MEKC determination of vanadium from mineral ore and crude petroleum oil samples using precapillary chelation with bis(salicylaldehyde)tetramethyl‐ethylenediimine

An analytical procedure has been developed for the separation of Cu(II), Ni(II), Co(II), Fe(II), Pd(II), Th(IV), V(IV), and determination of Fe(II), Co(II), Ni(II), and V(IV) by MEKC after chelation with bis(salicylaldehyde)tetramethylethylenediimine (H₂SA₂Ten). Uncoated fused silica capillary was used with an applied voltage of 30 kV with photo‐diode array detection at 228 nm. SDS was added as micellar medium at pH 8.2 with sodium tetraborate buffer (0.1 M). Linear calibrations were established within 0.015–1000 μg/mL of each element with LOD within 5–67 ng/mL. The method was applied for the determination of vanadium from crude oil and ore samples in the range 0.34–2.40 and 114.2–720.7 μg/g with RSD 1.7–3.8 and 0.98–2.30% (n = 3), respectively. Fe, Ni, and Co present in crude oil and ore samples were also determined with RSD 1.3–2.8, 1.1–4.1, and 1.2–3.5% (n = 3), respectively. The results were compared with that of supplier's specifications and atomic absorption spectrometry (AAS). Method was evaluated by standard addition technique.     

Application of C5-C13 light hydrocarbons in depositional envlrOnment diagnosis

Based on the geological background and Gammacerane/C31H(S+R)ratios,source rock depositional environments of the studied oil samples(194)from 13 oilfields were classified into three groups according to salinity:saline-lacustrine facies,fresh to brackish lacustrine facies(including linmetic facies),and semi-saline to saline facies(including marine facies of the Tarim Basin).C5-C13 compound groups in the crude oils were separated by GC,and about 286 compounds were qualitatively analyzed.The geochemical application of the C6-C13 compound groups and their ratios between each group with individual carbon number was investigated.Our studies show that(1)C6-C13 compound groups and their ratios in the crude oils could serve as new reliable parameters for oil-oil correlation because the C6-C13 light fractions are the major oil component,especially in light oil or condensate,in which they account for almost 90%of the whole oil;(2)the compound groups of C7 light hydrocarbons in oils derived from different depositional environments with different salinity have different characteristics;(3)C6-C13 compound groups and ratios may be affected by other factors such as maturity,but they are mainly controlled by salinity of depositional waters.     

基于缩减到53(20-72)步的SHA-1的H2-MAC的等价密钥恢复攻击

H2-MAC是Kan Yasuda在ISC 2009上提出的一种新型的MAC结构,与HMAC的不同之处仅在于H-MAC用固定的常数IV代替HMAC的外部密钥,计算MAC值时只访问一次种子密钥,在保持HMAC优势的基础上简化密钥管理。文中首次给出基于缩减到53 (20-72)步的SHA-1的H2-MAC的等价密钥恢复攻击,并进行一般性伪造攻击的理想复杂度。     

低功耗互补传输门绝热逻辑和时序电路的设计

研究了采用二相非交叠功率时钟的绝热触发器及时序电路的设计，介绍了采用二相无交叠功率时钟的互补传输门绝热逻辑（CPAL）电路，并分析了其工作原理．该电路利用nMOS管自举原理对负载进行全绝热驱动，从而减小了电路整体功耗，且CPAL能耗几乎与工作频率无关．提出了性能良好的低功耗绝热D、T和JK触发器，并与其他几种绝热触发器进行功耗比较．给出了绝热时序电路的一般设计方法，并作为实例采用应用绝热D触发器设计了十进制计数器．SPICE程序模拟表明：设计的电路具有正确的逻辑功能及低功耗的优点．     

气相色谱-质谱法分析橡苔浸膏中的挥发性化学成分

用挥发油提取器提取橡苔浸膏中的挥发油 ,利用气相色谱 -质谱法 ( GC- MS)分析了其中的化学成分 ,采用GC峰面积归一化法定量 ,鉴定出 2 4种化合物 ,共占挥发油总量的 83%以上     

采用分段喷油改善柴油机排放的研究

用分段喷油器实行发段射油以改变喷油特性，使喷油的初期速率降低，而在喷油持续期内逐渐升高，这样使燃烧初期放热率减而随后逐渐加快，从而可以改善柴油机的排放并降低燃油的消耗率，对使用分段喷油器的喷射规律作了研究并在单缸试验机上进行了试验，试验表明，采用分段喷射装置后在微粒未增加的情况下，ＮＯｘ有所降低。     

密立根油滴实验的微机数据处理

本文论述了密立根油滴实验中数据处理的计算机算法。用计算机运算快且准确的特点，通过寻找误差最小值，求最大公约数的方法，得到电子的电荷值ｅ。     

管道流体的瞬态仿真模型

通过对管道的离散化处理 ,建立了流体管道频率相关摩擦仿真模型 ;研究了N的取值、离散管段数对仿真结果的影响及管道与集中元件和扰动激励的耦合方法 ,并对带容腔的流体管道系统进行了数字仿真 .结果表明 ,该模型将管道的分布特性表示成网络形式 ,可方便地与各种边界条件进行耦合 ;仿真结果与有关文献提供的近似解析计算和实验结果吻合良好     

基本电荷的测定及近十年来对基本电荷的质疑

随着对物质结构更深层次的研究，人们重拾“油滴实验”，介绍利用超导铌球、测量剩余电荷的实验，指出寻找分数电荷的可能性。     

千山核桃叶中挥发油成份分析

利用水蒸汽馏方法提取了辽宁千山核桃叶中的挥发油，用毛细管ＧＣ／ＭＳ法从核桃叶的挥发油中分离鉴定了３２种化合物，占总量的７９．０９％。