全文获取类型
收费全文 | 5976篇 |
免费 | 190篇 |
国内免费 | 238篇 |
专业分类
化学 | 1790篇 |
晶体学 | 28篇 |
力学 | 185篇 |
综合类 | 26篇 |
数学 | 202篇 |
物理学 | 511篇 |
综合类 | 3662篇 |
出版年
2024年 | 8篇 |
2023年 | 39篇 |
2022年 | 146篇 |
2021年 | 125篇 |
2020年 | 129篇 |
2019年 | 122篇 |
2018年 | 111篇 |
2017年 | 133篇 |
2016年 | 141篇 |
2015年 | 142篇 |
2014年 | 275篇 |
2013年 | 288篇 |
2012年 | 340篇 |
2011年 | 368篇 |
2010年 | 256篇 |
2009年 | 324篇 |
2008年 | 389篇 |
2007年 | 507篇 |
2006年 | 420篇 |
2005年 | 337篇 |
2004年 | 300篇 |
2003年 | 258篇 |
2002年 | 223篇 |
2001年 | 195篇 |
2000年 | 142篇 |
1999年 | 111篇 |
1998年 | 102篇 |
1997年 | 61篇 |
1996年 | 65篇 |
1995年 | 69篇 |
1994年 | 47篇 |
1993年 | 50篇 |
1992年 | 53篇 |
1991年 | 27篇 |
1990年 | 17篇 |
1989年 | 17篇 |
1988年 | 16篇 |
1987年 | 10篇 |
1986年 | 9篇 |
1985年 | 4篇 |
1984年 | 6篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 3篇 |
1976年 | 3篇 |
1972年 | 2篇 |
1971年 | 1篇 |
1962年 | 1篇 |
排序方式: 共有6404条查询结果,搜索用时 0 毫秒
51.
地理学的贫困与出路(Ⅱ)--地理学发展的分形方向 总被引:2,自引:0,他引:2
陈彦光 《信阳师范学院学报(自然科学版)》1998,11(2):163-166,171
本文认为分形研究是未来地理学发展的主要方向。地理学研究对象的基本特征是差异性,差异性暗示了地理学的空间信息科学性质,而Shannon熵与Hausdorf维数等价,这表明分形维数可以作为地理系统信息分析的定量判据,故可借助分形几何学实现地理学的数量化;另外,运用分形模型进行地理系统的计算机模拟,可以弥补地理研究不可实验性的不足。地理学可望建立比较严格的逻辑体系。 相似文献
52.
旋风除尘器内锥形扩口芯管对其性能的影响分析和实验研究 总被引:3,自引:1,他引:2
用平衡粒径模型分析了旋风除尘器内常用的柱菜芯管结构存在的缺陷,提出了用带锥形扩口和十字板的芯管改进旋风除尘器的内部芯管结构,并用实验研究测得了新型结构减阻效的幅度。 相似文献
53.
利用电位滴定法测定了溶液中二肽H-Cys-Cys-OEt(1)的pKa值以及它的锌络合物的稳定常数和组分分布,从而推断出锌络合物的结构 相似文献
54.
张月清 《河北师范大学学报(自然科学版)》1998,22(3):428-432
根据硕士研究了整个学程的教育规律,以硕士研究了的科研训练为起点,用模数学建立了一套硕士论文质量的综合评判方法。 相似文献
55.
IR lattice vibration spectra were used to monitor the changes in the structure of zeolite Na-Y upon its dealumination with ethylenediaminetetraacetic acid (EDTA) or with HCl. The terminal Si-O(H,Na) bonds thus formed (which are detectable by characteristic absorbance at v 900–950 cm–1) are energetically less uniform when EDTA has been used as the dealuminating agent. This inhomogeneity is connected with the local deformations of zeolite structure which result in lowering the symmetry of silicon-oxygen tetrahedra. As a consequence, two novel bands appear at v 1090 cm–1 and 1200 cm–1 in addition to the fundamental absorption bands, vas (TO4) (T = Si, Al), at 1030 cm–1 and 1145 cm–1. A mechanism of dealumination is proposed, which takes into account the topochemical peculiarities involved in the chelation of the framework aluminum ions with EDTA.Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskay, No. 2, pp. 284–287, February, 1993. 相似文献
56.
