Radiochemical proton activation analysis for the determination of cadmium and lead in sediment reference materials

Proton activation analysis was used for the determination of cadmium and lead in three sediment reference materials. The method is based on the^111,112Cd(p, xn)¹¹¹ In and the^206,207,208Pb(p, xn)²⁰⁶Bi reactions.¹¹¹In and²⁰⁶Bi were chemically separated by anion exchange. The results obtained were taken into account for the certification of the materials and are in the excellent agreement with the certified values.     

A quark model based on QCD scale anomaly

We consider a quark model based on QCD scale anomaly in which the quarks move in the field of an effective glueball field. Hadrons correspond to solitonic bags of higher energy density in a nonperturbative sea of condensed gluons. We calculate the static properties of nucleon in this model and find that the nucleon mass is far too large (2.4–4 GeV) and the proton charge radius (0.37–0.54 fm) is low. The proton gyromagnetic ratio and g_A/g_v are in reasonable agreement with the experimental numbers.     

马歇尔-勒纳条件的实证研究

本文从人民币实际汇率变动是否会对我国贸易收支产生影响出发，基于马歇尔．勒纳条件，对计算贸易弹性常用的OLS回归模型进行了改进，建立了向量自回归误差修正模型来估算我国的国际贸易弹性。实证研究表明：我国进出口需求的价格弹性之和大于1。因此人民币贬值可改善贸易收支；反之升值将使贸易收支恶化。     

Stress-Strain State in the Zone of Load Transfer in a Composite Specimen under Uniaxial Tension

The stress-strain state in the zone of load transfer in a uniaxially stretched specimen made of a unidirectional epoxy carbon-fiber-reinforced plastic (CFRP) is investigated. A parametric analysis of the influence of geometric and mechanical characteristics of the specimen on its stress-strain state is performed by means of finite-element modeling. The parameters allowing us to significantly reduce the dangerous concentration of transverse and tangential stresses are revealed. The mechanical tensile characteristics of a high-strength pultruded unidirectional CFRP are determined experimentally, and the size effect of its strength is estimated.     

前缘弯掠斜流转子叶顶间隙流动特性数值分析

本文对前缘弯掠斜流转子叶顶间隙内的流动特性进行了数值分析。结果表明:叶顶间隙气流与主流发生卷吸而生成泄漏涡。泄漏涡作用的区域具有较低的压力分布。在叶片通道内,泄漏涡沿着与转子旋向相反的方向朝相邻叶片的压力面移动。大间隙时的泄漏涡比小间隙时强烈。低流量时泄漏涡的作用区域比高流量时大。在各种流量特性下,叶顶尾缘近吸力面区域都存在着二次间隙流。     

FT-IR study on solvent effects in building blocks of bioactive compounds. V

3-Hydroxy-4-hydroxymethyl pyrrolidin-2-ones, easily prepared from the Baylis–Hillman adduct 1-ethyl-4-methyl-2-hydroxy-3-methylenebutanedioate, are useful intermediates in the synthesis of bioactive compounds. In order to understand the mechanism involved in this reaction, vibrational and Montecarlo molecular mechanics conformational analysis on 1-ethyl-4-methyl-2-hydroxy-3-methylenebutanedioate were carried out, confirming the existence of a low energy intramolecular H-bonded five-member ring.     

Numerical analysis of turbulent structure in compound meandering open channel by algebraic Reynolds stress model

The turbulent flow in a compound meandering channel with a rectangular cross section is one of the most complicated turbulent flows, because the flow behaviour is influenced by several kinds of forces, including centrifugal forces, pressure‐driven forces and shear stresses generated by momentum transfer between the main channel and the flood plain. Numerical analysis has been performed for the fully developed turbulent flow in a compound meandering open‐channel flow using an algebraic Reynolds stress model. The boundary‐fitted coordinate system is introduced as a method for coordinate transformation in order to set the boundary conditions along the complicated shape of the meandering open channel. The turbulence model consists of transport equations for turbulent energy and dissipation, in conjunction with an algebraic stress model based on the Reynolds stress transport equations. With reference to the pressure–strain term, we have made use of a modified pressure–strain term. The boundary condition of the fluctuating vertical velocity is set to zero not only for the free surface, but also for computational grid points next to the free surface, because experimental results have shown that the fluctuating vertical velocity approaches zero near the free surface. In order to examine the validity of the present numerical method and the turbulent model, the calculated results are compared with experimental data measured by laser Doppler anemometer. In addition, the compound meandering open channel is clarified somewhat based on the calculated results. As a result of the analysis, the present algebraic Reynolds stress model is shown to be able to reasonably predict the turbulent flow in a compound meandering open channel. Copyright © 2005 John Wiley & Sons, Ltd.     

电动势的测定及其应注意的问题

本课题通过用不同的方法测定的电动势分析,经过电动势测定的误差分析,找到各种方法的利弊,并且对电极制备以及测定电动势的装置进行改进,近而对问题进行探讨。改进后找到实验和研究的捷径,从而在高等学校化学实验以及生产中节省很多的人力和财力。     

一类时滞系统的模糊预测控制方法

对模糊控制和预测控制相结合的控制方法进行研究,提出了一种简单易于实现的模糊预测控制的组合方法.此方法将模糊控制的定性分析特点和预测控制的定量分析特点有效地结合起来,同时积分器的引入可以消除稳态偏差.仿真结果表明,该方法对控制作用的滞后时间不确定的系统十分有效.