全文获取类型
收费全文 | 255篇 |
免费 | 9篇 |
国内免费 | 9篇 |
专业分类
化学 | 139篇 |
晶体学 | 2篇 |
力学 | 1篇 |
综合类 | 1篇 |
数学 | 22篇 |
物理学 | 11篇 |
综合类 | 97篇 |
出版年
2025年 | 1篇 |
2024年 | 10篇 |
2023年 | 7篇 |
2022年 | 33篇 |
2021年 | 29篇 |
2020年 | 24篇 |
2019年 | 19篇 |
2018年 | 14篇 |
2017年 | 8篇 |
2016年 | 10篇 |
2015年 | 3篇 |
2014年 | 11篇 |
2013年 | 6篇 |
2012年 | 9篇 |
2011年 | 15篇 |
2010年 | 9篇 |
2009年 | 5篇 |
2008年 | 8篇 |
2007年 | 8篇 |
2006年 | 11篇 |
2005年 | 5篇 |
2004年 | 3篇 |
2003年 | 6篇 |
2002年 | 3篇 |
2001年 | 6篇 |
2000年 | 2篇 |
1999年 | 4篇 |
1998年 | 2篇 |
1995年 | 2篇 |
排序方式: 共有273条查询结果,搜索用时 0 毫秒
11.
Laccases are multicopper oxidases that have shown a great potential in various biotechnological and green chemistry processes mainly due to their high relative non-specific oxidation of phenols, arylamines and some inorganic metals, and their high redox potentials that can span from 500 to 800 mV vs. SHE. Other advantages of laccases include the use of readily available oxygen as a second substrate, the formation of water as a side-product and no requirement for cofactors. Importantly, addition of low-molecular-weight redox mediators that act as electron shuttles, promoting the oxidation of complex bulky substrates and/or of higher redox potential than the enzymes themselves, can further expand their substrate scope, in the so-called laccase-mediated systems (LMS). Laccase bioprocesses can be designed for efficiency at both acidic and basic conditions since it is known that fungal and bacterial laccases exhibit distinct optimal pH values for the similar phenolic and aromatic amines. This review covers studies on the synthesis of five- and six-membered ring heterocyclic cores, such as benzimidazoles, benzofurans, benzothiazoles, quinazoline and quinazolinone, phenazine, phenoxazine, phenoxazinone and phenothiazine derivatives. The enzymes used and the reaction protocols are briefly outlined, and the mechanistic pathways described. 相似文献
12.
Massimo Lucarini Alessandra Durazzo Roberta Bernini Margherita Campo Chiara Vita Eliana B. Souto Ginevra Lombardi-Boccia Mohamed Fawzy Ramadan Antonello Santini Annalisa Romani 《Molecules (Basel, Switzerland)》2021,26(21)
The by-products/wastes from agro-food and in particular the fruit industry represents from one side an issue since they cannot be disposed as such for their impact on the environment but they need to be treated as a waste. However, on the other side, they are a source of bioactive healthy useful compounds which can be recovered and be the starting material for other products in the view of sustainability and a circular economy addressing the global goal of “zero waste” in the environment. An updated view of the state of art of the research on fruit wastes is here given under this perspective. The topic is defined as follows: (i) literature quantitative analysis of fruit waste/by-products, with particular regards to linkage with health; (ii) an updated view of conventional and innovative extraction procedures; (iii) high-value added compounds obtained from fruit waste and associated biological properties; (iv) fruit wastes presence and relevance in updated databases. Nowadays, the investigation of the main components and related bioactivities of fruit wastes is being continuously explored throughout integrated and multidisciplinary approaches towards the exploitation of emerging fields of application which may allow to create economic, environmental, and social value in the design of an eco-friendly approach of the fruit wastes. 相似文献
13.
循环经济是一种新兴的物尽其用的经济发展模式,它强调资源的再使用和再循环。实行循环经济是保障工业企业可持续发展的客观需要,也是实施可持续发展战略的重要途径和实现方式。 更多还原 相似文献
14.
为促进干旱区城市可持续发展,以乌鲁木齐城市系统为例,基于2004和2010年统计数据,利用相图法分析得出:2003和2009年系统对不可更新自然资源的利用比例极大,对可更新自然资源利用比例最小;6年间系统对自然资源利用比例下降,尤其对可更新资源利用比例下降显著,为33.84%,而社会反馈投入能值比例上升;两年系统虽都处于可持续发展状态,但可持续发展指数有所下降且均接近下限。欲提升系统可持续发展性能,必须合理调整其能值利用结构。 相似文献
15.
