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31.
Yaron Paz Ellina Kesselman Lulu Fahoum Irina Portnaya Ory Ramon 《Journal of Polymer Science.Polymer Physics》2004,42(1):33-46
The effect of two strong salting-out salts (Na2SO4 and K2SO4) on the temperature-induced phase-separation process in aqueous solutions of poly(N-isopropylacrylamide) (PNIPA) was examined by attenuated total reflectance/Fourier transform infrared spectroscopy, differential scanning calorimetry, and viscosity measurements. On the basis of these measurements, a detailed scenario of the phase-separation process was deduced. The phase-separation scenario of solutions containing PNIPA and water was altered in the presence of sulfate ions. Here, the sulfate ions induced partial intrachain collapse, manifested by a relatively compact structure well below the lower critical solution temperature. This led to a more gradual, smooth phase transition, with temperature-resolved intrachain collapse and interchain aggregation and a lesser extent of hysteresis. Although at the macrolevel one may not be able to differentiate among various scenarios altering the solvent into a poor solvent, the aforementioned microlevel measurements provided a way to expose the difference between raising the temperature and adding cosolutes. Follow-up studies on the effect of salting-in salts will be presented. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 33–46, 2004 相似文献
32.
Behavior of cellulose in NaOH/Urea aqueous solution characterized by light scattering and viscometry
Cellulose was dissolved in 6 wt % NaOH/4 wt % urea aqueous solution, which was proven by a 13C NMR spectrum to be a direct solvent of cellulose rather than a derivative aqueous solution system. Dilute solution behavior of cellulose in a NaOH/urea aqueous solution system was examined by laser light scattering and viscometry. The Mark–Houwink equation for cellulose in 6 wt % NaOH/4 wt % urea aqueous solution at 25 °C was [η] = 2.45 × 10?2 weight‐average molecular weight (Mw)0.815 (mL g?1) in the Mw region from 3.2 × 104 to 12.9 × 104. The persistence length (q), molar mass per unit contour length (ML), and characteristic ratio (C∞) of cellulose in the dilute solution were 6.0 nm, 350 nm?1, and 20.9, respectively, which agreed with the Yamakawa–Fujii theory of the wormlike chain. The results indicated that the cellulose molecules exist as semiflexible chains in the aqueous solution and were more extended than in cadoxen. This work provided a novel, simple, and nonpollution solvent system that can be used to investigate the dilute solution properties and molecular weight of cellulose. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 347–353, 2004 相似文献
33.
本文首先提出逆(反)对策这一新问题,给出了数学模型;探讨了“奇门遁甲”预测理论(术)中的数学问题;通过系统分析“专门遁甲”预测过程,可知它的预测过程隐含着一个特殊的逆(反)对策问题;最后指出逆(反)对策问题的广泛存在并给出案例分析. 相似文献
34.
35.
宫立波 《广西民族大学学报》1996,(1)
作者认为,引起个体应激反应的因素来自内部和外部两个方面.就当代中国而言,青年的应激反应主要是适应性反应.这种适应性反应的外部因素则集中表现在新的价值观念的冲突,竞争加剧,社会分配不公,生活节奏加快,家庭与学校的精神保健职能出现偏差.以及科学和技术的变革速度加快等六个方面.为了培养和提高青年的应激反应能力,作者提出了五个方面的措施,以指导青年建立适宜应激水平. 相似文献
36.
用气相色谱的分析方法研究了理想非线性单组分不同温度下的流出曲线,用"特征点"法回归出了各组分的物理常数G和b,代入理论模型公式,并与实验结果进行子比较。 相似文献
37.
H.-J. Sue E. I. Garcia-Meitin N. A. Orchard 《Journal of Polymer Science.Polymer Physics》1993,31(5):595-608
The fracture behavior of a core-shell rubber (CSR) modified epoxy is investigated using both fracture mechanics and microscopy tools. The CSR-modified epoxy is found to be toughened via numerous line-array cavitations of the CSR particles, followed by plastic flow of the epoxy matrix. The toughening effect via the above craze-like damage process is found to be as effective as that of the well-known widespread rubber cavitation/matrix shear yielding mechanisms. The conditions for triggering the craze-like damage appear to be both stress state and rubber concentration dependent. The type of rubber tougheners utilized also plays a critical role in triggering this rather unusual craze-like damage in epoxy systems. © 1993 John Wiley & Sons, Inc. 相似文献
38.
39.
Su Yongqing 《中国工程科学》2006,4(1):52-55
The relation between microwave conductivity and normal conductivity of solution is compared in this thesis. By building mathematical model and theoretical analyses, it indicates that the relationship of in situ conductivity of solution in microwave field and temperature is similar to that in non-microwave field. It can be expressed by quadratic equation but the values of both conductivities are different. Microwave field has effect on the mean path δ or hot vibrational frequency v of ions in solution. In microwave field, the mean energy barrier, which ions must surmount as they transit, is the function relation to temperature. 相似文献
40.
WANG Yuzhu LIAO Xiaofeng 《武汉大学学报:自然科学英文版》2006,11(6):1715-1717
0 IntroductionNowthere are many well known cryptosystems based ondiscrete logarithms , such as the ElGamal cryptosys-tem[1]and the digital signature algorithm(DSA)[2]. Discretelogarithms have many advantages . Breaking the discrete log-arithm modulo pri mepappears to be somewhat harder thanfactoringintegern,and elliptic curve cryptosystems may usemuchsmaller keysizesthan RSA-basedcryptosystems of com-parable security.The discrete logarithmproblemover a group can be bro-ken down into a numb… 相似文献