油松容器苗和裸根苗生长与造林效果对秋季施肥的响应

【目的】探究不同秋季施肥处理条件下油松容器苗和裸根苗苗期生长、养分积累和造林效果的差异,为生产上培育油松良种壮苗提供理论基础和技术支持。【方法】以大田培育的当年生油松播种容器苗和裸根苗为研究对象,设置0(对照)、12、24、36 mg/株4种秋季施肥水平,于90%以上苗木形成顶芽后进行施肥处理,并于翌年进行雨季造林试验。测定造林前的苗高、地径、生物量、根冠比、养分含量及造林后苗木成活率和苗高、地径相对生长量等指标,分析出圃苗木性状与造林效果之间的相关性。【结果】秋季施肥24 mg/株处理下的油松容器苗苗高、地径、生物量、氮、磷、钾含量均表现最佳,该处理下容器苗整株生物量、氮、磷、钾含量较对照分别增加了41.8%、31.4%、65.6%和48.8%;油松裸根苗受秋季施肥影响较小。容器苗氮含量在各器官中的分布从大到小表现为根>叶>茎,裸根苗氮含量在各器官中的分布从大到小表现为叶>根>茎;磷、钾含量在容器苗和裸根苗各器官中的分布从大到小均表现为叶>根>茎。雨季造林试验结果显示,油松造林效果受苗木类型影响显著,容器苗造林当年和第2年春季的苗高、地径相对生长量...     

基于Bert股吧舆情分析的特征融合股价走势预测研究

传统股价预测模型往往只考虑时序性数据且局限于模型自身机制,而忽略舆情对股价的影响,导致预测精度不高,针对该问题,提出基于 Bert 股吧舆情分析的特征融合预测模型对股价收盘价进行涨跌幅预测。 首先,采用Bert 自然语言处理对股吧舆情以及公司公告政策进行情感分类,并转化为虚拟变量,构建金融舆情情感特征库;然后将金融舆情特征库和时序性数据合并构建特征融合矩阵;最后输入长短期记忆网络模型(LSTM)进行股价收盘价预测,并得出股价的涨跌结果。 以华银电力(600744. SH)为例进行实证分析,实验结果表明:引入股票情感特征后的模型,得到的股价走势准确率上升了 8. 63%,预测收盘价的回归指标 FMAPE FRMSE 分别下降了 23. 59%、22. 9%,R2 提高了 8. 11%,证明引入新的舆情情感特征在实际预测中能提高股价预测的准确率,可以作为精准预测股价走势的手段。     

Titantetrafluorid – Eine überraschend einfache Kolumnarstruktur

Titanium Tetrafluoride – a Surprising Simple Column Structure For the first time single crystals of TiF₄ have been obtained by solvothermal decomposition of (O₂)₂Ti₇F₃₀ in anhydrous HF. The colourless, transparent needles crystallize orthorhombic in spacegroup Pnma–D (No. 62) with a = 2 281.1, b = 384.8, c = 956.8 pm, Z = 12. The new type of structure is dominated by isolated columns of corner-linked TiF₆-octahedra.     

Preparation of enantiomerically pure 1,1′-bi-2-naphthols from 85% cinchonine and 1,1′-bi-2-naphtholboric anhydride

A possibility of preparation of enantiomerically pure 1,1′-bi-2-naphthols using an impure cinchonine has been examined. The solid and the mother liquor formed from the reaction of 1,1′-bi-2-naphtholboric anhydride and 85% cinchonine in toluene could give optically pure (S)-(−)- and (R)-(+)-1,1′-bi-2-naphthol after acidification and kinetic crystallization, the overall yields were 40% and 28%, respectively. Supported by the National Natural Science Foundation of China (2937206) and the Natural Science Foundation of Hubei Province (93J27) Xiong Ying, born in 1971, Graduate student     

可持续发展中的代际财富均衡问题研究

运用可持续发展理论,探讨了代际财富均衡的内含,指出资源存量与环境质量是参与代际财富转移的重要部分,资源的分配管理的一定质量环境的保护要本着代际机会均等的原则,建立了代际财富均衡的模型,说明资源资本的增殖积累是缓解代际矛盾的重要途径。     

