SC-200质子加速器输运部磁体电源的输出纹波形成机理分析及其Simplorer仿真

介绍了质子治疗加速器输运部二极磁铁电流源的技术要求、主电路拓扑。该电源要求输出电流精度为25ppm，纹波小于25ppm。电源输出电流纹波由低频纹波和高频纹波组成。对电源输出电流纹波的形成机理进行了详细的理论分析和数学计算。得出了基于冲量控制原理的脉冲宽度调制(PWM)电流跟踪控制技术可以有效消除输入低频纹波对输出电流的影响。同时也对输出电流高频纹波采用两种方法进行了定量的数学分析，并得出量化的结论和计算公式。借助AnsoftSimplorer电路仿真软件构建模型，验证了纹波规律结论及计算公式的准确性，并且提出了相应的纹波抑制策略。     

Confined subdiffusion in three dimensions

Three-dimensional （3D） Fick＇s diffusion equation and fractional diffusion equation are solved for different reflecting boundaries. We use the continuous time random walk model （CTRW） to investigate the time-averaged mean square dis- placement （MSD） of a 3D single particle trajectory. Theoretical results show that the ensemble average of the time-averaged MSD can be expressed analytically by a Mittag-Leffler function. Our new expression is in agreement with previous formu- las in two limiting cases： （^-δ2） ~ △1 in short lag time and （^-δ2} ~ △1 -α in long lag time. We also simulate the experimental data of mRNA diffusion in living E. coli using a 3D CTRW model under confined and crowded conditions. The simulation results are well consistent with experimental results. The calculations of power spectral density （PSD） further indicate the subdiffsive behavior of an individual trajectory.     

Unsteady three‐dimensional boundary layer flow due to a stretching surface in a micropolar fluid

In this paper, the unsteady three‐dimensional boundary layer flow due to a stretching surface in a viscous and incompressible micropolar fluid is considered. The partial differential equations governing the unsteady laminar boundary layer flow are solved numerically using an implicit finite‐difference scheme. The numerical solutions are obtained which are uniformly valid for all dimensionless time from initial unsteady‐state flow to final steady‐state flow in the whole spatial region. The equations for the initial unsteady‐state flow are also solved analytically. It is found that there is a smooth transition from the small‐time solution to the large‐time solution. The features of the flow for different values of the governing parameters are analyzed and discussed. The solutions of interest for the skin friction coefficient with various values of the stretching parameter c and material parameter K are presented. Copyright © 2011 John Wiley & Sons, Ltd.     

Fe3O4@SiO2–ZrCl2‐MNPs: A novel magnetic catalyst for the clean and efficient cascade synthesis of 1‐(benzothiazolylamino)methyl‐2‐naphthol derivatives in the absence of solvent

A green, simple and eco‐friendly three‐component condensation for the synthesis of 1‐(benzothiazolylamino)methyl‐2‐naphthols using new magnetic nanoparticles formulated as Fe₃O₄@SiO₂–ZrCl₂‐MNPs is described. Considering the economic and environmental aspects, the method provides some advantages such as clean procedure, solvent‐free conditions, simple operation and work‐up, relatively short reaction times and high yields of the products. Moreover the introduced catalyst can be readily recovered up to 4 consecutive runs with consistent activity using an external magnet.     

Dual cocatalysts decorated three dimensionally ordered mesoporous g-C3N4 with homogeneous wall thickness for enhanced photocatalytic performance

Making several components be more intimate interfacial contacts in the photocatalyst is an efficient strategy to improve the separation and transfer of photogenerated charge carries and enhance the photocatalytic performance in the visible light region. In this work, a promising photocatalyst was fabricated by loading of Au nanoparticles and Cd_(0.58)Zn_(0.42)S nanoparticles onto the three dimensionally ordered mesoporous g-C₃N₄ material (Au/3DOM CN/Cd_(0.58)Zn_(0.42)S) via two-step synthesis method to significantly intensify the transfer capability of charge. The results of characterization demonstrate that Au/3DOM CN/Cd_(0.58)Zn_(0.42)S photocatalyst possesses the intimate interfacial contacts of three components and homogeneous wall thickness of 3DOM g-C₃N₄ framework, and these properties give Au/3DOM CN/Cd_(0.58)Zn_(0.42)S photocatalyst an ability that it can harvest a wider range of visible light and endow it superior photocatalytic activities for hydrogen evolution from water splitting and RhB degradation. Finally, a possible mechanism was proposed based on the photoelectrochemical measurement. This work would provide a new strategy to design and fabricate g-C₃N₄-based with 3DOM architecture materials with superior photocatalytic activity.     

