线性系统参数估计的改进凸多面锥法

文章对现有的凸多面锥法进行了改进．改进方法采用旧凸多面锥的边的凸组合来求新多面锥的新边,从而提高了算法的稳定性．并且将凸多面锥算法扩展到输出误差模型的参数估计上．仿真算例验证了改进方法的有效性．     

热动力学研究的时间参量法(Ⅲ)——简单级数反应的热谱面积比法

根据热导式量热计的理论基础——Ｔｉａｎ′ｓ方程,将时间作为已知参量,提出了一种新的热谱数据解析方法——简单级数反应的热谱面积比法．应用该法研究了几种简单反应的热动力学,实验结果验证了热谱面积比法的正确性．     

警告参数计算公式的推导

由警告参数的意义出发,计算实际应答反应与理想应答反应两种情况下有关变量间的协方差,从而导出了警告参数的计算公式。其结果与日本学者的研究结果相符合。     

异步DS—CDMA系统中传输时延估计

在异步ＤＳ＿ＣＤＭＡ系统中,由于“远－近”问题的影响,给系统参数（传播时延、幅度变化、相位变化）的估计带来很大的不利．本研究探讨了存在“远－近”问题情况下,异步ＤＳ＿ＣＤＭＡ系统中的参数估计问题,并提出了一种有效算法．     

广义分布参数变结构系统的不变性条件

首次研究了广义分布参数系统的不变性条件,利用特征向量函数法将广义分布参数系统化为一广义系统,证明了它们的不变性条件是等价的,同时也指正了某些文献个别结论和证明．     

构件预挤压孔的工艺弹塑性和残余应变分析方法

在对工艺应力进行理论分析的基础上,提出了一种构件预挤压孔的工艺弹塑性和残余应变分析方法,通过采用释放残余应变的方法和单光束激光散斑干涉术,分析了三种不同挤压量带孔铝板的预挤压孔对称面上的残余应力,验证了这种分析方法的可行性。     

MCP平均增益参数的快速估算法

该文利用“MCP综合特性测试分析仪”测得的G—V特性曲线结合运用E.E.Eberhardt的MCP增益模型提出一种对MCP平均增益参数的快速估算方法。可在G—V测试结果的基础上,通过计算得出MCP的各种增益参数和工作参数。这对MCP的研制和应用是很有意义的。     

Langevin dynamic simulation of hysteresis in a field-swept Landau potential

Numerical simulations are done of Langevin dynamics for a uniform-orderparameter, field-swept Landau model,= –|a/2|m ²+|b/4|m ⁴–mh(t) , to study hysteresis effects. The field is swept at a constant rateh(t)=h(0)+ht. The stochastic jump values of the field {h_J from an initially prepared metastable minimumm(0) are recorded, on passage to a global minimum m(). The results are: (a) The mean jump¯h _J(h) increases (hysteresis loop widens) with h, confirming a previous theoretical criterion based on rate competition between field-sweep and inverse mean first-passage time (FPT); (b) The broad jump distribution(h _J,h) is related to intrinsically large FPT fluctuations ( ²–²)/ ² O(1), and can be quantitatively understood. Possible experimental tests of the ideas are indicated.     

Self aggregation of binary mixtures of sodium dodecyl sulfate and polyoxyethylene alkyl ethers in aqueous solution

The mixed micelles of sodium dodecyl sulphate (SDS) with Brij35 and Brij 97 were studied separately by fluorescence measurement using pyrene as fluorescent probe. In the range of 0–1.0 mole fraction (X) of added SDS to Brij solutions, the cmc value of the mixed micelles varies from 0.085 to 8 mmol with Brij 35 and 0.04 to 8 mmol with Brij 97. The aggregation number also changes. A measure of the stability of mixed micelles is also presented. The interaction parameter ₁₂ and the chain–chain contribution parameter (B₁) are extracted from the analysis of the results. This parameter B₁ is related to the standard free energy change associated with the introduction of one ionic species into a nonionic micelle coupled with the release of one nonionic species from the micelle. The clouding behaviour of Brij 97 in the presence of SDS was investigated and the associated thermodynamic parameters of clouding were generated and discussed.     

Thermodynamic parameters of interaction of HC1 with alcohols in water Ⅲ.HCl-ethanol-water system at 278.15-318.15 K

Pt,H2(g,p0)HCl(mE)|AgCl-AgPt, H2(g, p0)|HCl(mE), EtOH(mN)|AgCl-Ag have been measured at 10 degree intervals from 278.15 to 318.15 K, where EtOH refers to ethanol, mE=0.005-0.1 mol.kg-1, mN=0.4-1.0 mol.kg-1. The salting constant kS of EtOH by HCl and the thermodynamic parameters of interaction, fEN(gEN> hEN, sEN] cP,EN)> of EtOH with HCI in water have been evaluated. It has been shown that kS>0, gEN>0,hEN>0, SEN>0 ,and cp,EN<0.The signs of these parameters and the temperature dependence of them have been discussed on the basis of structural interaction and the group additivity models.