中国古建筑的亲和力

从中国传统的自然观入手,对传统建筑的择址、用材、界面进行了分析,总结出中国古建筑的生命力在于建筑、人、自然三者之间的和谐统一.     

Synthesis and Structural Characterization of a New Cadmium(Ⅱ) Complex Bridged by Endo-norbornene-cis-5,6-dicarboxylic Acid

A polynuclear complex [Cd(endc)(H2O)]n·nH2O (endc = endo-norbomene-cis5,6-dicarboxylate anion) has been synthesized by the hydrothermal reaction of cadmium nitrate tetrahydrate with endo-norbomene-cis-5,6-dicarboxylic acid in 1:1 molar ratio,and structurally characterized by single-crystal X-ray diffraction.It crystallizes in monoclinic,space group P21/c with a = 1.16471(7),b = 0.95334(7),c = 0.91109(9) nm,Z = 4,V= 1.01035(14)nm3,Dc.= 2.160 g/cm3,μ= 2.172 mm-1,F(000) = 648,R =0.0302 and wR = 0.0752.According to structural analysis,each Cd(Ⅱ) ion is coordinated to six O atoms from three endc anions and one water molecule,giving a distorted octahedral geometry.Two- dimensional layer arrangement of the title complex is constructed from the bridging nature of endc.It is worth notice that adjacent two-dimensional layers are joined together to form a three-dimensional supramolecular framework via intermolecular hydrogen bonding interactions.     

NARROW-DISPERSED CROSSLINKED CORE-SHELL POLYMER MICROSPHERES PREPARED BY SURFACE-INITIATED ATOM TRANSFER RADICAL POLYMERIZATION＊

Grafting of polystyrene with narrowly dispersed polymer microspheres through surface-initiated atom transfer radical polymerization (ATRP) was investigated. Polydivinylbenzene (PDVB) microspheres were prepared by dispersion polymerization with poly(N-vinyl pyrrolidone) (PVP) as stabilizer. The surfaces of PDVB microspheres were chloromethylated by chloromethyl methyl ether in the presence of zinc chloride as catalyst to form chloromethylbenzene initiating core sites for subsequent ATRP grafting of styrene using CuCl/bpy as catalytic system. Polystyrene was found to be grafted not only from the particle surfaces but also from within a thin shell layer, resulting in the formation of particles size increased from 2.38-2.58μm, which can further grow to 2.93μm during secondary grafting polymerization of styrene. This demonstrates that grafting polymerization proceeds through a typical ATRP procedure with living nature. All of the prepared microspheres have narrow particle size distribution with coefficient of variation around 10%.     

SYNTHESIS AND THERMAL PROPERTIES OF POLYBENZOXAZOLE FROM SOLUBLE PRECURSOR WITH HYDROXY-SUBSTITUTED POLYENAMINONITRILE

Aromatic polybenzoxazole (PBO) precursor, hydroxy-substituted polyenaminonitrile, was prepared by direct polycondensation of 1,4-bis(l-chloro-2,2-dicyanovinyl)benzene (CCB) and 4,6-diaminoresorcinol dihydrochloride (DAR) using pyridine and N,N-dimethylacetamide as condensing agent and solvent. The precursor has good solubility in polar aprotic solvent which is due to the strong dipolar nature of the main chain. The soluble precursor was subjected to thermal cyclization in an inert atmosphere to convert it into the corresponding PBO, which has its 5% weight loss temperature at 540℃ The fully cyclized PBO were characterized by FT-IR and TGA. The introduction of 10% mol 1,3,5-benzenetricarboxylic chloride (BTC) into the main chain not only has little effect on the solubility of PBO precursor but also raises its 5% weight loss temperature to 552℃ and char yield at 700℃ for the cyclized PBO with BTC.     

铜试剂在有机合成中的应用研究进展

铜试剂催化的偶联反应是直接构建碳 碳键最有效的方法之一。本文综述了铜试剂催化的偶联反应构筑六种碳 碳键的方法;重点阐述了铜试剂催化构筑C(SP²)-C(SP²)的研究进展,含分子间偶联和分子内偶联。参考文献44篇。     

由教育产业化引发的思考

从教育属性、义务教育、城乡二元结构及教育产业化的危害等方面,阐述了教育是一种崇高的公益事业,应向一切能够接受教育的人提供教育,指出推行教育产业化违背了教育宗旨和办学方针,也损害了人民群众的利益。     

技术:从控制自然手段到被控制对象

技术在人们的认知和实践中一直是控制自然的手段。但随着全球性问题的加剧以及技术负面效应的突显,人们开始将技术作为被控制的对象。将技术作为被控制的对象,是历史发展的必然、是对技术异化的消解、是对人的主体性和工具理性反思的结果,也是技术哲学发展的最新阶段。将技术作为被控制的对象,有利于恢复文化与技术之间被破坏了的相互关系、缩短未来经济中的不确定性因素、响应人类未来命运的召唤、促进人的自由解放等。     

论邓小平社会主义本质论的理论创新

邓小平的社会主义本质论是中国特色社会主义理论的一项重大的理论创新。其真实理论意蕴和理论创新在于：在坚持社会主义制度的前提下追问社会主义社会的二级本质,用唯物史观的哲学原理深刻地揭示了社会主义制度的功能性本质,在更深层次上回答了＂什么是社会主义,怎样建设社会主义＂这一根本问题,把对社会主义的认识提高到新的科学水平,构筑了当代社会主义理论的重要基石。     

多元视角看自然: 论吴明益《复眼人》的艺术特色

吴明益的长篇小说《复眼人》延续了作者以往的自然书写，但又注入了他对环境议题更多元的思考。本文主要分析《复眼人》的艺术技巧，以及对比吴明益早期的同名短篇小说《复眼人》，了解吴明益观察世界的多元视角，以及他对生态理念和人性的深入探索。     

基于教育特质的教育理论重构——跨越教育理论与教育实践的鸿沟

理论与实践是必然统一的。目前教育理论与教育实践关系的脱离是因为教育理论的构建忽视了教育学科的独特学科性质。因此,重构适合教育学科独特性质的教育理论是联系教育理论与教育实践的关键。