L. Seralessandri 《Journal of solid state chemistry》2008,181(8):1992-1997
Sodium ferrimanganite carbonatation reaction was investigated at different temperatures/carbon dioxide partial pressures to evaluate the feasibility of the thermochemical water-splitting cycle based on the MnFe2O4/Na2CO3/Na(Mn1/3Fe2/3)O2 system.After thermal treatments in selected experimental conditions, the obtained powder samples were investigated by using the X-ray diffraction (XRD) technique and Rietveld analysis.Two different lamellar Na1−xMn1/3Fe2/3O2−δ phases were observed together with the expected MnFe2O4/Na2CO3 mixture. Different equilibrium regions among sodium-depleted lamellar phases, manganese ferrite and sodium carbonate were found as a function of the different reaction conditions. A hypothesis concerning the regeneration mechanism of the initial compounds is proposed. Chemical equilibrium between stoichiometric and sub-stoichiometric forms of sodium ferrimanganite and sodium carbonate formation/dissociation appears to be essential factors governing the oxygen-releasing step of the manganese ferrite thermochemical cycle. 相似文献
16.
This paper focuses on a new property for bankruptcy rules, calledsustainability, which requires that the agents with small enough claims be fully reimbursed. We show that the constrained equal-awards rule is the only rule that satisfies path independence and sustainability. Exploiting duality relations, we also provide a characterization of the constrained equal-losses rule, as the only one that satisfies composition and independence of residual claims (the dual property of sustainability). 相似文献
17.
18.
Castanea sativa Mill. is a species of the family Fagaceae abundant in south Europe and Asia. The fruits (chestnut) are an added value resource in producing countries. Chestnut economic value is increasing not only for nutritional qualities but also for the beneficial health effects related with its consumption. During chestnut processing, a large amount of waste material is generated namely inner shell, outer shell and leaves. Studies on chestnut by-products revealed a good profile of bioactive compounds with antioxidant, anticarcinogenic and cardioprotective properties. These agro-industrial wastes, after valorisation, can be used by other industries, such as pharmaceutical, food or cosmetics, generating more profits, reducing pollution costs and improving social, economic and environmental sustainability.
The purpose of this review is to provide knowledge about the type of chestnut by-products produced, the studies concerning its chemical composition and biological activity, and also to discuss other possible applications of these materials. 相似文献
19.
《液相色谱法及相关技术杂志》2012,35(7):801-809
Xylose oligomers are of interest to many fields of study and are intermediate reaction products of the hydrolysis of hemicelluloses. Protocols to generate xylose oligomers are reported, but these methods lead to the production of a pool of nonfractionated xylose oligomers with a wide range in degree of polymerization (DP). This work used switchgrass hemicelluloses as feedstock for production of purified xylose oligomers. Switchgrass hemicelluloses were autohydrolyzed at 160°C. Yields of xylobiose, xylotriose, xylotetraose, xylopentose, and xylohexose were 24, 34, 23, 19, and 38 mg, respectively, per g of hemicelluloses. The crude xylose oligomer mixture was fractionated using centrifugal partition chromatography (CPC) with a butanol:methanol:water (5:1:4, V:V:V) solvent system. Xylose oligomers with a DP from two to six were successfully purified. Purities obtained by CPC separation, as calculated by mass of a given oligomer divided by the total mass of detected oligomers and degradation products and then reported on a percent basis, were 75 ± 7%, 89 ± 1, 87% ± 2, 77 ± 6%, and 69 ± 12% for xylobiose, xylotriose, xylotetraose, xylopentose, and xylohexose, respectively. This work illustrates that a CPC-based process could be used to fractionate switchgrass xylose oligomers reference standards, which are currently not commercially available. 相似文献
20.
Plant oils and their derived fatty acids are a highly valuable renewable resource for polymer science. In this review, the use of this renewable resource for the synthesis of nitrogen‐containing step‐growth polymers, that is, polyamides and polyurethanes, is described. The focus is on the accessible structures of monomers and polymers and thus also the obtainable polymer properties. More importantly, the sustainability of the approaches is discussed and compared to each other where possible, also giving suggestions for future developments. 相似文献