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71.
We prove that the Hudson-Parthasarathy equation corresponds, up to unitary equivalence, to the strong resolvent limit of Schrödinger Hamiltonians in Fock space and that the symmetric form of this equation corresponds to the weak limit of the Schrödinger Hamiltonians.Translated fromMatematicheskie Zametki, Vol. 60, No. 5, pp. 726–750, November, 1996.  相似文献   
72.
The irreversible macroscopic dynamics of the Josephson junction coupled to external wires acting as a current source is derived rigorously from the underlying microscopic Hamiltonian quantum mechanics. The external systems are treated in the singular coupling limit. The use of this limit is explicitly justified via an interpretation of the singular coupling limit in terms of the relative magnitudes of system, reservoir, and coupling energies. The qualitative behavior of the macroscopic dynamical equations is shown to depend sensitively and crucially on the interaction between the wires and the superconductors and on the size of the wires: the dc Josephson effect only happens when one lets Cooper pairs be driven into the junction by collective (i.e., small) reservoirs.  相似文献   
73.
A 11-complex of trinitrophenol with benzyldimethylamine (1) and a 111-complex, the product of the interaction of benzyldimethylamine, glycidyl phenyl ether, and phenol (2), have been synthesized and characterized by means of X-ray analysis. Complex1 is a precursor for the catalysts of selective isocyanate cyclotrimerization, while complex2 is one of those catalysts. In the crystal structure complex1 forms H-bonded cationic-anionic aggregates with proton transfer from phenol to the N-atom of the tertiary amine. Complex2 crystallizes as a monohydrate (2a) with a strong H-bond between the quaternary ammonium and phenolic components, and exists in crystals in the form of globular H-bonded dimeric hydrates. Possible pathways of dissociation of complex2a are discussed. The data obtained may be used as a basis for further interpretation of the regularities of cyclotrimerization of isocyanates catalyzed by complexes of this type.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No 1, pp. 92–97, January, 1993.  相似文献   
74.
We derive a number of new results for correlated nearest neighbor site percolation onZ d. We show in particular that in three dimensions the strongly correlated massless harmonic crystal, i.e., the Gaussian random field with mean zero and covariance –, has a nontrivial percolation behavior: sites on whichS x h percolate if and only ifh c . with0 c < . This provides the first rigorous example of a percolation transition in a system with infinite susceptibility.  相似文献   
75.
The new chelate resins, abbreviated as PNBMZs and PBBMZs based on epoxide polymer, were synthesized by polycondensation of N,N-diglycidyl-4-glycidyloxyaniline or 1,4-bis(2,3-epoxypropyl)benzene with the primary amine group of 1,3-bis(benzimidazol-2yl)propylamine (BBPAH). The ion exchangers contain 2.71-3.23 mmol of the ligand contents per gram of the resin. Batch extraction capacities were determined for the metal chloride salts in buffer solutions in the pH range from -1 to 6.0. The chelate resins were very selective for Cu^2+, Zn^2+, Cd^2+ in the presence of other divalent transition metal ions. The maximum uptake capacities of PNBMZ (synthetic molar ratio = 1:1.5) under non-competitive condition were found to be 0.94 mmol/g for Cu^2+ at pH = 2, 1.3 mmol/g for Cd^2+ at pH = 1 and 1.75 mmol/g for Zn^2+ at pH = -1 respectively. While in the case of PBBMZ, it was 1.39 mmol/g for Cd〉 at pH = 1. The metal-uptake behaviors for both of them showed strong pH dependence, and their extraction capacities increase with decreasing pH. The uptake of Cu^2+ by the resin PNBMZs at pH = 1 was found to be rather fast with t1/2 = 18 min. Metal-uptake experiments under competitive conditions also confirm that the chelate resins have a high selectivity for Cu^2+, Zn^2+, Cd^2+ and the contrary pH dependence.  相似文献   
76.