干湿循环法制备抗菌性 5A 沸石

本文探索了制备抗菌性沸石的新方法———干湿循环处理法,采用５Ａ沸石分别与抗菌性离子Ｚｎ２＋、Ａｇ＋、Ｃｕ２＋的溶液进行干湿循环处理,制备抗菌性５Ａ沸石。研究了反应条件,如温度、浓度、循环次数对沸石中抗菌性离子含量的影响,找出了最佳反应条件。测试了抗菌性５Ａ沸石的耐洗涤性能和抗菌性５Ａ沸石对黑曲霉菌、大肠杆菌及嗜热脂肪芽胞杆菌的抗菌效果。研究结果表明,干湿循环法制备抗菌性沸石,具有抗菌性离子含量多,抗菌性能好,方法简便,反应时间短,节约原料等优点。     

Preparation and characterization of Fully stoichiometric SrCoO3 by electrochemical oxidation

A nearly stoichiometric SrCoO₃ phase had been prepared up to now only using high oxygen pressure. A new method for preparing fully stoichiometric SrCoO₃ has been proposed using electrochemical oxidation. Brownmillerite-type SrCoO_2.50 is oxidized into a completely stoichiometric perovskite at a potential of 500 mV for 180 hours at room temperature in alkaline media (1 M KOH). The oxidized phase has a cubic unit cell (a=383.5 pm). It is metallic and, at temperatures below T=280 K, it shows ferromagnetic behavior. The magnetic moment at 0 K is 2.1 μ_B. The physical properties of SrCoO_3.00 have been explained in terms of partial occupancy of a σ*e band.     

Coupling of thermal desorption in modified closeable sampling columns with wide-bore capillary gas chromatography and mass spectrometric detection

In contrast to usability of Curie-point pyrolysis at 700°C directly attached to gas chromatography-mass spectrometry (GC-MS) for determination of organic wood preservatives in waste wood samples the investigation method reported here consists of thermal desorption at temperatures about 260°C in connection with GC-MS for peak identification or GC with flame ionization detection for quantitative analyses. So-called “modified closeable sampling columns” are used as batch-reactor in thermal desorption experiments. Desorbed vapours can be introduced on capillary columns without sample discrimination and without a disturbing lost of resolution. In this manner a lot of individual polycyclic aromatic hydrocarbons were determinated in waste wood samples, especially in railway sleepers.     

Glass capillary gas chromatography of amino acid enantiomers

Glass capillaries coated with Chirasil-Val, a chirally functionalised polysiloxane, are capable in principle of resolving all protein amino-acid enantiomers in a single run and within a short analysis time, thus allowing for example the quantitative amino acid determination by enantiomer labelling. The elution characteristics of the individual amino acids however are also dependent upon the chemical nature of the capillary wall surface, and a surface pretreatment is found to be necessary if all protein amino acids are to be analysed. Of the various methods of pretreatment tested, etching of borosilicate glass with gaseous HCl followed by deposition of colloidal silicic acid is considered to be the most suitable.     

Darstellung und Kristallstruktur von LnAl3Br12 (Ln = La,Ce, Pr,Nd, Sm,Gd) und thermischer Abbau zu LnBr3

Preparation and Crystal Structure of LnAl₃Br₁₂ (Ln = La, Ce, Pr, Nd, Sm, Gd) and Thermal Decomposition to LnBr₃ LnAl₃Br₁₂ (Ln = La, Ce, Pr, Nd, Sm, Gd) was prepared in crystalline form for the first time. The crystal structures of LaAl₃Br₁₂, PrAl₃Br₁₂, and NdAl₃Br₁₂ were determined on single crystals by X-ray methods. The isotypic compounds crystallize with trigonal symmetry, space group P 3₁12, Z = 3. A structural comparison to lanthanoide chloroaluminates of equal composition is given and thermal decomposition of LnAl₃Br₁₂ (Ln = Nd) to the corresponding lanthanoide tribromide is described.