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21.
Time-dependent reorientations of resorcinol-based acridinidione (ADR) dyes in glycerol were studied using steady-state and
time-resolved fluorescence studies. The difference between fluorescence anisotropy decays recorded at 460 nm when exciting
at 250 nm and those obtained when exciting at 394 nm are reported. When exciting at 394 nm, the fluorescence anisotropy decay
is bi-exponential, while on exciting at 250 nm a mono-exponential fluorescence anisotropy decay is observed. We interpret
this in terms of different directions of the absorption dipole at 394 and 250 nm with the emission dipole respectively, which
is experimentally validated and further analysed as a prolate model of ellipsoid. 相似文献
22.
油溶性银漂染料的合成及性能研究 总被引:1,自引:1,他引:0
合成并鉴定了黄色、品红色及青色共11个油溶性偶氮染料,研究了染普在溶剂中的光谱性质和油溶性,结果表明,各染料色光纯正、有害吸收少,分子支链度大的染料Y-2、Y-6等具有良好的油溶性,可望用于银漂感光材料。 相似文献
23.
The constants of binding dye molecules with the micelles of sodium dodecyl sulfate are determined using quenching of delayed fluorescence of acridine dyes by sodium iodide in aqueous–micellar solutions. Kinetic equations have been composed that describe the processes of deactivation of the excited states of dyes. By solving these equations at the concentration of the quencher sodium iodide corresponding to the minimum lifetime of triplet states and at the concentration of micelles corresponding to the least value of the delayed fluorescence quenching rate constants, we obtained the constants of binding dyes with micelles equal to 1.3·107, 2.9·107, and 3.1·107 M–1 for trypaflavine, acridine orange, and acridine yellow, respectively. We calculated the rate constants of quenching of the triplet states of the molecules of dyes by iodide ions (I
–) that decreased in transition from trypaflavine to acridine orange and acridine yellow. 相似文献
24.
25.
氧鎓盐类化合物因具有较强的亲电性,在有机合成[1]及电照相体系[2]中存在着广泛的应用前景.由于它们还表现出较强的荧光发射能力[3],因而在作为激光工作材料[4,5]方面也受到重视.正因如此,这类化合物的光物理和光谱特性引起了许多化学家的兴趣.氧钠盐化合物溶液的荧 相似文献
26.
碱性二苯基萘基甲烷染料褪色分光光度法测定肝素 总被引:5,自引:0,他引:5
肝素(Heparin, Hep)由葡萄糖胺磺酸、葡萄糖醛酸和艾杜糖醛酸组成, 在水溶液中由于其酸性基团的离解而成为带多个负电荷的大阴离子[1].肝素具有广泛的生物学功能, 在人体内由肥大细胞分泌而自然存在于血液中, 在体内外均有延缓或阻止血液凝固的作用. 肝素或其衍生物还可用于调血脂、抗血栓、改善血液流变学指标、抗炎、抗过敏及免疫调节等, 是重要的生化药物之一 [2]. 对不同的疾病, 肝素有不同的最适剂量, 临床上常采用生物方法 [3]来进行监控. 但由于受生物个体的影响较大, 故使其应用受到限制. 此外, 分光光度法 [1,4,5]、荧光法[6]、HPLC法[7]、细管电泳法[8]及电化学传感器[9]已用于肝素的测定, 其中分光光度法由于操作简便、快速、仪器价廉和灵敏度较高等优点而得到重视. 相似文献
27.
28.
Guo Yang Zhu Rong Wang Guo Hua Liu Li Qun Xu Bei Zhang Xia Qin Wu College of Life Environment Science Shanghai Normal University Shanghai China State Key Laboratory of Chema/Biosensing Chemometrics Hunan University Changsha China 《中国化学快报》2007,18(6):633-635
Starting from the hydroxylamine (dimethyl amino ethanol, triethanolamine) and 1,3-propane sultone, a series of hydroxyl and sulfonyl dual-functionalized zwitterionic salts and corresponding acidic room temperature ionic liquids have been synthesized. The hydroxyl groups of the synthesized substances were confirmed by the 1H NMR measurement. These zwitterionic salts and ionic liquids may be used for synthesizing other functionalized ionic liquids or ionic liquid-polymer (polyelectrolyte). 相似文献
29.
A study of migration of the active components of oxygen sensors into food is presented. Six types of sensors, based on different oxygen sensitive dyes (two metalloporphyrins and one ruthenium dye), polymers (polystyrene and polysulfone) and support materials, were exposed to a number of standard ‘food simulants’ recommended by FDA/EU guidelines and then assayed for migration or sensor components and changes in oxygen calibration. Both metalloporphyrin sensor dyes leached only in olive oil and in 95% ethanol (used as a positive control), at maximum levels of 19.22 μg/dm2 for PtOEPK and 113.96 μg/dm2 for PtTFPP. The RuDPP dye showed maximum leaching in 95% ethanol (25.19 μg/dm2) while also migrating in an acidic aqueous simulant. Planar supports such as polyester tended to enhance the stability of the sensor. Migration of the styrene monomer from the polystyrene encapsulation medium was concluded to be low enough to be insignificant. Migration of sensor components was shown to correlate with the changes in sensor response to oxygen. Based on these results, sensor combinations were ranked on the basis of their resistance to leaching and their general stability, safety and suitability for use on a large scale in packaged foods and related food applications was proven. 相似文献
30.
烷基季铵盐插层剂的合成及应用 总被引:1,自引:0,他引:1
Three novel intercalation agents were synthesized for the first time, which arose from oleic acid diethylenetriamine or triethylenetetramine 3 - chloro - 2 - hydroxypropy trimethylammonium choride (CHPTA) and chloroethanol. Organophilic vermicullites were synthesized from sodium type vermiculite by cation exchange with new intercalation agents. The results of X - ray diffraction study showed that the gallery distance of the organophilic vermiculite was enlarged from 1 nm to 5 nm or more. A new idea of making design for intercalation agent was provided. 相似文献