纤维素纤维及薄膜动态粘弹性及其不连续非常态行为

详细考察了三种再生纤维素样品在宽广温度范围内（－１５０￣３５０℃）的粘弹性能。实验结果表明,在该温度范围内,三种再生纤维素均出现了ａ１、ａ２、ａｓｈ、ａ３、β和γ松弛等多转变。从这些转变的特征值分析,三种样品在结构上存在较大差异。样品ＲＡＹ有较低的结晶度,在晶区内和无定形区域内存在较高的结构不均匀性;样品ＮＥＷ的结晶度较高,在晶区和无定区内存在较高的结构均匀性,而样品ＢＥＮ的超分子结构介于这两者之     

2D self-assembling of 4, 5-didodecylthiolphthalonitrile on graphite surface

An important precursor 4,5-didodecylthiolphthalonitrile (DCP) for synthesis of phthalocyanines (Pcs) and subphthalocyanines (SubPcs) was synthesized and the assembling structure of this molecule on the basal plane of highly oriented pyrolytic graphite (HOPG) surface was characterized using the scanning tunneling microscopy (STM) in ambient conditions. In high-resolution images of the molecules, we found that the arrangement of the cyano groups forms a “head-to-head” configuration to keep the stability of the entire system. The mismatch of the DCP molecules with the substrate lattice has also been observed in the experiment.     

A definable nonstandard enlargement

This article establishes the existence of a definable (over ZFC), countably saturated nonstandard enlargement of the superstructure over the reals. This nonstandard universe is obtained as the union of an inductive chain of bounded ultrapowers (i.e. bounded with respect to the superstructure hierarchy). The underlying ultrafilter is the one constructed by Kanovei and Shelah [10]. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Effects of several lanthanide trichloride hydrates on the melting behavior and spherulitic superstructure of poly(ethylene oxide)

Binary mixtures of poly(ethylene oxide) (PEO) with the trichloride hydrates of lanthanum, cerium, europium, terbium, and ytterbium have been studied with calorimetry, polarized optical microscopy, and infrared spectroscopy. Melting‐point depression of the PEO‐rich phase occurs in all cases. At sufficiently high concentrations of the low molecular weight lanthanide complex, crystallization of the polymer is absent. The lighter lanthanides with larger ionic radii, such as lanthanum and cerium, are more effective in suppressing PEO crystallization from solution or the molten state because they are more oxophilic. The spherulitic superstructure of PEO disappears at rather low concentrations of the lanthanide salts, between 2 and 8 mol % Ln³⁺. Lanthanum and terbium are most efficient at disrupting the formation of PEO spherulites, and europium is least efficient. Infrared spectroscopy identifies twisting and wagging vibrational absorptions of CH₂ groups in the polymer that are sensitive to the morphologies of these mixtures. Modifications of the PEO infrared absorbances in the presence of these five lanthanide salts correlate more closely with the presence or absence of major PEO melting, not the formation of a spherulitic superstructure. The phase behavior is rather simple, with no evidence of eutectic solidification upon cooling from the molten state. Multiple melting endotherms are observed in the differential scanning calorimetry heating traces of binary mixtures containing 8 mol % Yb³⁺ and between 10 and 20 mol % Eu³⁺, but the concentration dependence of these first‐order endothermic transitions is not characteristic of eutectic phase behavior. The presence of trivalent cations, such as Eu³⁺ or Yb³⁺, in these complexes perturbs the crystallization kinetics of PEO upon cooling from the molten state, as well as the melting behavior upon heating. Ion–dipole or electrostatic interactions between the lanthanide cation and the ether oxygen of PEO might alter the surface free energy at the periphery of the crystalline lamellae and perturb the chain‐folding characteristics of PEO. Consequently, coupling between the amorphous matrix and the PEO crystallites is strengthened, and this provides stability for the existence of multiple‐chain‐folded crystals composed of rather thin lamellae that could be responsible for multiple melting behavior. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 2200–2213, 2003     

