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31.
32.
E. Ferrero J. F. Espeso J. G. de la Campa J. de Abajo A. E. Lozano 《Journal of polymer science. Part A, Polymer chemistry》2002,40(21):3711-3724
A series of polyisophthalamides containing pendent phthalimido groups and flexible side spacers were prepared from four novel diacids and three commercial aromatic diamines. These polyamides were prepared in high yields and with high molecular weights by direct polycondensation with triphenyl phosphite and pyridine as condensing agents. The weight‐average and number‐average molecular weights, measured by gel permeation chromatography, were 70,000–137,000 and 47,000–86,000 g/mol, respectively. The novel polyamides were amorphous and readily soluble and showed glass‐transition temperatures of 150–240 °C, as measured by differential scanning calorimetry. Thermogravimetric analysis showed that the 10% weight‐loss temperatures in nitrogen were 355–430 °C, a significant improvement in thermal stability having been observed with the increase in the side‐chain length. A theoretical quantum mechanical study was successfully carried out to explain these results. Flexible and tough films, cast from polymer solutions, showed tensile strengths of 50–125 MPa. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 3711–3724, 2002 相似文献
33.
秦永祥 《阜阳师范学院学报(自然科学版)》1998,(3)
百米跑模式对于教学和训练具有很高的价值;本文根据百米跑模式原理,结合教学实例论述了模式在教学中的应用,对教师尽快发现及解决百米成绩较差学生存在的主要问题,颇有帮助,并在教学实践中取得了显著地效果。 相似文献
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The rational function optimization algorithm is one of the widely used methods to search stationary points on surfaces. However,
one of the drawbacks of this method is the step reduction procedure to deal with the overstepping problem. We present and
comment on a method such that the step obtained from the solution of the rational function equations possesses the desired
correct length. The analysis and discussion of the method is mainly centered on the location and optimization of transition
states.
Received: 18 June 1998 / Accepted: 17 September 1998 / Published online: 23 November 1998 相似文献
36.
Oxygen Atom Adsorption and Diffusion on Pd Low-index Surfaces and (311) Stepped Surface 总被引:2,自引:0,他引:2
Introduction Atom adsorption on transition metal surfaces has attracted special attention as a base for understanding the fundamental processes of oxidative catalysis. Particularly interesting is the adsorption and diffusion of oxygen on well-defined metal surfaces. An oxygen covered palladium surface, for example, plays a central role in several important reactions such as oxidation of carbon monoxide and ammonia. In particular, the (100), (111), (110) surfaces and the interactions with oxyge… 相似文献
37.
Uniform-sized molecularly imprinted polymer (MIP) beads were prepared using a one-step swelling and polymerization method. The obtained sulfamethazine (SMZ)-imprinted polymer showed high affinity and selectivity toward SMZ and other structurally related sulfonamides in acetonitrile or water-acetonitrile mobile phases, particularly in high aqueous systems. The column performance of the MIPs for SMZ and its analogues could be improved by elevating the column temperature and optimizing the flow rate. The hydrogen-bonding effect plays a significant role in the recognition process of SMZ-imprinted polymer systems in organic media, while the ion-exchange effect, as well as hydrophobic effect, dominates the retention mechanism in aqueous-rich media, in addition to shape recognition. 相似文献
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39.
D.H. Kim J.H. Moon D.W. Lee Y.G. Shul 《Journal of Sol-Gel Science and Technology》2003,26(1-3):403-406
The acid catalyzed sol-gel reaction in the mixed binder system, 3-glycidoxypropyltrimethoxysilane (GPTS)/3-aminopropyltriethoxysilane (APTS) was investigated and one step and two step synthesis process were compared. Hydrolysis product was observed using the 1H, 13C NMR and Raman spectra. Especially, based on the Raman spectra, epoxy ring opening was observed, varying the ratio of GPTS to APTS. The two step process made clear sol, while the one step process resulted in a milky suspension. According to the Raman spectra, the epoxy ring opening reaction kinetics proceeded slower in the two step process than one step process. Throughout the two step process, it was possible to apply the binder for the coating of substrate. 相似文献
40.
给出求解组合预测权系数的回归分析方法,文章首先给出了基于最小二乘和最小一乘准则的线性回归组合预测模型,然后应用最小二乘原理得到权系数最小二乘估计值。由于最小一乘准则下,目标函数不可微,传统的优化规则方法无法求解,故文中提出用基于最小二乘的逐步变权方法进行求解。同时,还给出了百分误差绝对值最小为目标的组合预测模型及权系数求解方法。通过实例分析,表明组合预测模型的预测精度很高,回归效果很显著。 相似文献