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11.
应用模糊模式识别方法对阜新新邱露天煤矿排土场附近(于家沟),地下水污染区的水质监测点分类优选问题进行了研究,对研究区内的12眼水井分别采样,进行水质分析,识别出总硬度、硫酸盐、氯化物、溶解性总固体等主要污染因子;进而采用模糊模式识别方法,对区内的12个监测点进行了优化.计算结果表明可从于家沟地下水污染区的12个监测点中选取具有代表性的3、7、11号监测点进行监测,节省了人力、物力及资源. 相似文献
12.
机动车排放的尾气污染物,在城市街道峡谷内的稀释扩散及分布特性,主要由街道内流动结构决定,而街道布局和结构对流动结构有重要影响。基于二维不可压缩流动的Navier-Stocks方程、污染物组分输运方程及标准k-?湍流模型,获取所构建模型的数值解。采用验证的模型参数,构建了9种2类高宽比H/W为1的二维城市街道截面形态构造,在来流平均风速为3 m/s情况下,研究了街道截面形态对机动车尾气污染物扩散传递的影响。结果表明:下沉式道路结构不会改变街道峡谷内主涡结构和污染物分布;随着下沉深度的增加,机动车道内污染程度将进一步加剧;廊道内污染物浓度分布受廊道高度的影响较大,其人行呼吸高度处背风侧附近污染物浓度值相对参考工况增加大约5%,廊道深度对街谷内污染物扩散影响不大。 相似文献
13.
小图像由于像素少、分辨率低、整幅图像包含信息较少,识别较为困难。目前优秀的深度卷积神经网络模型多为大图像而设计,而用于小图像的模型则存在着层次不够深、难以对特征进行充分抽象的不足。本文基于VGG19模型,依据卷积核分解的原理,设计了一种KDS-DCNN模型,模型深度达到31层,解决了目前超深度模型不能直接用于小图像识别的问题,实验表明该方法不但提升了识别性能,而且还降低了模型的时间复杂度。在CIFAR-10、CIFAR-100和SVHN三个数据集上的验证结果显示,KDS-DCNN模型性能优越,其识别错误率分别降低到29.46%、6.02%和2.17%。 相似文献
14.
Pollutants release is highly consistent with suspended sediment concentration (SSC) in water column, especially during re-suspension and transport events. The present research focuses on pollutant dynamic release from re-suspended sediment, especially the vertical distribution relationship between them. The sediment erosion experiments on a series of uniform flow are conducted in a circulate flume. Reactive tracer (phosphorus) is used as the contaminant in fine-grained sediments to identify the release characteristic length and time. Experimental results show that the flow condition near-bed depends on the sediment surface roughness. The region with high turbulent intensities corresponds to a high concentration sediment layer. In addition, the SSC decreases with the distance, water depth, and particle grain size. The sediment in a smaller grain size takes much more time to reach equilibrium concentration. Total phosphorus (TP) concentration changes along the water depth as SSC in the initial re-suspension stage, appearing in two obvious concentration regimes: the upper low-concentration layer and the high-concentration near-bottom layer. This layered phenomenon remains for about 3 hours until SSC distri- bution tends to be uniform. Longitudinal desorption plays an important role in long-way transport to reduce the amount of suspended sediment in water column. 相似文献
15.
16.
水动力作用对污染物在河流水沙两相中分配的影响研究进展 总被引:1,自引:0,他引:1
通过总结近年来有关水动力作用对河流中泥沙吸附/释放重金属、磷等污染物影响研究成果,分析了水流紊动强度和流速对污染物在河流水沙两相中分配的影响规律。当水流紊动强度较低时,泥沙主要以床沙形式存在,泥沙对污染物的吸附/释放速率和强度较低;随着紊动强度增大,水沙界面切应力随之增大并促使泥沙悬浮,污染物与悬浮泥沙颗粒接触面积增大,使得泥沙对污染物的吸附/释放速率和强度显著增加。流速对污染物在水沙两相间分配的影响较为复杂。泥沙静止时,流速的增大会减小边界层厚度,增大水体溶解氧含量、氧化还原电位等参数,并使污染物在水体里的扩散由分子扩散转变为以紊动扩散为主,增强污染物在水-沙界面的交换通量,对污染物在水沙两相间的分配产生影响;随着流速进一步增大,床沙逐渐起动、悬浮,此时除上述因素外,泥沙运动状态、悬浮颗粒间碰撞强度、悬浮物的絮凝等均会对泥沙吸附/释放污染物产生影响,由于影响因素较多,作用机制复杂,目前关于泥沙运动对污染物在水沙两相间分配的影响所得结论仍存在分歧。相应的机理研究及数学模型的建立均做了较大简化。综观当前的研究成果,水沙运动及其化学生物过程等对污染物在河流水沙两相中的分配作用机理和耗氧有机物、有毒有机物等污染物与泥沙的作用机理是这一领域的未来研究重点。 相似文献
17.
