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971.
T. Saraidarov R. Reisfeld A. Sashchiuk E. Lifshitz 《Journal of Sol-Gel Science and Technology》2003,26(1-3):533-540
PbS nanocrystals (NCs) ranging between 4–8 nm were incorporated into Zirconium-Silica-Urethane (ZSUR) matrix obtained by the sol-gel method. The sizes of the particles were controlled by temperature treatment and by concentration of PbS in ZSUR matrix. The sizes of PbS NCs were determined by TEM measurements. The quantum size effect could also be extracted from optical absorption and photoluminescence spectra. The new matrix allows incorporation of up to 40% PbS forming a characteristic structure of dendrite by reacting lead acetate with ammonium thiocyanate in sol-gel matrix. The sol precursors of the matrix for Zirconium-Silica-Urethane contained zirconium oxide (ZrO2) matrix solution, tetramethoxysilane (TMOS), 3-glycid oxypropyl trimethoxysilane (GLYMO) and polyethylene urethane silane (PEUS) synthesized separately. The ZrO2 matrix solution was obtained from zirconium n-tetrapropoxide in propanol and acetic acid was used as a chelating agent to stabilize the zirconium oxide precursor. 相似文献
972.
Chemometric techniques have been used to compare two methods for fat extraction, namely focused microwave-assisted Soxhlet extraction (FMASE) and dynamic ultrasound-assisted extraction (DUAE), with the conventional Folch method, frequently used as reference. The data generated by a mid infrared spectrometer, after appropriate treatment, provide a simple and effective way for the detection of potential alterations of the fat obtained with the assistance of auxiliary energies, in this case, microwaves and ultrasounds. The results thus obtained are as compared with those from the Folch method, a mild extraction method with a view to finding faster alternatives for routine analysis. Moreover, classification of the samples between cookies and snacks based on extraction kinetics studies was possible, thus demonstrating the importance of these studies for the development of analytical methods. Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA) were used for both purposes, namely detection of alterations and classification of the samples as a function of their extraction kinetics, while K Nearest Neighbours (KNN) and Soft Independent Modelling of Class Analogy (SIMCA), based on PCA, models were generated in order both to predict the extraction kinetics of unknown samples, thus adjusting the extraction time as a function of the matrix, and find out explanation to the different extraction kinetics. 相似文献
973.
974.
The organic nanoparticles of a blue-light-emitting molecule, 1,3-diphenyl-5-(9-anthryl)-2-pyrazuline, were prepared by reprecipitation method using acetonitrile as the solvent for the molecular precursor. Three morphologies, spherical, doughnut-shaped and cubic, could be observed on the silicon substrate forthe nanoparfides by the volume-controlled addition of acetonitrile. The evolution of particle morphology as a function of acetonitrile addition was attributed to the variation of the growth habits of the particles in the different environment. The nanoparticles exhibit the novel photoluminescence spectra as compared to those of monomer and the bulk crystals. 相似文献
975.
Stribeck N 《Analytical and bioanalytical chemistry》2003,376(5):608-617
The prospects of a modern analysis of nanostructure evolution during the processing of polymer materials by means of scattering from synchrotron radiation are demonstrated in examples. The beam sources have gained stability, shortages are located in beamline setups and in method development for the quantitative analysis of voluminous data sets.By using the proposed multidimensional chord distribution function (CDF) analysis method, nanostructure information from small-angle X-ray scattering (SAXS) data are extracted and visualised. The method can be automated if the beamline setup is able to deliver a full data set with simple constraints. In this case even a simultaneous data evaluation is possible (while one pattern is accumulated, the previous one is analysed). The advantages of the method are demonstrated in a study of the straining of a thermoplastic elastomer. The possibilities of an automated analysis are demonstrated in an investigation of the crystallisation behaviour of high-pressure injection-moulded polyethylene (HPIM-PE). The achievable results of nanostructure analysis of polymer materials are discussed. It is shown that the time-resolved SAXS of polymer materials studied during a transformation and analysed by the CDF method is not just a powerful tool to investigate the relationship between structure and properties of materials; the information that can be gained concerning the processes that control nanostructure evolution is equally important. In the future the enlightenment of such relationships may help to tailor polymer materials with respect to their properties and, beyond that, to improve assessments concerning their aging. 相似文献
976.
Tautomerism of Nunsubstituted benzohydroxamic acids and their anions in the gas phase was investigated by the semiempirical AM1 method. The possibility of estimating pK
a in aqueous solutions using calculated characteristics of molecules is demonstrated. 相似文献
977.
以金属硝酸盐为原料,分别采用高分子前驱体法、柠檬酸盐凝胶法制备了纳米级的Ce-Zr-Ba-O复合氧化物超细粒子,采用X-射线衍射(XRD)、透射电镜(TEM)、BET比表面测定、热重-差热(TG-DTA)技术对催化剂进行了表征,并考察了催化剂的CO氧化活性和热稳定性。实验结果表明,高分子前驱体法和柠檬酸盐凝胶法制备的催化剂粉体都达到了纳米级。两种方法中,高分子前驱体法所制得的催化剂的BET比表面达118.96m2·g-1,CO氧化反应活性较高,同时该方法制得的催化剂分散性好,无团聚,经1000℃高温焙烧后仍基本无烧结、无团聚现象,具有较高的热稳定性。 相似文献
978.
Pt3Co核-Pt壳型纳米粒子的制备及磁性 总被引:1,自引:1,他引:1
Pt3Co alloy nanoparticles were prepared by the reduction of H2PtCl6 and Co(OOCCH3)2 using NaBH4 as a reducing agent. The Pt3Co core-Pt shell nanoparticles (Pt3Co@Pt) were synthesized using hydrogen absorption reduction and characterized by plasma-atomic emission spectrometry (ICP), transmission electron microscopy (TEM), X-ray diffraction (XRD) and SQUID magnetometer. The results show that average size of Pt3Co@Pt nanoparticles is 3.6 nm with a standard deviation of 0.9 nm. Heating Pt3Co nanoparticles in air at 700 ℃ for 1 h, Co in Pt3Co nanoparticles was oxidized to Co3O4 and CoO; while no oxidation tendency was detected for Pt3Co@Pt nanoparticles. The crystallize structure of Pt3Co@Pt changed from the face centered cube (fcc) to the face centered tetragonal (fct) after the heating treatment. The coercivity of the heated Pt3Co@Pt reached to 276 Oe at room temperature. 相似文献
979.
建立火焰原子吸收光谱法测定天然气转化催化剂中氧化钾的分析方法。该方法将催化剂样品和助溶剂四硼酸锂熔融后再用盐酸溶解定容,采用火焰原子吸收光谱仪对样品溶液进行测定。在优化的实验条件下,钾离子的质量浓度在0.05~0.50 mg/L范围内与吸光度呈良好线性关系,相关系数为0.9995。钾的方法检出限为0.001 mg/L,定量限为0.01 mg/L,测定结果的相对标准偏差为2.6%~4.3%(n=6),样品加标回收率为97.8%~102.3%。与HG/T 3543-2014中的酸溶制样法相比,该方法能够将催化剂样品中的难溶钾盐溶出,分析结果准确度更高,可用于天然气转化催化剂中氧化钾含量的测定。 相似文献
980.