A computational study is made of the effect of basis set upon the energy, properties and inversion barrier of the phosphine molecule. The calculations are performed at both the SCF and CI level. The flexibility of the double zeta basis is discussed in the light of the results. 相似文献
57.
The reaction of imidazole with benzoyl chloride in pyridine affordedcis-1,2-bis(benzoyl-amino)ethylene (1) rather than 2-benzoylimidazole, as has been suggested previously. The structure of1 was confirmed by1H NMR spectroscopy and X-ray diffraction study.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1593–1595, August, 1998. 相似文献
58.
A. N. Bilyachenko A. A. Korlyukov M. M. Levitskii M. Yu. Antipin B. G. Zavin 《Russian Chemical Bulletin》2007,56(3):543-545
The first cage-like ferrophenyl siloxane containing FeIII ions in different coordination spheres (four iron ions have a trigonal-bipyramidal coordination and two iron ions have a
distorted octahedral coordination) was synthesized by the exchange reaction of sodium phenylsilanolate with FeIII chloride. An exotic lantern-like structure is formed with the involvement of two metal oxide fragments Fe—O—Fe. The structure
of this compound was established by X-ray diffraction.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 522–524, March, 2007. 相似文献
59.
Single nucleotide polymorphisms (SNPs) are currently being mapped and databased at a remarkable pace, providing a viable means for understanding disease susceptibility, differential drug response and human evolution. Consequently, there is an increasing demand for SNP genotyping technologies that are simple, rapid, cost effective and readily amenable to automation for high-throughput analyses. In this study, we improved the Survivor Assay, a SNP detection method based on electrospray ionization mass spectrometry (ESI-MS), with several developments. One improvement is the development of a one-well assay, requiring no off-line purification of the polymerase chain reaction product, achieved by simple addition of reagent solution into a single well. Another is the on-line separation of magnesium and dideoxynucleotides using an in-house made monolithic metal chelating column, eliminating any off-line sample preparation prior to mass spectrometric analysis. Here the Survivor Assay is extended from a proof-of-principle concept to a validated method by genotyping six SNPs from five different regions of human genomic DNA in 55 individual samples with 100% accuracy. This improved Survivor Assay eliminates the tedious and time-consuming steps of sample preparation, minimizes sample handing and offers a high-throughput analysis of SNPs by ESI-MS. The current combined preparation and analysis time is 2 min per sample. The simplicity of this method has potential for full automation and parallel chromatography and, thus, reduced analysis time. In addition, we have adapted the Survivor Assay for quantitative SNP analysis in pooled DNA samples. The capabilities and sensitivity of this approach were evaluated. We demonstrate that an allele occurring at a frequency of 2% can consistently be quantitated. 相似文献
60.
V. F. Mironov A. V. Bogdanov A. V. Nemtarev A. A. Shtyrlina E. N. Varaksina V. K. Cherkasov A. B. Dobrynin D. B. Krivolapov R. Z. Musin I. A. Litvinov A. I. Konovalov 《Russian Chemical Bulletin》2007,56(9):1900-1910
The reactions of 3,5-di(tert-butyl)-1,2-benzoquinone with aryl-and alkylacetylenes in the presence of phosphorus trichloride afford 4-aryl(alkyl)-8-tert-butyl-2,6-dichloro-2-oxo-2H-benzo[e][1,2]oxaphosphinines as the major ipso-substitution products of the tert-butyl group by the chlorine atom. 4-Aryl(alkyl)-6,8-di(tert-butyl)-2,5-dichloro-2-oxo-and 4-aryl(alkyl)-6-tert-butyl-2,8-dichloro-2-oxo-2H-benzo[e][1,2]oxaphosphinines were obtained as the minor products. The structures of the stable representatives of this series were
confirmed by X-ray diffraction.
Dedicated to Academician G. A. Abakumov on the occasion of his 70th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1836–1845, September, 2007. 相似文献