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51.
52.
The viscoelastic photoelastic behaviour of networks of 2-hydroxyethyl methacrylate — dodecyl methacrylate (DMA) copolymers in the main transition and rubberlike region was investigated. With increasing DMA content, photoelastic functions are quickly shifted to lower temperatures or shorter times; a detailed course of the functions suggests heterogeneity of the copolymers. Due to the existence of long side chains, optical function of all samples change the sign from positive to negative with increasing temperature. While the temperature dependences of the moduli of copolymers can be described by the two-phase Takayanagi model, the temperature dependences of optical functions cannot be described by using this model. It has been found, however, that the tempeature and time dependences of photoelastic functions can be described semiquantitatively by a three-phase model with a hypothetical statistical copolymer as the third component. The high values of the volume fraction of the hypothetical statistical copolymer found for the individual samples, suggest a considerable miscibility and a strong influence of the interphase boundary on the photoelastic behaviour of the copolymers. 相似文献
53.
Rodica Olar Michaela Badea E. Cristurean C. Parnau D. Marinescu 《Journal of Thermal Analysis and Calorimetry》2006,84(1):53-58
The complexes of the type M(HDMBG)2(CH3COO)2·nH2O ((1)
M:Mn, n=1.5; (2)
M:Ni, n=0; (3)
M:Cu, n=2; (4)
M:Zn, n=2; DMBG: N,N-dimethylbiguanide)
present in vitro antimicrobial activity. The thermal analysis has evidenced
the thermal intervals of stability and also the thermodynamics effects that
accompany them. The different nature of the ligands generates a different
thermal behaviour for the complexes. The thermal transformations are complex
processes according to TG and DTG curves including dehydration, oxidative
condensation of –C=N– units as well as thermolysis processes.
The final products of decomposition are the most stable metal oxides. 相似文献
54.
Narcís Homs Jordi Llorca Montserrat Riera Jordi Jolis Jos-Luis G. Fierro Joaquim Sales Pilar Ramírez de la Piscina 《Journal of molecular catalysis. A, Chemical》2003,200(1-2):251-259
Silica-supported trimetallic catalysts containing Pt, Sn and a group 13 metal (PtSnM, M=Ga, In, Tl) were prepared by consecutive impregnation steps from cis-[PtCl2(PPh3)2] and chloride precursors. X-ray diffraction (XRD), transmission electron microscopy (TEM), selected-area electron diffraction (ED) and energy dispersive X-ray analysis (EDX) showed large platelet-like particles of PtSn1−xMx phases. PtSnGa catalyst with a Pt/(Sn+Ga) molar ratio of 1.72 showed a bimodal particle distribution and a Pt phase was identified. Differences in surface structures were also revealed by the performance of catalysts in the dehydrogenation of n-hexane. For PtSnIn and PtSnTl (Pt/(Sn+M) molar ratio of about 1) the dehydrogenation was favoured. In contrast, PtSnGa catalyst yielded hydrogenolysis products. Photoelectron spectra showed the Pt 4f7/2 level at a binding energy of 70.0–71.8 eV in all cases. Moreover, the FT-IR spectra of chemisorbed CO on the PtSnGa showed a slight shift in the ν(CO) toward higher values with respect to the monometallic catalyst, pointing to an electronic effect in accordance with photoelectron spectroscopy. 相似文献
55.
SHEN Yu-Feng WANG Qing-Hai ZHU Dao-Qian ZHOU Liang-Mo Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian Liaoning China 《中国化学》1994,12(2):129-137
The study on retention behavior in supercritical fluid chromatography (SFC) is necessary to understand the mechanism of the various interactions in SFC. The retention of SFC in carboxylic acid methyl ester/polymethylsiloxane/CO2 system was studied systematically and the retention behavior of this kind of compounds under various typical operation conditions was described using the method of an alternative unified theory of chromatographic retention. The results illustrated that expression: Ink.= a + b/T + cp + dp/T + ep2/T can be used to describe quantitatively the retention behavior of carboxylic acid methyl ester/polymethylsiloxane/CO2 system in the ranges of reduced density from 0.549 to 1.411. It was also found that the entropy of solute in stationary phase is dependent on the density of supercritical fluid (SF) under typical operating conditions of SFC. 相似文献
56.
张正球 《湖南大学学报(自然科学版)》1996,23(6):11-14
考虑一个广义时滞人口增长模型,获得了它的每个正解当t→∞时趋于其正平衡点的充分条件。 相似文献
57.
动力系统的胞映射—点映射法及应用 总被引:1,自引:0,他引:1
对动力系统的胞映射法进行了改进,采用点映射法对胞映射法的计算结果进行后处理,求得精确的周期运动和吸收域,将胞映法和点映射法结合起来,有较高的计算精度和效率。 相似文献
58.
讨论了一类一阶中立型差分方程的振动性及其非振动解的渐近性,获得了一些充分性判据,推广了一些已有文献中的结果。 相似文献
59.
本文首次报导应用简单工艺,在常压下制备CrO3-MoO3合成材料。对该材料的结构特征及电性能进行了测试和研究。结果表明,CrO3-MoO3是一种新型的阴极材料。它不仅具有良好的放电性能,而且与CrO3相比,它的毒性、腐蚀性和吸水性均大为降低,可直接作为固体电池的新阴极材料。 相似文献
60.
高速磨削加工的残余硬度 总被引:2,自引:0,他引:2
研究了淬硬钢回火硬度与回火温度的关系.建立了回火硬度与回火温度关系的回火效应模型。磨削热导致回火引起淬硬钢磨削后表面硬度变化。通过合并磨削热模型和回火效应,可以预测工件磨削后的表面硬度变化。进行了45^#钢的高速磨削试验.研究了工件速度和磨削深度对磨削后表面硬度的影响。试验值与预测值能够较好吻合。 相似文献