阳离子交换树脂催化合成1—萘乙酸甲酯的研究

本文研究了用强酸性阳离子交换树脂作催化剂,１—萘乙酸和甲醇直接酯化合成１—萘乙酸甲酯的反应。考察了催化剂用量,反应物料配比,反应时间等因素对产率的影响,通过正交实验,找到了较佳反应条件：当催化剂用量为反应液的３％,醇酸摩尔比为２０～３０,在回流温度下反应４小时,酯的收率＞９２％,纯度＞９９％。该法工艺简单,操作方便,无三废污染,适合工业化生产。     

一类非线性拟抛物方程的初边值问题

考虑一类非线性拟抛物方程ｕｔ－ｕｘｘｔ＋ｆ（ｕ）－ｇ（ｕｘ）ｘ＝ｈ（ｘ,ｔ）的初边值问题．证明了整体强解的存在唯一性,并讨论了对应非负初值解的非负性、正则性、渐近性及爆破问题．     

Fuzzy导集算子与Fuzzy拓扑

在Ｉ＾Ｘ上,定义了Ｆｕｚｚｙ半导集算子与Ｆｕｚｚｙ导集算子,讨论了它们与拓扑的关系,借助于文献（３）中提出的强导集概念,得到：若ｄ是Ｘ的Ｆｕｚｚｙ导集算子,则在Ｘ上唯一存在一个Ｆｕｚｚｙ拓扑ｆ,使得（Ｘ,Ｆ）是Ｆｕｚｚｙ准Ｔ０空间,且在（Ｘ,Ｔ）中Ｆｕｚｚｙ集Ａ的强导集恰是Ａ在ｄ下的像ｄ（Ａ）。     

建设农业强省的基本思路

根据广西作出建设农业强省的战略决策,结合广西农业发展的现状,提出广西建设农业强省应转变传统的观点和思维方式,把农业看成包括农业科研、农业管理与服务、农业产品加工与销售等构成的现代农业新概念。把发展养殖业作为建立高效农业结构体系实现现代农业强省的突破口。让农民自主经营、自主决策,农产品集中出售,建立与农民利益直接结合的机制。充分发挥科学、教育、推广“知识网络”的作用,提高农业劳动者素质。     

关于极大极小定理的一点注记

本文证明了关于Von Neumann型极大极小原理的许多结果,可作为论文“不动点型极大极小定理的一点推广”的直接结论。     

交联聚苯乙烯强－弱碱树脂的合成及脱色性能研究

交联聚苯乙烯氯甲基化后，分别与甲胺（或二甲胺）、三甲胺（或α－甲基吡啶、二甲基乙醇胺）混合胺化试剂进行亲核取代反应，合成了一系列同时带有强－弱碱功能基的交联聚苯乙烯树脂，并表征了这些树脂的结构，测定了树脂对甜菊甙的脱色性能，结果表明，这些树脂功能基碱性适中，脱色容量较高，甜菊甙损失较少，再生效率高。     

Crystal Structures of 1,5,9,18,22,26-Hexaaza[11.11]-p-cyclophane Adducts; Two-dimensional Supramolecular Networks

Two newly identified supramolecular structures arise from self-assembly of the macrocyclic 1,5,9,18,22,26- hexaaza[11.11]-p-cyclophane salts with o-nitrophenol (C₂₈H₅₀N₆)⁴⁺·4(C₆H₄NO₂O)⁻ (1) and with HCl (C₂₈H₅₂N₆)⁶⁺·6Cl^-·4H₂O (2). In both cases two-dimensional supramolecular sheets are formed.     

担体对Fe—MnO催化剂CO＋H2反应性能的影响

考察氧化物担体对Fe-MnO催化剂反应性能影响的结果表明,担体的类型对Fe-MnO催化剂CO加氢反应性能影响很大,其低碳烯烃选择性相差悬殊,Al_2O_3、SiO_2和MgO担载的Fe-MnO催化剂都不利于低碳烯烃的生成,而TiO_2担载的Fe-MnO催化剂则具有较高的烯烃选择性和催化活性。从担体-金属相互作用本质的差异,研究了担体对金属活性组分化学状态的影响及催化活性相与F-T合成烯烃的关系,发现担体-金属间的电子效应有利于催化剂活性和选择性的提高,其它物理化学效应引起的相互作用则不利于改善催化剂性能;还表明Fe_(?)C是催化活性相,Fe~(2+)物种的存在不利于提高烯烃的选择性。     

Asymmetric Intramolecular Hydroalkoxylation of Unactivated Alkenes Catalyzed by Chiral N‐Triflyl Phosphoramide and TiCl4†

By using a combination of a chiral N‐triflyl phosphoramide and TiCl₄ as the catalyst, a new process for asymmetric intramolecular hydroalkoxylation of unactivated alkenes was developed, producing various chiral tetrahydrofuran derivatives in 51%—99% yields with 30%—71% ee's.     

Synthesis of Nickel Supported Catalysts for Hydrogen Production by Sol-Gel Method

SiO₂ and Al₂O₃ supported Ni catalysts were synthesized in the form of xerogels: the SiO₂ based materials were prepared starting from Ni propionate or glycolate salts and reacting them with tetraethoxysilane (TEOS) in propionic acid, Si(ethylene glycolate) or sodium silicate. The Al₂O₃ supported catalysts were prepared similarly from Ni propionate salts with Al iso-propoxide salts. Narrow metal particles and strong metal support interactions are observed in the sol-gel catalysts. The metal dispersion was higher for Al₂O₃ based materials than the SiO₂ ones and it deeply depends on the Ni precursor for the silica supported Ni. Wet impregnated oxides with similar Ni loading have higher metal surface area than those from sol-gel processing. The influence of surface differences on the catalytic activity of the materials was studied following the CH₄ and CO₂ reaction in dry reforming conditions by pulse reaction tests.