大口径厚液膜毛细管柱的制备

制备出了内径从0.46～0.74mm、液膜厚度从0.9～5.6μm的SE-54大口径厚液膜玻璃毛细管柱,并对它们的性能进行了评价。对低沸点的C_1-C_4烃进行了初步分离。     

Thick Silicate Film by an Interfacial Polymerization

A thick silica gel film, corresponding to the glass film of 10–20 micron in thickness, has been formed at the interface between two immiscible liquids, hexane and water, using E-40, a partially polymerized silicon alkoxide, as the precursor. The film formation was possible using both acid- and base-catalyzed water, but was greatly dependent on the type of catalyst. Only the trace of a film was observed for the system catalyzed with a strong electrolyte such as HCl, HNO₃ or NaOH, while a gel film, corresponding to the glass film of several to 10 micron in thickness was formed with a weak electrolyte such as ammonia, organic acid like acetic acid, citric acid, etc., of similar pH value. The direct introduction of organic base catalyst like triethylamine in hexane was much more effective than the use of ammonia water, suggesting that the polymerization of E-40 to form a gel film takes place in the organic phase, where water molecules, as well as undissociated ammonia or organic acids, can diffuse in.     

The preparation of thick-film glass capillary columns

A detailed method for the routine preparation of glass capillary columns is presented. The method consists of coating a glass tube with quartz powder prior to pulling the tube into a capillary. The inner surface of the capillary consists of an even distribution of quartz particles fused to the walls. This surface has been found readily deactivated by standard procedures and ideal for the preparation of thick-film glass capillary columns. The method has been thoroughly tested in two independent laboratories to ensure that the procedures described are reproducible.     

用于焊缝跟踪的调制式红外光学传感器

叙述了一种以脉冲调制的红外光束为信号光源的焊缝跟踪传感器。通过对接 收信号的滤波及“自适应消噪”处理,可以有效地克服电弧光的干扰;利用光源的脉冲 驱动特性,加大了瞬时信号功率,改善了光学传感器对工件表面的适应性。传感器结构简 单、体积小、灵敏度高、能同时实现对焊缝在水平及高度两个方向的自动跟踪在埋弧 及明弧自动焊中均能准确地跟踪。     

夹层曲板在均匀轴向压缩下的稳定性

研究四边简支具有不等厚度表层的３层夹层曲板在均匀轴向压缩下的稳定性问题。方法采用广义变分原理和布勃诺夫－伽辽金法。     

综放开采在小峪3^#煤层应用的可行性研究

采用多因素分析综合评价方法,论证了在小峪３＾＃煤层应用综放开采是可行的,并提出了具体实施方案,对矿井生产及类似条件的煤层开发有指导借鉴意义。     

H2S-sensing properties of SnO2 produced by ball milling and different chemical reactions

In this work, the mechanochemical synthesis of a moderately agglomerated tin oxide (SnO₂) powders and the subsequent preparation of semiconductor gas sensors as prototypes, were studied. Tin (II) chloride (SnCl₂) powder was milled with calcium hydroxide (Ca(OH)₂) and potassium carbonate, (K₂CO₃) powder, respectively, in a ball mill at room temperature and in an air atmosphere. Heat treatment of milled mixtures at 400 °C resulted in the formation of a tetragonal phase, confirmed by X-ray diffraction (XRD). During milling in the presence of water, a high number of hydroxide (OH) groups are formed at the surface. When SnCl₂ was milled with K₂CO₃, no water was produced and the Fourier-transform infrared spectrum (FT-IR) of the powder has no surface hydroxyl deformations. On exposure to hydrogen sulfide (H₂S) gas, the particles, prepared from anhydrous powder, have higher sensitivity than these, prepared from hydrated powder. The SnO₂ thick film, prepared from anhydrous powder may be successfully applied to a H₂S gas sensor.     

大柳塔煤矿12305工作面覆岩活动规律的相似模拟

为了研究薄基岩浅埋煤层开采过程中覆岩活动规律,利用相似材料模型法,对大柳塔煤矿12305工作面进行了相似模拟实验,得出了薄基岩浅埋煤层开采过程中覆岩活动特点.结果表明,薄基岩浅埋煤层开采的覆岩活动规律与常规开采顶板活动规律存在根本区别,应该有其自身的开采理论指导现场生产.     

单面约束螺接中厚板弯曲弹塑性分析

根据薄壁结构中螺栓连接板件的支撑特点,基于Mindlin板横向剪切理论,考虑单面约束的接触作用,提出了螺接中厚板连接件承载能力的分析方法·对于两边支撑的线性硬化材料螺接板的弯曲进行了弹塑性有限元分析,以螺接区外缘应力进入塑性作为判据,给出了计算承载能力的方法,并通过试验(钛合金试件)得到了破坏载荷的实验值,验证了文中建议的分析方法的有效性·     

角焊缝弯扭计算的两类问题

利用已知弯扭力学模型和力学知识，对连接中角焊缝弯扭问题给出一套界定办法，使弯扭问题的判别变得明确清楚，从而解决了弯扭设计中的一些模糊问题。