聚联苯酰亚胺/聚硫醚酰亚胺共混体系的相容性

<正> 聚酰亚胺是一种性能极其优异的高性能树脂,它在许多高技术领域有着极其重要的应用价值。在80年代以前,人们工作的重点是合成出一系列分子结构不同的聚酰亚胺,研究分子结构与性能间的关系,开发聚酰亚胺新品种。自80年代后期,有关高性能树脂聚酰亚胺共混物的研究日益引起人们的关注,其中有关不同分子结构的聚酰亚胺/聚酰亚胺共     

The thermorheological complexity of photoelastic behaviour of 2-hydroxyethyl methacrylate — dodecyl methacrylate copolymers

The viscoelastic photoelastic behaviour of networks of 2-hydroxyethyl methacrylate — dodecyl methacrylate (DMA) copolymers in the main transition and rubberlike region was investigated. With increasing DMA content, photoelastic functions are quickly shifted to lower temperatures or shorter times; a detailed course of the functions suggests heterogeneity of the copolymers. Due to the existence of long side chains, optical function of all samples change the sign from positive to negative with increasing temperature. While the temperature dependences of the moduli of copolymers can be described by the two-phase Takayanagi model, the temperature dependences of optical functions cannot be described by using this model. It has been found, however, that the tempeature and time dependences of photoelastic functions can be described semiquantitatively by a three-phase model with a hypothetical statistical copolymer as the third component. The high values of the volume fraction of the hypothetical statistical copolymer found for the individual samples, suggest a considerable miscibility and a strong influence of the interphase boundary on the photoelastic behaviour of the copolymers.     

Thermal behaviour of new N,N-dimethylbiguanide complexes having selective and effective antibacterial activity

The complexes of the type M(HDMBG)₂(CH₃COO)₂·nH₂O ((1) M:Mn, n=1.5; (2) M:Ni, n=0; (3) M:Cu, n=2; (4) M:Zn, n=2; DMBG: N,N-dimethylbiguanide) present in vitro antimicrobial activity. The thermal analysis has evidenced the thermal intervals of stability and also the thermodynamics effects that accompany them. The different nature of the ligands generates a different thermal behaviour for the complexes. The thermal transformations are complex processes according to TG and DTG curves including dehydration, oxidative condensation of –C=N– units as well as thermolysis processes. The final products of decomposition are the most stable metal oxides.     

Silica-supported PtSn alloy doped with Ga, In or, Tl: Characterization and catalytic behaviour in n-hexane dehydrogenation

Silica-supported trimetallic catalysts containing Pt, Sn and a group 13 metal (PtSnM, M=Ga, In, Tl) were prepared by consecutive impregnation steps from cis-[PtCl₂(PPh₃)₂] and chloride precursors. X-ray diffraction (XRD), transmission electron microscopy (TEM), selected-area electron diffraction (ED) and energy dispersive X-ray analysis (EDX) showed large platelet-like particles of PtSn_1−xM_x phases. PtSnGa catalyst with a Pt/(Sn+Ga) molar ratio of 1.72 showed a bimodal particle distribution and a Pt phase was identified. Differences in surface structures were also revealed by the performance of catalysts in the dehydrogenation of n-hexane. For PtSnIn and PtSnTl (Pt/(Sn+M) molar ratio of about 1) the dehydrogenation was favoured. In contrast, PtSnGa catalyst yielded hydrogenolysis products. Photoelectron spectra showed the Pt 4f_7/2 level at a binding energy of 70.0–71.8 eV in all cases. Moreover, the FT-IR spectra of chemisorbed CO on the PtSnGa showed a slight shift in the ν(CO) toward higher values with respect to the monometallic catalyst, pointing to an electronic effect in accordance with photoelectron spectroscopy.     

Retention behaviour of carboxylic acid methyl esters in supercritical fluid chromatography

The study on retention behavior in supercritical fluid chromatography (SFC) is necessary to understand the mechanism of the various interactions in SFC. The retention of SFC in carboxylic acid methyl ester/polymethylsiloxane/CO2 system was studied systematically and the retention behavior of this kind of compounds under various typical operation conditions was described using the method of an alternative unified theory of chromatographic retention. The results illustrated that expression: Ink.= a + b/T + cp + dp/T + ep2/T can be used to describe quantitatively the retention behavior of carboxylic acid methyl ester/polymethylsiloxane/CO2 system in the ranges of reduced density from 0.549 to 1.411. It was also found that the entropy of solute in stationary phase is dependent on the density of supercritical fluid (SF) under typical operating conditions of SFC.     

一个广义时滞人口增长模型解的渐近性

考虑一个广义时滞人口增长模型，获得了它的每个正解当ｔ→∞时趋于其正平衡点的充分条件。     

动力系统的胞映射—点映射法及应用

对动力系统的胞映射法进行了改进，采用点映射法对胞映射法的计算结果进行后处理，求得精确的周期运动和吸收域，将胞映法和点映射法结合起来，有较高的计算精度和效率。     

一阶中立型差分方程的振动性与渐近性

讨论了一类一阶中立型差分方程的振动性及其非振动解的渐近性，获得了一些充分性判据，推广了一些已有文献中的结果。     

新阴极材料CrO3—MoO3的合成及电性能研究

本文首次报导应用简单工艺，在常压下制备ＣｒＯ３－ＭｏＯ３合成材料。对该材料的结构特征及电性能进行了测试和研究。结果表明，ＣｒＯ３－ＭｏＯ３是一种新型的阴极材料。它不仅具有良好的放电性能，而且与ＣｒＯ３相比，它的毒性、腐蚀性和吸水性均大为降低，可直接作为固体电池的新阴极材料。     

高速磨削加工的残余硬度

研究了淬硬钢回火硬度与回火温度的关系．建立了回火硬度与回火温度关系的回火效应模型。磨削热导致回火引起淬硬钢磨削后表面硬度变化。通过合并磨削热模型和回火效应，可以预测工件磨削后的表面硬度变化。进行了45^#钢的高速磨削试验．研究了工件速度和磨削深度对磨削后表面硬度的影响。试验值与预测值能够较好吻合。