Structure and properties of the mesophase of syndiotactic polystyrene—III. Selective sorption of the mesophase of syndiotactic polystyrene

Syndiotactic polystyrene (sPS) has various crystalline forms such as α, β, γ, and δ forms, and a mesophase depending on the preparation method. In this study, we focused on the mesophase with the molecular cavity of sPS, which is obtained by step‐wise extraction of the guest molecules from the sPS δ form. To prepare the mesophase containing different shapes and sizes of the cavity, two kinds of the sPS δ form membrane cast from either toluene or chloroform solution were first prepared and then the guest molecules were removed by a step‐wise extraction method using acetone and methanol. We could succeed in the preparation of two kinds of mesophase with different shapes and sizes of the molecular cavity. Either toluene or chloroform vapor sorption to the sPS mesophase membranes was examined at 25 °C. Sorption analysis indicates that the mesophase with large molecular cavities can mainly sorb large molecules; on the other hand, the mesophase with small cavities can sorb only the small molecules, and is unable to sorb a large amount of large molecule because the cavity was too small to sorb the large molecules. Therefore, the sPS mesophase membrane has sorption selectivity based on the size of the molecular cavity. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 238–245, 2004     

步进扫描时间分辨光谱及其在太阳电池光电导上的应用

建立傅里叶变换步进扫描时间分辨光电导光谱，并研究太阳电池中与转换效率密切相关的少数载流子寿命.实验选取三种典型的硅太阳电池(单晶硅样品1、多晶硅样品2和多晶硅样品3 )，发现其瞬态光电导的上升和衰退曲线可以分别用两个简单的指数函数描述.由于有复合中心的参与，复合过程中少数载流子的寿命比产生过程中的寿命短.为验证实验结果的可靠性，采用了提取样品少数载流子的体寿命和计算其有效扩散长度两种方法.通过与太阳电池暗伏安特性和负载特性研究相结合，进一步分析和讨论了少数载流子寿命与短路电流、开路电压和转换效率的关系.同时探讨了步进扫描时间分辨光谱实验的其他用途. 关键词： 步进扫描 时间分辨 硅太阳电池 瞬态光电导     

One-dimensional non-nearest-neighbor random walks in the presence of traps

A one-dimensional lattice random walk in the presence ofm equally spaced traps is considered. The step length distribution is a symmetric exponential. An explicit analytic expression is obtained for the probability that the random walk will be trapped at thejth trapping site.     

Order conditions for linearly implicit fractional step Runge Kutta methods

^{In this paper, we study the consistency of a variant of fractionalstep Runge–Kutta methods. These methods are designed tointegrate efficiently semi-linear multidimensional parabolicproblems by means of linearly implicit time integration processes.Such time discretization procedures are also related to a splittingof the space differential operator (or the spatial discretizationof it) as a sum of ‘simpler’ linear differentialoperators and a nonlinear term.}     

基于MPEG-4的视频流式传输系统及动态带宽分配方法

提出了一个基于MPEG 4精细可分级编码技术的视频流式传输系统。介绍了系统中主要模块的作用,并重点研究了速率控制模块。速率控制模块采用了适合视频流式传输的动态带宽分配方法。它可以根据实时的网络通道波动状况来动态调整滑动参数,以适应网络波动和高效地利用网络的有限资源。实验结果表明,动态带宽分配方法在动态带宽波动条件下不仅可以使相邻帧间的视频质量更加平滑,而且可以大大提高解码视频图像的总体质量,也就是说可同时改善解码视频的主客观性能。     

压缩偶相干态的制备及其非经典特性

通过保持非耗散介观LC电路的固有频率不变，而使电路参数作阶跃函数变化，就可将介观LC电路由初始的偶相干态制备到压缩偶相干态；在压缩偶相干态下，介观电路系统不仅有非经典的量子压缩效应，而且有非经典的反聚束效应. 关键词： 介观LC电路 单位阶跃函数 压缩算符 压缩偶相干态     

多环节冲击测量系统方波响应时间的计算

实际的冲击高电压测量系统，通常由多个不同特性的环节组成．作者以最简洁的数学推导式，表达了多环节测量系统方波响应时间的计算方法。借助于这一计算方法．讨论了方波源波形非理想时，它对实际方波响应时间测量值的影响。所提出的反映原始方波质量的技术指标，可比“上升时间”更易确定，而且实用性强．     

一种高级计算机语言──SAS语言初探

扼要介绍了ＳＡＳ语言及其关键步（ＤＡＴＡ步和ＰＲＯＣ步）．给出了几个例子，以说明如何使用ＳＡＳ语言。     

对DEBUG实用程序的一点改进──使DEBUG能跟踪“反跟踪软件”

作者提出对ＩＢＭＰＣ系列微机上ＤＥＢＵＧ实用程序的一种改进方法，即通过修改单步中断和断点中断的处理程序，使之能跟踪“反跟踪软件”，这对软件解密和病毒分析无疑是有用的。     

关于用奇异函数求解阶梯形梁变形的两个问题

对于n段阶梯形梁,X_o=0,X_1,X_2,……,X_(n-1)为第一、第二、……、第n段梁左截面的坐标,J_1,J_2,.....,J_n为相应段梁的惯性矩。根据,先将梁惯性矩的倒数用阶梯函数表示:其中此时,梁的挠曲线微分方程为其中E为材料的弹性模量;M(X)为梁的弯矩,由奇异函数法求出。依据奇异函数的积分规则,由(3)式可分别得到梁的转角方程和挠度方程: