全文获取类型
收费全文 | 10027篇 |
免费 | 1918篇 |
国内免费 | 1847篇 |
专业分类
化学 | 4314篇 |
晶体学 | 421篇 |
力学 | 655篇 |
综合类 | 77篇 |
数学 | 96篇 |
物理学 | 4800篇 |
综合类 | 3429篇 |
出版年
2024年 | 15篇 |
2023年 | 47篇 |
2022年 | 214篇 |
2021年 | 214篇 |
2020年 | 189篇 |
2019年 | 174篇 |
2018年 | 212篇 |
2017年 | 299篇 |
2016年 | 359篇 |
2015年 | 317篇 |
2014年 | 465篇 |
2013年 | 674篇 |
2012年 | 686篇 |
2011年 | 788篇 |
2010年 | 660篇 |
2009年 | 750篇 |
2008年 | 678篇 |
2007年 | 791篇 |
2006年 | 812篇 |
2005年 | 674篇 |
2004年 | 646篇 |
2003年 | 497篇 |
2002年 | 461篇 |
2001年 | 398篇 |
2000年 | 413篇 |
1999年 | 346篇 |
1998年 | 283篇 |
1997年 | 290篇 |
1996年 | 275篇 |
1995年 | 227篇 |
1994年 | 189篇 |
1993年 | 153篇 |
1992年 | 139篇 |
1991年 | 107篇 |
1990年 | 105篇 |
1989年 | 73篇 |
1988年 | 66篇 |
1987年 | 40篇 |
1986年 | 23篇 |
1985年 | 12篇 |
1984年 | 5篇 |
1983年 | 5篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
101.
K. M. A. Salam Hidekazu Konishi Masahiro Mizuno Hisashi Fukuda Shigeru Nomura 《Applied Surface Science》2002,190(1-4):88-95
Polycrystalline (1−x)Ta2O5−xTiO2 thin films were formed on Si by metalorganic decomposition (MOD) and annealed at various temperatures. As-deposited films were in the amorphous state and were completely transformed to crystalline after annealing above 600 °C. During crystallization, a thin interfacial SiO2 layer was formed at the (1−x)Ta2O5−xTiO2/Si interface. Thin films with 0.92Ta2O5–0.08TiO2 composition exhibited superior insulating properties. The measured dielectric constant and dissipation factor at 1 MHz were 9 and 0.015, respectively, for films annealed at 900 °C. The interface trap density was 2.5×1011 cm−2 eV−1, and flatband voltage was −0.38 V. A charge storage density of 22.8 fC/μm2 was obtained at an applied electric field of 3 MV/cm. The leakage current density was lower than 4×10−9 A/cm2 up to an applied electric field of 6 MV/cm. 相似文献
102.
MA Yunsheng ZHU Junfa Zhuang Shuxian JIANG Zhiquan ZHOU Weiping ZHAI Runsheng Bao Xinhe 《科学通报(英文版)》2002,47(14)
The preparation of SmOx/Rh(100) and CO adsorption on this model surface have been investigated with Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption spectroscopy (TDS). The oxygen adsorption on the SmRh alloy surface leads to the aggregation of Sm on the surface. The thermal treatment of this oxidized surface induces the further agglomeration of SmOx on the Rh(100) surface. Compared with CO TDS on the clean Rh(100) surface, three additional CO desorption peaks can be observed at 176, 331 and 600 K on the SmOx/Rh(100) surface. The CO desorption peak at 176 K may originate from CO adsorbed on SmOx islands, while the appearance of the CO adsorption peaks at 331 and 600 K, depending on the oxidation state of Sm, is attributed to CO species located at the interface of SmOx/Rh(100). 相似文献
103.
