Charge transport properties of MDMO PPV thin films cast in different solvents

Charge transport properties in thin films of Poly(2‐methoxy‐5‐(3′,7′‐dimethyloctyloxy)‐1,4‐phenylenevinylene) (MDMO PPV) cast using either chloroform (CF), toluene (TOL), or chlorobenzene (CB) as solvent were investigated. Hole mobility (μ) in these thin films measured using time‐of‐flight transient photoconductivity showed an increasing trend with respect to the solvent used in the same order, that is, μ_CF (2.4 × 10^?7 cm²/Vs) < μ_TOL (6.9 × 10^?7 cm²/Vs) < μ_CB (2.3 × 10^?6 cm²/Vs). Observed variations in mobilities were attributed to different morphologies of MDMO PPV chains in thin films cast using the aforesaid solvents. Nature of the interchain interactions and aggregate formation were obtained using photoluminescence (PL), Raman spectroscopy, and AFM studies. Ratio of PL peak intensities of 0–0 and 0–1 transitions, which is a direct measure of interchain interaction, was the highest in CB and lowest in CF. Variation in the relative intensities of out‐of‐plane wagging of vinylene group (～963 cm^?1 mode) in Raman spectra suggested different extent of coiling of polymer chains in these thin films. From these observations, it was elicited that aggregate size and interchain interactions are highest in CB and least in CF. AFM‐based topographic images of thin films further supported these variations in the size of aggregates. Variation in the aggregate sizes and interchain interactions explained the corresponding variation in the mobility. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1431–1439     

New ceramic microfiltration membranes from mineral coal fly ash

This work aims to develop a new mineral porous tubular membrane based on mineral coal fly ash. Finely ground mineral coal powder was calcinated at 700 °C for about 3 h. The elaboration of the mesoporous layer was performed by the slip casting method using a suspension made of the mixture of fly ash powder, water and PVA. The obtained membrane was submitted to a thermal treatment which consists in drying at room temperature for 24 h then a sintering at 800 °C. SEM photographs indicated that the membrane surface was homogeneous and did not present any macro defects (cracks, etc.). The average pore diameter of the active layer was 0.25 μm and the thickness was around 20 μm. The membrane permeability was 475 l/h m² bar.This membrane was applied to the treatment of the dying effluents generated by the washing baths in the textile industry. The performances in term of permeate flux and efficiency were determined and compared to those obtained using a commercial alumina microfiltration membrane. Almost the same stabilised permeate flux was obtained (about 100 l/h m²). The quality of permeate was almost the same with the two membranes: the COD and color removal was 75% and 90%, respectively.     

Influence of chitosan and epoxy cross-linking on physical properties of binary blends

In this study, blends of chitosan (Cs) and bisphenol-F-diglycidyl ether (3.80 × 10^?3 to 3.80 × 10^?2 mol) were cast by the solution route. FT-IR results suggested that chitosan was cross-linked at terminal amino groups through diepoxide linkage. The chitosan films became less flexible and stiffer upon reaction with epoxy. Blending improved percentage elongation (31%) and toughness (10 MPa), whereas Young’s modulus (145 MPa) and tensile strength (45 MPa) were decreased. Extent of weight loss in Cs/BPFDGE was lower (15%) than that of original precursors (chitosan 33%). Moreover, blending of chitosan with BPFDGE increased water absorption properties due to generation of hydrophilic ?OH groups.     

连续铸钢凝固传热过程数学模型及仿真算法研究

连续铸钢计算机控制系统的建立,是连铸生产自动化的保证。为了进一步提高和完善该系统的控制功能,运用计算机辅助手段对连续铸钢凝固传热过程的数学模型(尤其是二冷水控制模型)进行仿真分析与研究,具有特别重要的意义。 本文主要介绍了连续铸钢凝固传热过程数学模型的建立、仿真算法的数学抉择、连续铸钢凝固传热过程计算机仿真软件包的主要内容及该软件包应用于实际的结果分析等。     

干砂消失模铸造工艺过程及铸件质量控制

总结了干砂消失模铸造技术的研制经验，探讨了主要工艺因素对消失模铸造工艺过程的影响，介绍了典型铸件的干砂消失模铸造工艺和技术经济效果。     

铸造铝青铜的摩擦特性与机械性能

针对高压齿轮泵侧板的工作特点，熔制了五种铸造铝青铜并分别进行了拉伸性能、摩擦特性和耐磨性实验，为该侧板国产化提供了必要的准备。     

平衡补缩法对铸件结晶性能的影响

概述了平衡补缩铸造方法，并根据金属在压力下的结晶理论，分析了强制补缩铸造条件下，铸件不同凝固阶段的温度场特征，外加压力强制补缩可以大大增加晶核数目，因而可获得细晶粒组织的铸件。     

用大孔出流理论解决大中型盘类铸件浇注系统设计问题

通过对电线电缆设备中的各类大、中型绞盘类铸件的浇注系统的研究，分析了用传统的阿暂公式计算此类铸件的浇注系统，致使铸件易产生浇不足、冷隔、夹砂、粘砂等铸造缺陷的原因介绍了用大孔出流理论设计绞盘类铸件的浇注系统的方法，考虑了浇口比这一影响因素，可有效防止上述缺陷，使铸件的废品率降低，质量提高     

球铸管件试压设备的设计与研究

本文对球铸管件试压设备的总体设计方案、结构类型、液压系统、电气控制系统进行了研究，并经工厂使用证明，结构合理，使用方便，制造成本低，生产效率高。     

带液芯控制的异型坯连铸二冷区动态控制模型

本文以马钢三炼钢异形坯连铸机为目标机型 ,在凝固传热数学模型的基础上 ,自行开发了一种带液芯控制的异型坯连铸二冷区动态控制模型。采用切片法进行目标温度的动态跟踪 ,通过计算机仿真验证了模型的可靠性