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21.
The motivation of this work is to provide reliable and accurate modeling studies of the physical (surface, thermal, mechanical and gas diffusion) properties of chitosan (CS) polymer. Our computational efforts have been devoted to make a comparison of the structural bulk properties of CS with similar type of polymers such as chitin and cellulose through cohesive energy density, solubility parameter, hydrogen bonding, and free volume distribution calculations. Atomistic modeling on CS polymer using molecular mechanics (MM) and molecular dynamics (MD) simulations has been carried out in three dimensionally periodic and effective two dimensionally periodic condensed phases. From the equilibrated structures, surface energies were computed. The equilibrium structure of the films shows an interior region of mass density close to the value in the bulk state. Various components of energetic interactions have been examined in detail to acquire a better insight into the interactions between bulk structure and the film surface. MD simulation (NPT ensemble) has also been used to obtain polymer specific volume as a function of temperature. It is demonstrated that these V–T curves can be used to locate the volumetric glass transition temperature (Tg) reliably. The mechanical properties of CS have been obtained using the strain deformation method. Diffusion coefficients of O2, N2, and CO2 gas molecules at 300 K in CS have been estimated. The calculated properties of CS are comparable with the experimental values reported in the literature. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1260–1270, 2007 相似文献
22.
二十多年来学术界关于《淮南万毕术》“夏造冰”问题的讨论颇具戏剧性.1983年洪震襄否定了这种可能性,十年之后李志超、赵虹君的相关研究得出了相反的结果.2004年厚宇德研究了李、赵肯定说实验方案,得到出乎意料的相反结论.本文根据原文提出一个新的技术思路,按此思路,则有可能实现“夏造冰”.实际操作中能不能达到预想的目标,还有待于实验验证. 相似文献
23.
24.
The effect of the temperature factor, that is, the ratio of the body temperature to the freestream stagnation temperature, on the structure of the separated flow formed in the presence of a concave corner in a supersonic stream is studied. The strong influence of the temperature factor on the separation zone length and the flow-generated aerodynamic characteristics is established. It is shown that for fairly large deflection angles this flow cannot be described by free interaction, or triple deck, theory. 相似文献
25.
Most adhesives and binders, including bitumen for asphalt mixture production, are presently produced from petrochemicals after
the refining of crude oil. The fact that crude oil reserves are a finite resource means that in the future, it may become
necessary to produce these materials from alternative and probably renewable sources. Suitable resources of this kind may
include polysaccharides, plant oils and proteins. This paper deals with the synthesis of polymer binders from monomers that
could, in future, be derived from renewable resources. These binders consist of polyethyl acrylate (PEA) of different molecular
weight, polymethyl acrylate (PMA) and polybutyl acrylate (PBA), which were synthesised from ethyl acrylate, methyl acrylate
and butyl acrylate, respectively, by atom transfer radical polymerisation. The rheological properties of these binders were
determined by means of oscillatory testing using a dynamic shear rheometer and combinations of stress/strain, temperature
and frequency sweeps. The results indicate that PEA can be produced to have rheological properties similar to that of ‘soft’
100/150 penetration grade bitumen, PMA with similar rheological properties to that of ‘hard’ 10/20 penetration grade bitumen,
while PBA, due to its highly viscous nature and low dynamic moduli, cannot be used on its own as a binder. The synthetic polymers
were found to be thermo-rheologically simple, and the shift factors, used to produce the dynamic moduli master curves, were
found to fit an Arrhenius function. 相似文献
26.
本文介绍了数字式温度传感器的工作原理、性能特征以及如何在冰箱检测系统中引入单总线技术,使用数字式温度传感器更好的实现温度的采集。 相似文献
27.
曾良才 《武汉科技大学学报(自然科学版)》1996,(4)
从降低液压试验台温控系统的成本而又保证温控精度出发,分析影响温控精度提高的主要因素,提出了采用串级双闭环负反馈的温控方案,并应用辨识技术获得了被控对象的较精确的数学模型,通过两级校正,使温控精度达到了50±1℃。 相似文献
28.
在饲育温度条件下研究了S.decipiens的生长和产仔数及与饲育水温的关系。结果表明水温在上升期和下降期,新生贝和稚贝的生长速度较快,产仔数也较多.成体贝在水温11℃~29℃时,都可产出新生贝,以18℃~24℃时产出较多.在高温饲育条件下,成体贝的生长速度缓慢。 相似文献
29.
以内燃机排气-固体吸附制冷系统为背景,建立了固体吸附制冷系统发生器瞬态温度场数值计算模型,并讨论模型中涉及的部分物性参数。通过实验验证,该模型能较好地模拟发生器内瞬态温度场。 相似文献
30.
探讨了用涂层的高温透气性的变化率评价涂层自愈合性的实验方法,研究了涂层高温自愈合能力的可能性,并用该方法研究了玻璃质涂层的高温自愈合性能. 相似文献