K. Alagumalai R. Shanmugam T.-W. Chen S.-M. Chen M. Balamurugan S.S. Choi M.A. Ali A.M. Al-Mohaimeed C.-H. Fan 《Materials Today Chemistry》2022
In this work, we developed a perovskite structured samarium cobalt oxide nanoparticles (SmCoO3 NPs) with the aid of the co-precipitation method. The rare earth metal (Sm) and cobalt oxide combined to form a perovskite lattice structure. One-pot route synthesized SmCoO3 NPs were scrutinized successfully through various physicochemical techniques. Concerning its effective thermal stability and electrical properties, the synthesized SmCoO3 NPs have been effectively implemented in the electrochemical evaluation of promethazine hydrochloride (PHY) using cyclic voltammetry. The electrochemical detection of PHY was performed through SmCoO3 NPs-modified glassy carbon electrode (GCE) and unmodified GCE. The electron transfer kinetics, effect of scan rate, the influence of pH, electroactive surface area, selectivity, and sensitivity have been studied. The electron charge transfer rate (Rct) and electrolyte resistance (Rs) were calculated to be 105.59 (Ω) and 150 (Ω) in the ferricyanide probe, indicating great facilitation of the electron transfer between PHY and SmCoO3 NPs deposited on the electrode surface. Further, the optimized SmCoO3-modified GCE exemplifies excellent selectivity, storage stability, reproducibility, repeatability, detection limit (5 nM), sensitivity (0.594 μA μM?1 cm?2), and wide consecutive linear ranges, respectively. Besides, the proposed method has been effectively employed for the detection of PHY in the various real samples which reveals good recoveries of 95.40–99.17%. 相似文献
18.
Deling Yuan Mengting Sun Shoufeng Tang Yating Zhang Zetao Wang Jinbang Qi Yandi Rao Qingrui Zhang 《中国化学快报》2020,31(2):547-550
Constructing a Z-scheme is a significant approach to improve the separation of photogene rated carriers for effective organic pollutant degradation.Herein,a BiVO4/ZnIn2S4(BZ) Z-scheme composite was successfully synthesized,and applied to photodegrade methyl orange(MO) irradiated by a LED lamp.Anchoring the BiVO4 on the ZnIn2S4 nanoparticles promoted the separation of photogenerated electronholes and broadened the light response range.The detailed characterizations,including surface morphology,elements valence state,and photocurrent performance,demonstrated that the enhanced separation of photogenerated carriers was the pivotal reason for the enhanced photocatalysis reaction.Benefiting from the excellent photocatalytic characteristics,the 5% mass ratio of BZ composite presented the highest MO degradation rate of 0.00997 min^-1,which was 1.9 and 10.3 times greater than the virgin ZnIn2S4 and BiVO4,respectively.Furthermore,the BZ hybrid materials indicated a well photo-stability in the four recycling tests. 相似文献
19.
对中学化学学生实验活动中产生的气体污染物进行测试,得到不同通风条件下化学实验室内部空气污染物的数据。结果表明,中学化学学生分组实验产生的主要气体污染物有苯、甲苯、甲醛、氨气等,实验过程中如不采取任何通风措施,实验室气体污染物的浓度短时间内会急剧升高,所以采取有效措施对实验室内部空气污染物进行消除是非常必要的。目前中学化学实验室配备的通风设备以桌面排风设备为主,相比于自然通风的环境,学生实验时开启桌面排风设备,能够有效降低实验产生的气体污染物浓度。 相似文献
20.
Tuba Tabanlgil Calam 《Electroanalysis》2020,32(1):149-158
A simple and fast electrochemical method was described and evaluated to determine the hazardous compound, 4‐nitrophenol (4NP). In this work, concentration of 4NP was determined by differential wave voltammetry (DPV). A gold electrode (Au) was modified with 3,5‐diamino‐1,2,4‐triazole (35DT). The modified electrode (35DT‐Au) was characterized by using electrochemical impedance spectroscopy (EIS), fouirer transform infrared spektrofotometre (FTIR), cyclic voltammetry (CV) and DPV. The modified electrode showed more sensitivity towards 4NP compared to unmodified one. A wide linear concentration range from 0.24 to 130.6 μM was obtained for 4NP with a detection limit of 0.09 μM. In the reproducibility and repeatability studies, the relative standard deviation (RSD%) values of the method were obtained as 3.72 % and 2.56 %, respectively, which are acceptable values. This proposed method was successfully used for the analysis of 4NP in lake and tap water samples. Simplicity, sensitivity, selectivity and high efficiency of the proposed method can be used in routine analysis of trace amounts of 4NP in polluted waters. 相似文献