油气两相流流过弯管的局部阻力特性研究

以油气、气水为工质，对进口水平、出口垂直向上的９０弯管内气液两相流局部阻力特性进行了实验研究．弯管内径４５ｍｍ、弯曲半径为３００ｍｍ．根据实验结果，总结出了气水、油气两相流体流过弯管时的局部阻力变化规律，并与前人的结果进行了比较．重新提出了统一的弯管局部阻力计算公式，计算值和实验值符合良好．     

野生和人工栽培窄裂缬草香精油的GC/MS分析对比研究

应用GC／MS分析对比研究野生和人工栽培香料植物窄裂缬草香精油，分别鉴定出38个和29个化合物，两种香精油其相同组分20个，主成分基本相同，为窄裂缬草开发利用建立原料栽培基地，保证其香精油工业化生产提供依据。     

用正交试验法选择劣化变压器油脱色的最佳条件

本文讨论用活化硅胶处理劣化变压器油的净化效果。用正交试验法选出脱色的最佳工艺条件。     

A first high enantiocontrol of an asymmetric tertiary carbon center attached with a fluoroalkyl group via Rh(I)-catalyzed conjugate addition reaction

Treatment of fluoroalkylated electron-deficient olefins with various boronic acids in the presence of a catalytic amount of Rh(I) coordinated with (S)-BINAP in toluene/H₂O at the reflux temperature for 3 h gave the corresponding conjugate addition products with high enantioselectivity in high yields.     

Diffusion-Ordered Spectroscopy (DOSY) as a Powerful NMR Method to Investigate Molecular Mobilities and Intermolecular Interactions in Complex Oil Mixtures

Studying the characteristics and molecular mechanisms of liquid self-diffusion coefficient and viscosity changes is of great significance for, e. g., chemical and petroleum processing. As examples of highly complex liquid,an asphaltene-free high-acid and high-viscosity crude oil and its extracted fractions were studied by comparing their ¹H DOSY diffusion maps. The crude oil exhibited a polydisperse diffusion distribution, including multiple diffusion portions with diffusion coefficients much smaller than that of any single fraction in independent diffusion. The main mechanism that leads to the decreases in the diffusion coefficients of crude oil is attributed to diffusion resistance enhanced by Dynamical Molecular-Interaction Networks (DMINs), rather than by enlargement of the diffusion species caused by molecular aggregation. Constructed through the synergistic interactions of various polar molecules in crude oil, DMINs dynamically bind polar molecules, trap polarizable molecules, and spatially hinder the free motion of non-polar molecules. Overall, this reduces the mobility of all molecular species, as illustrated by the decreased diffusion coefficients. This study demonstrates that DOSY is a powerful NMR method to investigate molecular motion abilities also in complex mixtures. In addition, the insights in the influence of the interaction matrix on the molecular mobility also help to understand the contribution of “structural viscosity” to the viscosity of heavy oil.     

松辽盆地北部扶-杨油层污染因素浅析

讨论了污染松辽盆地北部扶－杨油层的根本原因。地质因素主要是水敏，由间层粘土矿物引起；工程因素与泥浆浸泡时间有关：两者都与膨胀性的蒙皂石层有关。     

Implicit finite element methods for two-phase flow in oil reservoirs

The equations governing immiscible, incompressible, two-phase, porous media flow are discretized by generalized streamline diffusion Petrov–Galerkin methods in space and by implicit differences in time. Systems of non-linear algebraic equations are solved by Newton–Raphson iteration employing ILU-preconditioned conjugate-gradient-like methods to the non-symmetric matrix system in each iteration. The resulting solution methods are robust, enable complex grids with irregular nodal orderings and allow capillary effects. Several numerical formulations are tested and compared for one-, two- and three-dimensional flow cases, with emphasis on problems involving saturation shocks, heterogeneous media and curved boundaries. For reservoirs consisting of multiple rock types with differing capillary pressure properties, it is shown that traditional Bubnov-Galerkin methods give poor results and the new Petrov–Galerkin formulations are required. Investigations regarding the behaviour of several preconditioned conjugate-gradient-like methods in these type of problems are also reported.     

石香薷挥发油化学成分研究

本文用气相色谱、气相色谱-质谱-计算机联用仪、红外光谱、核磁共振谱等方法研究了石香薷挥发油的化学成分,在已分析的36个成分中鉴定了其中的31个化合物,占挥发油总量的95.46％。它们是:α—蒎烯、异戊酸异丁酯,α—菲兰烯,对—伞花烃,γ—萜品烯,萜品—4—醇,百里香酚,香荆芥酚,甲基丁子香酚,甲基黑椒酚,α—反式—香柠檬烯,瑟林烯,橙花叔醇,β—红没药烯等.其中百里香酚含量为24.56％,香荆芥酚的含量达43.22％。     

圈闭含油气性信息灰色聚集ART网络聚类评价法

对某地托库测区 1 0种物探综合信息 ( 72× 2 4× 1 0 )进行油气圈闭性评价 ,采用信息灰色聚集法压缩信息形成灰色聚集样本属性 ,采用 ART网络聚类法自动对聚集信息进行聚类分析 ,达到圈闭含油气性评价的目的 .该方法具有智能化程度和可信度较高的特点