全文获取类型
收费全文 | 27522篇 |
免费 | 2527篇 |
国内免费 | 1941篇 |
专业分类
化学 | 8129篇 |
晶体学 | 382篇 |
力学 | 4346篇 |
综合类 | 151篇 |
数学 | 860篇 |
物理学 | 5382篇 |
综合类 | 12740篇 |
出版年
2024年 | 82篇 |
2023年 | 255篇 |
2022年 | 708篇 |
2021年 | 694篇 |
2020年 | 674篇 |
2019年 | 557篇 |
2018年 | 587篇 |
2017年 | 761篇 |
2016年 | 912篇 |
2015年 | 861篇 |
2014年 | 1087篇 |
2013年 | 1718篇 |
2012年 | 1352篇 |
2011年 | 1388篇 |
2010年 | 1043篇 |
2009年 | 1258篇 |
2008年 | 1333篇 |
2007年 | 1683篇 |
2006年 | 1554篇 |
2005年 | 1432篇 |
2004年 | 1355篇 |
2003年 | 1217篇 |
2002年 | 1110篇 |
2001年 | 1021篇 |
2000年 | 965篇 |
1999年 | 873篇 |
1998年 | 688篇 |
1997年 | 654篇 |
1996年 | 616篇 |
1995年 | 586篇 |
1994年 | 543篇 |
1993年 | 478篇 |
1992年 | 399篇 |
1991年 | 306篇 |
1990年 | 295篇 |
1989年 | 215篇 |
1988年 | 223篇 |
1987年 | 168篇 |
1986年 | 102篇 |
1985年 | 58篇 |
1984年 | 38篇 |
1983年 | 24篇 |
1982年 | 35篇 |
1981年 | 22篇 |
1980年 | 9篇 |
1979年 | 12篇 |
1978年 | 5篇 |
1977年 | 4篇 |
1976年 | 8篇 |
1973年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
91.
The question about the definition of the “internal pressure” concept is being discussed. It is shown that the previously found differential relation between the cohesion energy density and the internal pressure is one of the examples of an absolutely general interrelation between definitely connected differential functions. It is ascertained that the ratio (the internal pressure divided by the cohesion energy density) is a structuresensitive parameter inherent to the calorific (thermal) equation of a liquid state. 相似文献
92.
复合桩基中承台内区土阻力群桩效应系数的有限元分析 总被引:1,自引:0,他引:1
采用有限元方法,对复合桩基中承台内区土阻力群桩效应系数进行了分析,并编制了相应的有限元程序。应用该程序讨论了桩距、桩数、桩长、土类等对承台内区土阻力群桩效应系数的影响。 相似文献
93.
Based on the stress transport model, a rate-dependent algebraic expression for the Reynolds stress tensor is developed. It is shown that the new model includes the normal stress effects and exhibits viscoelastic behavior. Furthermore, it is compatible with recently developed improved models of turbulence. The model is also consistent with the limiting behavior of turbulence in the inertial sublayer and is capable of predicting secondary flows in noncircular ducts. The TEACH code is modified according to the requirements of the rate-dependent model and is used to predict turbulent flow fields in a channel and behind a backward-facing step. The predicted results are compared with the available experimental data and those obtained from the standard k-ε and algebraic stress models. It is shown that the predictions of the new model are in better agreements with the experimental data. 相似文献
94.
本文分别研究了ZrO2(MgO)固体电解质管头壁厚,参比电极量对定氧测头响应时间的影响,得出了以ZrO2管头壁厚为0.60-0.80mm,Cr/Cr2O3参比电极加入量为40-60mg所组成的定氧测头响应速度最快,同时采用了“双偶法”对定氧测头在工作过程中的热平衡态进行了研究。结果表明:氧浓差电池中的传热是响应过程的控速步骤,氧电势曲线上峰值的产生是起源于电池中的热平衡态。 相似文献
95.
96.
岩石扩容现象与超声横波特征参数相互关系研究评述 总被引:8,自引:2,他引:6
介绍了岩石扩容现象与超声皮特征参数相互关系相关专业领域研究的现状及其应用,在用横波速度最大值(Vsmax)来分析岩石微裂纹初始扩展时的应力值(应力门槛值)新方法的基础上,建议利用主动的人工横波震源,应力门槛值、Vsmax后的横波速度值与岩石裂纹加速发展的同步减小特性,更深入地进入地震破裂丛集及前兆特征的研究,有可能建立地震和地质灾害性预报的新方法,并提出利用利用传统方法研究岩石扩容机理,应力门槛值,泊松比等的同时,进行岩石扩容现象,声发射和超声波横波等特性参相互关系研究的新思路。 相似文献
97.
