid-state polymerization, a reaction rate-controlled process, causes the polymer viscosity average molecular weight to increase by chain extension from about 14,000 g/mole to more than 87,000 g/mole with a simultaneous impressive increase in tenacity from about 10 g/d (1.2 GPa) to almost 30 g/d (3.7 GPa). To understand the changes in mechanical properties, we have modeled the fiber structure as short rod-like molecules poorly bonded to a continuous matrix of parallel molecules. Lengthening of the reinforcing molecules facilitates better transfer of load from matrix to molecules, resulting in higher tenacity fibers. © 1994 John Wiley & Sons, Inc. 相似文献
102.
李学敏 《山东师范大学学报(自然科学版)》1994,9(1):6-10
讨论了第一临界情形下的平面三次系统高次奇点的局部拓朴结构,并给出利用多项式系数的判断准则。 相似文献
103.
A general relationship between the volume fraction and the specific interfacial area for averaged dispersed two-phase flows is proposed. This relationship, expressed as a basic set of two scalar evolution equations and two vectorial non-uniformity state equations, is an analytical result obtained by a systematic approach using the derivatives of some generalized functions and a local volume-averaging technique. The proposed set of equations was expressed for measurable macroscopic parameters of the system and has the same generality as the averaged transport equations of two-phase flows. By combination of the basic set of equations, called the averaged topological equations (ATEs), second-order ATEs for the volume fraction were found. The second-order ATEs were expressed both by a Lagrangian formulation and by a Eulerian formulation. The importance and physical meaning of the ATEs developed in this study were clarified within the framework of the theory of kinematic waves. 相似文献
104.
超球拓扑积域特征流形上的奇异积分 总被引:1,自引:1,他引:0
在超球拓扑积域中建立了Cauchy型积分,定义了其特征流行上的奇异积分和奇异积分的Cauchy主值,进一步讨论了Cauchy型积分在特征流形上极限。 相似文献
105.
106.
We have studied the temperature dependence of the radiative deactivation of the Pd-porphine triplet states in Shpol’skii matrices
in the temperature range 1.2–210 K. A substantial transformation of the phosphorescence spectra is observed as the temperature
increases and is due to the inclusion of thermally activated Pd-porphine states in the radiative deactivation processes. The
activation energy Ea of these Pd-porphine states is measured in matrices of n-octane and n-nonane. The splitting of the lowest quasidegenerate
triplet state ΔE(T2−T1) is determined for planar and distorted conformations of the Pd-porphine macrocycle in the n-octane matrix as 40 and 57 cm−1, respectively. The ability to use the temperature dependence of the phosphorescence properties of Pd-porphine to fabricate
molecular thermometers for the low-temperature range is analyzed.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 4, pp. 460–464, July–August, 2007. 相似文献
107.
惠小静 《延安大学学报(自然科学版)》2007,26(2):5-8
提出了r不定序同态、r连续序同态、r开序同态并讨论了它们之间的相互关系,得出了LF-r开集在开子空间中仍是LF-r开集,两个LF拓扑空间之间序同态r连续的充要条件等结论。 相似文献
108.
在L-smooth拓扑空间中借助于L-smooth半闭集给出了L-smooth s-远域、s-附着点、s-聚点等概念,进一步讨论了网的s收-敛,并研究了它们的一些基本性质.从而,丰富了已有的结果. 相似文献
109.
110.
S. F. Chekmarev R. Mitri V. Bonaci-Koutecký 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):45-48
The ab initio molecular
dynamics (AIMD) [1] is combined with the heuristic, successive
confinement method of surveying a potential energy surface (PES)
[2], thereby offering a framework for the simulation study of
kinetics and equilibrium properties of metallic clusters. This
approach is applied to the study of Au4,
a cluster possessing a simple but specific PES, which consists
of very shallow and deep basins and due to this presents a
challenge to the conventional AIMD methods. Among other things,
the probabilities of the transitions between isomers have been
found, and on this basis, both the time-dependent and
equilibrium populations of the isomers have been calculated for
the conditions typical of the NeNePo experiments [3] in the
femtosecond pump-probe spectroscopy. 相似文献