我们用离子团束-飞行时间质谱(ICB-ToFMS)系统制备了金(Au)超微粒子-聚乙烯(PE)薄膜和C_(60)-聚乙烯薄膜。用透射电子显微镜(TEM)分析了所制备的样品。它们的结构是Au超徽粒子镶嵌在多晶的PE薄膜中,其中Au原子团呈球形,直径分布在2.0-5.0nm窄范围内,当沉积基底温度为90℃时,Au原子团相互靠近,几乎连接起来,但仍保持原来大小。基底温度为140℃蒸积的C_(60)-pE薄膜具有晶态结构,其晶格常数为1.454nm。 相似文献
104.
D.A. Mazón-Montijo M. Quevedo-López H.N. Alshareef R. Ramírez-Bon 《Applied Surface Science》2007,254(2):499-505
We study the initial growth stages of CdS thin films deposited by an ammonia-free chemical bath deposition process. This ammonia-free process is more environmentally benign because it reduces potential ammonia release to the environment due to its high volatility. Instead of ammonia, sodium citrate was used as the complexing agent. We used atomic force microscopy (AFM), Rutherford backscattering (RBS) and X-ray photoelectron spectroscopy (XPS) to investigate the morphological and chemical modifications at the substrate surface during the first initial stages of the CdS deposition process. Additionally, X-ray diffraction (XRD) and optical transmission spectroscopy measurements were carried out to compliment the study. XPS results show that the first nucleation centers are composed by Cd(OH)2 which agglomerate in patterns of bands, as demonstrated by AFM results. It is also observed that the conversion to CdS (by anionic exchange) of the first nucleus begins before the substrate surface is completely covered by a homogenous film. 相似文献
105.
用化学气相沉积法制备碲薄膜,其步骤为:通过电化学方法制得碲化氢,碲化氢在室温下分解后在聚乙烯塑料箔上沉积得到碲薄膜.用傅里叶红外光谱仪、紫外/可见/近红外光谱仪、X射线衍射仪及扫描电镜表征碲薄膜的光学性能和结构.结果表明,化学气相沉积法在Mn-O覆盖的聚乙烯塑料箔上沉积得到的碲薄膜在大气窗口(8~13μm)光谱区域具有很高的透过率,同时能阻挡几乎所有的太阳光谱,表明碲薄膜是适用于辐射制冷装置的太阳光辐射屏蔽材料. 相似文献
106.
107.
研究以水泥处理固体有机物时,有机物对水泥水化的影响。以膜流模式说明水份在水泥浆体内传输的现象。水膜存在半干之水泥浆体,其厚度小于100nm,膜流由离分压所驱动,而离分压来自分子间作用力。膜拟结果发现,水泥浆体内局部位置可用以进行水化之水量为Q=-Aslv/6vπ。当有机物添加在水泥浆体内时,会影响Hamaker常数,Aslv因此可能使膜流不稳定或完全抑制膜流,因而使水泥浆体内局部缺水,影响水化进行,造成成品强度降低,影响品质。 相似文献
108.
Katsumasa Iwai Yi-Wei Shi Mitsunobu Miyagi Yuji Matsuura 《Optics & Laser Technology》2007,39(8):1528-1531
An improved coating method was proposed in order to form a uniform polymer layer in the fabrication of cyclic olefin polymer-coated silver (COP/Ag) hollow fiber. A COP solution was flowed in a closed loop, in which the silver-coated tube was used as a part of the loop. Owing to the constant flowing speed of the COP solution and the airtight flowing environment, a COP layer was uniformly formed. The hollow fibers attain high performance and deliver multi-wavelength laser light from the infrared to the visible simultaneously. The method was successfully applied to the fabrication of practical hollow fibers with 2 m length for the near and mid-infrared lasers. 相似文献
109.
本文建立了高效有机吸附膜吸附数学模型,并与实验数据进行了比较,发现模型的数值计算结果与实验值基本相符,本模型具有较高的实用价值。 相似文献
110.
提出了单层光学薄膜中薄膜与衬底反射光之间的双重干涉效应的理论,实验结果证实了理论分析的正确性。双重干涉效应使薄膜-衬底体系的热致反射调制度高达80%,这一效应可望有极广泛的应用 相似文献