CuO nanoparticles supported on three‐dimensional nitrogen‐doped graphene as a promising catalyst for thermal decomposition of ammonium perchlorate

In the present work, CuO nanoparticles grown on three‐dimensional nitrogen‐doped graphene‐based frameworks (CuO@3D‐(N)GFs) were synthesized using a two‐step method. After the synthesis of three‐dimensional nitrogen‐doped graphene, CuO nanoparticles were deposited on it, by adding cupric acetate followed by thermal treatment. Different analysis methods were used to characterize the products. The as‐prepared nanocomposite was used as a promising catalyst for thermal decomposition of ammonium perchlorate (AP) as one of the most common oxidizer in composite propellants. Differential scanning calorimetry (DSC) and thermogravimetry analysis (TGA) techniques were used to investigate the thermal decomposition of ammonium perchlorate. According to the DSC/TGA, high temperature decomposition of AP decreased to 111 °C in the presence of 4% CuO@3D‐(N)GFs and the total heat release (ΔH) from decomposition of AP increased to 1893 J g^?1 which is much more than 590 J g^?1 for pure AP.     

A review on enzyme and ultrasound: A controversial but fruitful relationship

A critical review on the effect of ultrasound (US) on enzymes and their biocatalytic action is presented here. Discussion on the information users of US acquire before utilizing the different devices, and the importance they give to US frequency is constant along the review. The authors have gone into the different areas in which the US–enzyme binomial has been applied. The lack of enough information on the US–enzyme-working conditions under which each piece of research has been developed, and the necessity to provide complete information on the data and metadata to give enough light on each piece of research (and thus on the potential comparison of results from different studies) are critically exposed. With this aim, the study has been divided into the positive effect of US on enzymes to favor the production of metabolites, polymers or proteins; and the degradation, inhibition or activation of the biocatalyst under US application. Also the effect of US on enzyme production and the main fields of application of the US–enzyme binomial are discussed.     

Excess molar volumes and deviation in viscosities of binary liquid mixtures of acrylic esters with hexane-1-ol at 303.15 and 313.15 K

Densities and viscosities for the four binary liquid mixtures of methyl acrylate, ethyl acrylate, butyl acrylate and methyl methacrylate with hexane-1-ol at temperatures 303.15 and 313.15 K and at atmospheric pressure were measured over the entire composition range. These values were used to calculate excess molar volumes and deviation in viscosities which were fitted to Redlich–Kister polynomial equation. Recently proposed Jouyban Acree model was also used to correlate the experimental values of density and viscosity. The mixture viscosities were correlated by several semi-empirical approaches like Hind, Choudhary–Katti, Grunberg–Nissan, Tamura and Kurata, McAllister three and four body model equations. A graphical representation of excess molar volumes and deviation in isentropic compressibility shows positive nature whereas deviation in viscosity shows negative nature at both temperatures for all four binary liquid mixtures. Positive values of excess molar volumes show that volume expansion is taking place causing rupture of H-bonds in self associated alcohols. The results were discussed in terms of molecular interactions prevailing in the mixtures.     

刚构连续梁桥墩梁固节点结构的光弹性试验及有限元分析

某铁路特大桥的主桥部分采用预应力混凝土刚构连续梁桥,本文采用光弹性模型冻结应力法对该刚构连续梁桥墩梁固节点结构进行了应力分析,给出了结构边界应力分布和主应力迹线。应用ANSYS软件对墩梁固节点实际结构进行了有限元计算。将实验与有限元分析结果进行了比较,结果表明,实验应力分析法与有限元数值法吻合较好。在有限元分析中,对墩梁固节点结构梁端加载边界的影响区进行了研究,通过合理选择梁的长度可以有效减小局部应力。模型实验和有限元计算的结果为结构的优化设计提供了重要的依据。