Duygu Avci Aylin Ziylan Albayrak 《Journal of polymer science. Part A, Polymer chemistry》2003,41(14):2207-2217
Two phosphorus‐containing acrylate monomers were synthesized from the reaction of ethyl α‐chloromethyl acrylate and t‐butyl α‐bromomethyl acrylate with triethyl phosphite. The selective hydrolysis of the ethyl ester monomer with trimethylsilyl bromide (TMSBr) gave a phosphonic acid monomer. The attempted bulk polymerizations of the monomers at 57–60 °C with 2,2′‐azobisisobutyronitrile (AIBN) were unsuccessful; however, the monomers were copolymerized with methyl methacrylate (MMA) in bulk at 60 °C with AIBN. The resulting copolymers produced chars on burning, showing potential as flame‐retardant materials. Additionally, α‐(chloromethyl)acryloyl chloride (CMAC) was reacted with diethyl (hydroxymethyl)phosphonate to obtain a new monomer with identical ester and ether moieties. This monomer was hydrolyzed with TMSBr, homopolymerized, and copolymerized with MMA. The thermal stabilities of the copolymers increased with increasing amounts of the phosphonate monomer in the copolymers. A new route to highly reactive phosphorus‐containing acrylate monomers was developed. A new derivative of CMAC with mixed ester and ether groups was synthesized by substitution, first with diethyl (hydroxymethyl)phosphonate and then with sodium acetate. This monomer showed the highest reactivity and gave a crosslinked polymer. The incorporation of an ester group increased the rate of polymerization. The relative reactivities of the synthesized monomers in photopolymerizations were determined and compared with those of the other phosphorous‐containing acrylate monomers. Changing the monomer structure allowed control of the polymerization reactivity so that new phosphorus‐containing polymers with desirable properties could be obtained. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2207–2217, 2003 相似文献
98.
宣益民 《南京理工大学学报(自然科学版)》1994,(5):37-41
该文运用模糊数学理论分析热工设备设计的不确定性问题,讨论模糊设计方法的应用,以热管式空气预热器为例进行模糊设计计算。 相似文献
99.
板坯结晶器钢水凝固的数值模拟 总被引:10,自引:1,他引:9
以实测结晶器铜板温度计算的热流量作边界条件,采用有限元方法,建立了结晶器内凝固传热方程.对凝固传热方程进行了离散化,利用ANSYS商业软件进行求解,得到凝固坯壳的应力、应变情况,从而确定连铸结晶器壁的合理锥度. 相似文献
100.
A new cyanate ester monomer, 1,1-bis(3-methyl-4-cyanatophenyl)cyclohexane has been synthesized and characterized. Epoxy modified with 4, 8 and 12% (by weight) of cyanate ester were made using epoxy resin and 1,1-bis(3-methyl-4-cyanatophenyl)cyclohexane and cured by using diaminodiphenylmethane. The cyanate ester modified epoxy matrix systems were further modified with 4, 8 and 12% (by weight) of bismaleimide (N,N′-bismaleimido-4,4′-diphenylmethane). The formation of oxazolidinone and isocyanurate during cure reaction of epoxy and cyanate ester blend was confirmed by IR spectral studies. Bismaleimide-cyanate ester-epoxy matrices were characterized using differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and heat deflection temperature (HDT) analysis. Thermal studies indicate that the introduction of cyanate ester into epoxy resin improves the thermal degradation studies at the expense of glass transition temperature. Whereas the incorporation of bismaleimide into epoxy resin enhances the thermal properties according to its percentage content. However, the introduction of both cyanate ester and bismaleimide influences the thermal properties according to their percentage content. DSC thermogram of cyanate ester modified epoxy and bismaleimide modified epoxy show unimodel reaction exotherms. The thermal degradation temperature and heat distortion temperature of the cured bismaleimide modified epoxy and cyanate ester-epoxy systems increased with increasing bismaleimide content. The morphology of the bismaleimide modified epoxy and cyanate ester-epoxy systems were also studied by scanning electron microscopy. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献