The crystal chemistry of L-Ta2O5 and related structures

Single crystals of a new form of L-Ta₂O₅ with a 19×b superstructure have been synthesised by flux growth. The phase is most likely stabilised by the incorporation of a small amount of lithium (0.14 wt% Li) from the flux. The phase has C-centred monoclinic symmetry with , (), , γ=90.00(1)°. The structure was refined in space group C112/m to R₁=0.044 for 814 unique reflections with F>4σ(F). The structure can be described as comprising chains of edge-shared TaO₇ pentagonal bipyramids that are regularly folded at (010) planes to give sinusoidal chains along [010]. These chains are interconnected along [100] and [001] by corner sharing, creating inter-chain regions that are occupied by isolated TaO₆ octahedra and pairs of corner-shared octahedra. A comparison with published data for high-quality refinements of related structures has led to the development of a general model that can explain the structural chemistry variations in the known L-Ta₂O₅-related structures. A shorthand notation is presented for representing the structures, based on the sequence along [010] of the interchain octahedra.     

纤维素纤维与薄膜动态粘弹性及其不连续非常态行为的研究(Ⅰ)不同温度和湿度下再生纤维素纤维的动态粘弹行为考察

采用动态粘弹仪详细研究了湿度对再生纤维素纤维粘弹性的影响。结果表明,在３５～６５℃温度范围内,随着湿度的增加,再生纤维素的Ｅｒ下降,ｔａｎδ上升。这表明水分子的渗入对纤维素起到了增塑作用,对纤维素分子链间及分子链内的氢键起到了屏蔽作用,使得一些运动单元得以运动。实验结果也表明,三种再生纤维素样品有不同的结构,说明再生方法和纺丝条件对再生纤维素结构有较大的影响,对再生纤维素性能也有较大影响     

超结构换热器网络综合优化的遗传/模拟退火算法-Ⅰ.改进的换热器网络通用解方法

在换热器网络的最优化设计中,为计算其年度总费用,必须首先得到网络中各换热器流体的进出口温度.本文提出了分级超结构换热器网络中流体温度的显式解析解.这一新算法大大降低了它对计算机内存的要求,使其能适用于大规模换热器网络的温度计算和最优综合.     

The Löwenheim—Skolem—Mal'tsev Theorem for ℍ\mathbb{F}-Structures

We deal with the problem asking whether hereditarily finite superstructures have elementary extensions of the form . In so doing, we settle the question whether a theory for some hereditarily finite superstructure have models of arbitrarily large cardinality. A Hanf number is shown to exist, and we provide an exact bound for the countable case.     

Σ-Subsets of Natural Numbers

It is shown that the class of all possible families of -subsets of finite ordinals in admissible sets coincides with a class of all non-empty families closed under e-reducibility and . The construction presented has the property of being minimal under effective definability. Also, we describe the smallest (w.r.t. inclusion) classes of families of subsets of natural numbers, computable in hereditarily finite superstructures. A new series of examples is constructed in which admissible sets lack in universal -function. Furthermore, we show that some principles of classical computability theory (such as the existence of an infinite non-trivial enumerable subset, existence of an infinite computable subset, reduction principle, uniformization principle) are always satisfied for the classes of all -subsets of finite ordinals in admissible sets.     

顶层设计与文山学院的科学发展

新建地方本科院校在建设高等教育强国中肩负着重要的历史使命。新建地方本科院校必须完善顶层设计,明确办学理念,找准自身定位,做好战略规划,凝练办学特色,才能在激烈的竞争中科学发展,继续在我国建设高等教育强国进程中做出应有的贡献。     

NiW合金基带表面c(2×2)-S超结构的硫化处理

由于硫元素与氧元素化学特性相近,利用硫在Ni基带表面形成的c(2×2)-S超结构可以有效地控制氧化物缓冲层在Ni基带表面的织构.本研究提出将单质硫在120℃下挥发,利用单质硫在基带表面的吸附与脱附形成有序c(2×2)-S超结构的新技术路线.X光电子能谱(XPS)结果显示,采用新技术处理的金属基带表面有明显的硫元素,基带表面Ni和S的原子比例符合c(2×2)结构中S的覆盖度,即0.5的要求.在经过硫化处理后的NiW基带表面制备缓冲层,结果显示,新硫化处理技术改善了NiW基带表面的物理化学特性,有利于氧化物缓冲层的外延生长.     

Model Approach to Nonstandard Analysis in the Context of Axiomatic Set Theory

In this paper, the model approach to nonstandard analysis is developed on the basis of Zermelo—Fraenkel axiomatic set theory with atoms. The traditional consideration of the standard superstructure V as the primary object of nonstandard analysis is justified. Set-theoretic axioms for the nonstandard system *V are obtained.     

Direct Chemical Fine‐Tuning of Electronic Properties in Sc2Ir6−xPdxB

Crystal orbital Hamilton population (COHP) bonding analysis has predicted that ScPd₃B_0.5 is the least stable compound of the entire series Sc₂Ir_6?xPd_xB. Here, we report a systematic study of Sc₂Ir_6?xPd_xB (x=3, 5 and 6) by means of ¹¹B nuclear magnetic resonance (NMR), Knight shift (K) and nuclear spin‐lattice relaxation rate (1/T₁). NMR results combined with theoretical band structure calculations provide a measure of s‐ and non‐s‐character Fermi‐level density of states. We present direct evidence that the enhanced s‐state character of the Fermi level density of states (DOS) in ScPd₃B_0.5 reduces the strength of the B 2p and Pd 4d hybridized states across the entire Sc₂Ir_6?xPd_xB series. This hybridization strength relates to the opening of a deep pseudogap in the density of states of Sc₂IrPd₅B and the chemical bonding instability of ScPd₃B_0.5. This study is an experimental realization of a chemical fine‐tuning of the electronic properties in intermetallic perovskites.     

暴露{001}面TiO2纳米片分等级花状结构的制备及其光催化活性

以钛酸盐纳米管为前驱体,在HF-H2O-C2H5OH的混合溶液中,采用一种简单的醇热方法合成了具有87%暴露{001}面的TiO2纳米片自组装形成的分等级花状TiO2超结构.运用X射线衍射、扫描电镜、透射电镜和N2吸附-脱附等方法对样品进行了表征,并在紫外光照射下于空气和溶液中分别考察了其光催化降解丙酮和甲基橙反应活性...