对扩散运动中粒子动能平均值发散问题的讨论

从扩散运动的不规则力出发 ,指出了泰勒理论导致扩散运动中粒子动能平均值发散的根源 ,从而提出了解决此问题的一种新的理论模型—即粒子碰撞前速度与碰撞中速度的变化量不应是完全独立的概率变量 .     

Simultaneous imaging of the structure and fluorescence of a supramolecular nanostructure formed by the coupling of π‐conjugated polymer chains in the intermolecular interaction

We fabricated a micrometer‐long supramolecular chain in which π‐conjugated polyrotaxane was coupled. A new experimental setup was designed and constructed, and the simultaneous direct imaging of the structure and fluorescent function was achieved. Furthermore, we identified the formation of a polymer intertwined network and observed novel fluorescence due to a long‐range interaction via this intertwined network over a distance of 5 μm or more without quenching over 15 min in the near field. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 801–809, 2006     

青海城镇体系发展的历史轨迹与动力

青海城镇体系经历了发韧期、奠基期、转型期3个发展历程.在这一过程中,湟水谷地最先拉开了城镇发展的历史帏幕,随后逐步向西扩展进入青海湖地区.宏观上,从农耕区向农牧交错区渗透,进而向游牧区拓展,反映了社会历史进程和地域开发进程的调控作用,因此城镇分布数量和密度呈现出农耕区—农牧交错区—游牧区逐级递减的趋势.中观上,以河流为脉络,城镇发展或溯源而上伸入高原腹地,或向河谷两岸推进,进入山区,表现为从优势生存空间向劣势生存空间的时空转化,城镇数量与密度呈现出川水地区—浅山地区—脑山地区的递减趋势.微观上,河谷农耕区城镇选址多位于河流阶地上,土地肥沃,取水便利;而牧区城镇的选址却往往与水草丰美的牧场相关,映射出古代城镇对自然条件和自然物质基础的依赖性.总体而言,青海省城镇兴起和发展的动力,主要来自于外部中央行政建制和军事据点的设置,而非城镇内部社会经济自我发展.就单个城镇而言,民族文化、民族宗教与民族贸易的亲合关系和响应力,是城镇成长的主要推进剂.     

Observation of baker’s yeast strains used in biotransformation by atomic force microscopy

Different strains of baker’s yeast(Saccharomyces cerevisiae) were imaged with an atomic force microscope (AFM). The images of uncoated and nonfixed samples were reproducible with high-constrast and nanometer-resolution. Molecules from the polysaccharide surface of the cell wall were pictured and the distance of atoms was measured. The preparation of samples was easy, suggesting that AFM is a useful tool in this type of analyses.     

微型硅谐振式力传感器的振动分析

介绍了谐振式力传感器的工作原理，并从理论上和实验上对中科院合肥智能所研制的第一代微型硅谐振梁（３×０．４×０．０４５ｍｍ＾３）式测力传感器进行了全面的振动分析，所得结构为其进一步优化设计提供了科学根据，文中使用的实验分析方法，为其它微小物体的动态和识别提供了一条有效途径。     

安装误差对正交弧齿锥齿轮副接触区影响的分析

本文从理论上分析了正交弧齿锥齿轮副的各种安装误差对啮合接触区的单独影响和综合影响,建立了安装误差作用下齿面接触区的数学模型,并通过具体实例讨论了各项安装误差对啮合接触区单独影响和综合影响的程度以及综合影响的“叠加效应”和“互补效应”,提出了满足接触要求前提下降低安装要求的措施.     

Vibrational assignment, <Emphasis Type="Italic">ab initio</Emphasis> calculation and normal coordinate analysis of 2,2′-biquinoline

The vibrational wavenumbers and the fundamental modes of 2,2′-biquinoline were obtained by density functional theory (DFT) with the B3LYP functional using the 6-31G(d,p) basis set. The calculated wavenumbers were scaled by a single factor of 0.965 to correct them for vibrational anharmonicity, but the force constants were overestimated. Normal coordinate analysis of the molecule was also carried out by using the force field of the quinoline molecule and the force field parameters of quinoline are shown to be transferable to 2,2′-biquinoline. The potential energy distribution associated with the normal modes is also given. The theoretical wavenumbers are found to be in good agreement with the experimental data.     

Characterization of Ultrathin Films of Cellulose Esters

The adsorption of cellulose acetate (CA), cellulose acetate propionate (CAP) and cellulose acetate butyrate (CAB) from solutions prepared in acetone onto silicon wafers led to ultrathin films, which were characterized by ellipsometry, atomic force microscopy (AFM) and contact angle measurements. The polysaccharides films were characterized in the air just after their formation and after annealing at temperatures higher than their glass transition temperature or melt temperature. The films thickness close to 2 nm and surface roughness did not vary significantly upon annealing. AFM images revealed the presence of small clumps dispersed on a homogeneous layer, which covered completely the Si wafers. Such topographic details were also observed after annealing. However, upon annealing the films surfaces changed from hydrophilic to hydrophobic, evidencing molecular re-orientation at the solid–air interface. The adhesion of bovine serum albumin (BSA) and lipase onto the cellulose esters films was quantified in order to evaluate the possibility of applying such films as selective support for biomolecules.     

Surface forces in foam films from ABA block copolymer: a dynamic method study

The thinning of foam films from aqueous solutions of an ABA triblock copolymer of polyethylene oxide and polypropylene oxide (average molecular weight 14,000 g/mol) is studied experimentally. The dependence of the surface forces on film thickness is obtained by the dynamic method of Scheludko and Exerowa.The total surface force measured in foam films (radius 60–70 m) from 10^–5 M (0.014 wt%) polymer solution with 0.1 M NaCl is positive at thicknesses from about 800 down to 460 . The electrostatic repulsion is negligible while the contribution of van der Waals attraction is small (within 15%). Therefore a positive surface force component predominates. Most probably it arises from steric interactions between the hydrophilic polyethylene oxide tails of the polymer. The dynamic method appears to be a suitable technique for exploring the stabilization of foam films from ABA copolymers.     

Dynamic imaging of single DNA-protein interactions using atomic force microscopy

Atomic force microscopy (AFM) imaging of static DNA-protein complexes, in air and in liquid, can be used to directly obtain quantitative and qualitative information on the structure of different complexes. For example, DNA length, the location of preferential binding sites for proteins and bending of DNA as a result of the complexation can all be measured. Recording consecutive AFM images of DNA and protein molecules under conditions that they are still able to move and interact, or dynamic AFM imaging, however, can reveal information on the dynamic aspects of the interactions between these molecules. Here, an overview is given of the technical challenges that need to be considered for successful dynamic AFM imaging studies of individual DNA-protein interactions. Necessary technical improvements to the AFM set-up and the development of new sample preparation methods are described in this paper.