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91.
Shasha Song Haiqiao Wang Prof. Dr. Aixin Song Prof. Dr. Shuli Dong Prof. Dr. Jingcheng Hao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(29):9063-9072
The aggregation behavior of mixtures of the alkaline amino acid L ‐Arginine (L ‐Arg) and bis(2‐ethylhexyl)phosphoric acid (DEHPA) in water was studied in detail. At a fixed L ‐Arg concentration, a phase sequence of micellar phase (L1 phase), vesicle phase (Lαv phase), planar lamellar phase (Lαl phase), and sponge phase (L3 phase) was obtained with increasing DEHPA concentration due to changes in the packing parameter. The phase transition of the lamellar structures was determined by freeze‐fracture TEM and 2H NMR spectroscopy. Rheological measurements reflected the phase transition through significant variations of both the elastic modulus and the viscous modulus. Porous CeO2 materials were produced by utilizing the L3 phase as template, and the porous CeO2 exhibited excellent catalytic oxidation activity toward CO due to its high surface area, which provides more active sites for CO conversion. 相似文献
92.
Tobias Grewe Xiaohui Deng Dr. Harun Tüysüz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(25):7692-7697
A systematic study on the growth of Cr2O3 in three‐dimensional cubic ordered mesoporous silica (KIT‐6) and its replication through nanocasting is reported. By changing the loading time and amount of precursor, the size and shape of the obtained replica could be controlled to some extent. More interestingly, in contrast to previously published studies, when KIT‐6 with an aging temperature of 100 °C, which has a high degree of interconnectivity, was used as a hard template, a cubic ordered mesoporous Cr2O3 replica with an open uncoupled subframework structure and reduced symmetry was obtained. Formation of a replica with different symmetry and uncoupled subframework structure is not only related to the degree of interconnectivity of the parent, but also strongly depends on the type of metal oxide and its growth mechanism in the silica template. Nanocasting of Cr2O3 with a low loading results in a replica with monomodal pore size distribution that has same symmetry as the hard template, whereas increasing the loading amount alters the symmetry of the replica and yields a replica with bimodal distribution. 相似文献
93.
Prof. Ashok R. Patel Nick Cludts Mohd Dona Bin Sintang Benny Lewille Ans Lesaffer Prof. Koen Dewettinck 《Chemphyschem》2014,15(16):3435-3439
The preparation and characterization of oleogels structured by using a combination of a surface‐active and a non‐surface‐active polysaccharide through an emulsion‐templated approach is reported. Specifically, the oleogels were prepared by first formulating a concentrated oil‐in‐water emulsion, stabilized with a combination of cellulose derivatives and xanthan gum, followed by the selective evaporation of the continuous water phase to drive the network formation, resulting in an oleogel with a unique microstructure and interesting rheological properties, including a high gel strength, G′>4000 Pa, shear sensitivity, good thixotropic recovery, and good thermostability. 相似文献
94.
In the present work,an interconnected sandwich carbon/Si-SiO2/carbon nanospheres composite was prepared by template method and carbon thermal vapor deposition(TVD).The carbon conductive layer can not only efficiently improve the electronic conductivity of Si-based anode,but also play a key role in alleviating the negative effect from huge volume expansion over discharge/charge of Si-based anode.The resulting material delivered a reversible capacity of 1094 mAh/g,and exhibited excellent cycling stability.It kept a reversible capacity of 1050 mAh/g over 200 cycles with a capacity retention of 96%. 相似文献
95.
以Si-MCM-41为硬模板,利用介孔材料的吸附作用,将Fe3+和Ni 2+按一定比例定量吸附组装到介孔材料的孔壁上;然后通过程序升温在900℃条件下高温焙烧,并经氢氟酸处理,得到直径大约为3.0nm的中空铁氧体纳米管.分别利用傅立叶变换红外光谱仪、扫描电镜、透射电镜、X射线衍射仪分析了合成材料的结构、组成、形貌;采用振动样品磁强计测定了其磁性能.结果表明,合成的镍铁氧体纳米管具有良好的管状形貌,其结构与分子筛MCM-41的结构相似,并具有良好的磁学性能.这说明MCM-41分子筛孔道结构具有可复制性,本研究可望为制备具有适当长径比的一维纳米磁性材料打下良好基础. 相似文献
96.
We report two anion-templated Ag40 clusters, [Ag40(E)4(SO4){S2P(OEt)2}24](PF6)6 (E = S, 1 ; Se, 2 ). The anionic templates were generated in situ from the decomposition of dithiophosphate (dtp) ligands. The extrusion of sulfur undergoes disproportionation reactions to generate sulfide and sulfate anions, which provide the source of templates in the subsequent cluster assembly reactions. Two Ag40 clusters display high similarity in their structures. The sulfide (selenide) anions and the central sulfate anion reveal a six-coordinate and a rare dodecametallic dodecaconnective pattern, respectively. Four near-equivalent [Ag10(E){S2P(OEt)2}6]2+ motifs were assembled via the connection of central sulfate anion to construct Ag40 clusters. The cluster cation, [Ag40(E)4(SO4){S2P(OEt)2}24]6+, displayed in T symmetry, is unprecedented in anion-templated silver clusters. 相似文献
97.
In this work, a novel electrochemiluminescent (ECL) pesticide sensor based on zinc oxide nanocrystals decorated nickel foam is proposed for determination of imidacloprid for the first time. The silica film was used as a morphology‐controlling factor for modification of the electrode with zinc oxide nanocrystals. Zinc oxide was selected as luminescent material due to its cheapness, non‐toxicity, high thermal stability and excellent luminescence properties which truly adhered on the surface of nickel foam. The K2S2O8 was used as strong co‐reactant for this purpose. The silica template plays an important role in controlling the size of ZnO nanocrystals. The Physical morphology of the ZnO/Ni‐foam electrode was performed by electrochemical impedance spectroscopy, Brunauer‐Emmett‐Teller (BET), X‐Ray diffraction analysis, field emission scanning electron microscopy, and energy‐dispersive X‐ray analysis. The ultra‐sensitive electrochemiluminescence method was successfully used for ultra‐trace determination of imidacloprid. The linear dynamic range and low detection limit were obtained 3×10?14 ?8×10?8 M and 4.4×10?15 M, respectively. Also, the relative standard deviation for 15 repetitive optical signals was calculated 1.09 %.The present ECL sensor exhibited superior performance toward the accurate determination of imidacloprid with good reproducibility and stability. 相似文献
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100.
刘荷花 《重庆大学学报(自然科学版)》2011,34(12):109-114
针对NativeXML数据存储性能不高、支持查询和更新效率低等不足,提出一种新的半结构化信息存储模型WNXD。引入动态倒排技术和数据映像机制,将记录和分页的存储模式相结合,建立3种结构化索引,用不同方法解决了结构化和动态增长的矛盾。创建了实用的存储模型,提供了从整体到局部,从元素、属性到具体值的全面覆盖访问策略,底层的数据存取,尤其是内容混杂的各类形式异构数据的有效性和完整性存取,得到了最大程度保证,查询次数减小了I/O,提高了系统处理性能。 相似文献