土-桩-结构相互作用体系随机地震反应分析

本文采用随机振动理论与有限元技术相结合的方法，以基岩随机地震作为输入，对群桩基础和土-桩-结构相互作用体系进行了三维随机地震反应分析。文中首先以一3X3群桩基础作为分析模型，探讨了桩-土-桩动力相互作用对承台随机地震反应的影响；然后，用单自由度体系模拟上部结构，分析了上部结构惯性对桩基承台随机地震反应的影响。在此基础上，以某桥桥墩为背景，用多自由度体系模拟上部结构，建立了土-桩-结构相互作用体系的三维分析模型，获得了桩基承台的功率谱响应、以及桩顶处的主应力标准差和主应力速率标准差等结果，探讨了群桩顶部各桩主应力标准差的分布规律，得到了一些有应用价值的结果。     

Addendum to “A definable nonstandard enlargement”

?o?'s theorem for bounded D ‐ultrapowers, D being the ultrafilter introduced by Kanovei and Shelah [4], is established. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

模糊拓扑空间中Q-紧集的非标准刻画

在非标准扩大模型下,讨论了模糊拓扑空间中Q-紧集的非标准刻画．首先,将模糊集合扩张为非标准模糊集合,借助模糊点的重域定义了模糊点的单子．其次,以模糊点的单子为工具,给出了Q-紧集的非标准刻画,并在此基础上得到了Q-紧空间的非标准刻画．最后,证明了Q-紧空间的Tychonoff乘积定理．     

滑跃式甲板气流场数值模拟

利用FLUENT软件对舰船进行数值模拟,与已有风洞实验数据对比分析,验证数值模拟的准确性．针对滑跃式舰船甲板,讨论不同网格形式对计算结果的影响,发现棱柱层网格可以改善计算过程的收敛特性,提高收敛速度,沿甲板边界的网格细化是采集船首和边界涡产生的关键．通过对全尺寸的滑跃式甲板舰船船型的计算,得到船首分离涡和岛型建筑后面复杂的涡旋结构．结果表明：岛型建筑分离涡计算的准确度直接影响了岛型建筑下游流场的整体特征;船体尺寸和岛形建筑的形状和位置会严重影响船后涡旋的强度和位置．     

Visible‐Light‐Driven Halogen Bond Donor Based Molecular Switches: From Reversible Unwinding to Handedness Inversion in Self‐Organized Soft Helical Superstructures

Visible‐light‐driven molecular switches endowing reversible modulation of the functionalities of self‐organized soft materials are currently highly sought after for fundamental scientific studies and technological applications. Reported herein are the design and synthesis of two novel halogen bond donor based chiral molecular switches that exhibit reversible photoisomerization upon exposure to visible light of different wavelengths. These chiral molecular switches induce photoresponsive helical superstructures, that is, cholesteric liquid crystals, when doped into the commercially available room‐temperature achiral liquid crystal host 5CB, which also acts as a halogen‐bond acceptor. The induced helical superstructure containing the molecular switch with terminal iodo atoms exhibits visible‐light‐driven reversible unwinding, that is, a cholesteric–nematic phase transition. Interestingly, the molecular switch with terminal bromo atoms confers reversible handedness inversion to the helical superstructure upon irradiation with visible light of different wavelengths. This visible‐light‐driven, reversible handedness inversion, enabled by a halogen bond donor molecular switch, is unprecedented.     

Theory of the Lamellar Superstructure of an ABC 3‐Miktoarm Star‐Terpolymer

Summary: The theory of lamellar superstructures of an ABC 3‐miktoarm star terpolymer in the conditions corresponding to the strong segregation limit for linear ABC triblock terpolymer has been developed. According to the particular molecular topology (namely, the common junction point for all three blocks), the system cannot avoid volume interactions between monomers of different blocks even in this limit. Hence, in the lamellar superstructure, there exists the so‐called “mixed” domain containing monomers of all three blocks but formed mainly of the block with the lowest degree of incompatibility. It is shown that unfavorable volume interactions in this domain are minimized by the increase of the interfacial area per ABC molecule which makes the mixed domain narrow. This leads to an unusual behavior of the period of the superstructure which decreases with an increase in the length of the block with the lowest incompatibility. However, in the case of a “synchronous” increase in the size of the branches of the ABC 3‐miktoarm star terpolymer, the period of the superstructure increases similarly to that for a linear ABC triblock terpolymer.

ABC 3‐miktoarm star terpolymer.