Organic nanocrystals of N-4-nitrophenyl-l-prolinol (NPP) have been grown in sol-gel matrices prepared from silicon alkoxide precursors. Our process is based on the control of the nucleation and growth kinetics of the dye in the pores of dense gels. Nanocomposites gel-glasses are obtained with a high optical quality due to the small size of the nanocrystals (10-20 nm). Differential scanning calorimetry experiments evidenced clearly the melting point of NPP nanocrystals, which is registered 51°C above that of NPP powder. Micro-Raman and solid state NMR spectroscopies allowed us to demonstrate that our nanocrystallization process does not chemically modify NPP molecules. We specified also the nature of interactions existing between the NPP nanocrystals and the xerogels. These strong interactions, which explain the important increase of the melting point of the nanocrystals in comparison to the NPP powder, are hydrogen bonds between nitro groups of NPP and uncondensed silanol functions of the silicate network.  相似文献   
77.
阿斯美胶囊中四种组分的高效液相色谱分析   总被引:2,自引:0,他引:2  
建立了反相高效液相色谱法测定阿斯美胶囊中氨茶碱、盐酸甲氧非那明、马来酸氯苯那敏及那可汀四种组分的含量。色谱柱为SpherisorbC8,5μm,200cm×40mmID,流动相为体积分数05%的三乙胺溶液(磷酸调节pH55)+乙腈+甲醇(550+368+82),检测波长为264nm,线性范围分别为:氨茶碱3125~250mg/L,γ=09996,盐酸甲氧非那明15625~1250mg/L,γ=10000,马来酸氯苯那敏25~200mg/L,γ=09999,那可汀875~700mg/L,γ=09999;回收率(n=3)分别为1012%,1008%,999%,995%;精密度:日内平均RSD(n=6)分别为07%,04%,04%,06%;日间平均RSD(n=3)分别为10%,10%,11%,12%。  相似文献   
78.
杨旭  赵卫东 《计算数学》2022,44(2):163-177
本文研究跳适应向后Euler方法求解跳扩散随机微分方程在非全局Lipschitz条件下的强收敛性.通过克服方程非全局Lipschitz系数给收敛性分析带来的主要困难,我们成功地建立了跳适应后向Euler方法的强收敛性结果并得到相应的收敛率.最后,我们通过数值试验对前文所得理论结果做进一步的验证.  相似文献   
79.
《Discrete Mathematics》2022,345(7):112796
We introduce the active partition of the ground set of an oriented matroid perspective (or morphism, or quotient, or strong map) on a linearly ordered ground set. The reorientations obtained by arbitrarily reorienting parts of the active partition share the same active partition. This yields an equivalence relation for the set of reorientations of an oriented matroid perspective, whose classes are enumerated by coefficients of the Tutte polynomial, and a remarkable partition of the set of reorientations into Boolean lattices, from which we get a short direct proof of a 4-variable expansion formula for the Tutte polynomial in terms of orientation activities. This formula was given in the last unpublished preprint by Michel Las Vergnas; the above equivalence relation and notion of active partition generalize a former construction in oriented matroids by Michel Las Vergnas and the author; and the possibility of such a proof technique in perspectives was announced in the aforementioned preprint. We also briefly highlight how the 5-variable expansion of the Tutte polynomial in terms of subset activities in matroid perspectives comes in a similar way from the known partition of the power set of the ground set into Boolean lattices related to subset activities (and we complete the proof with a property which was missing in the literature). In particular, the paper applies to matroids and oriented matroids on a linearly ordered ground set, and applies to graph and directed graph homomorphisms on a linearly ordered edge-set.  相似文献   
80.
图G的强边染色是指对图G进行正常边染色使得任意长度为3的路的三条边染不同的颜色.图G的强边色数,记为χ’s(G),是使得图G是强k边着色的最小正整数kk.2015年,Zang [arXiv:1510.00785]证明了:最大度△(G)=5的图G,χ’s(G)≤37.本文证明了:最大度△(G)=5且最大平均度小于8/3(或者14/5)的图G,χ’s(G)≤13 (或者14).另外,本文证明了:最大度△(G)≥3的不含K2,3-图子式的图G,χ’s(G)≤4△(G)-6,这个界是紧的.  相似文献   
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