高压下液态Ag-20 at%Ge合金的凝固及密排六方亚稳相的形成

 利用高压淬火方法，在液态Ag-20at%Ge合金的凝固过程中，对比液态急冷低四个数量级的冷却速率得到了单相密排六方结构亚稳相，其点阵参数为a=0.289 8 nm，c=0.470 8 nm，c/a=1.625。     

熔断器误动作原因分析及排除方法

针对熔断器在电路正常负载下发生熔断这一误动作现象 ,通过理论分析认为造成熔断器误动作的原因是过大的接触电阻 ,提出了识别这种误动作现象及排除误动作故障的方法。指出了遇到熔断器误动作时不能随意加粗熔断器熔体     

轧机设备油液监测技术的应用

通过对轧机关键设备的润滑油进行定期跟踪监测 ,利用理化分析、光谱分析和铁谱分析等摩擦学分析手段 ,及时掌握油品的使用状况和设备的磨损情况 ,以实现对设备进行故障诊断和视情维修     

Mechanism of the reaction of neutral and anionic N-nucleophiles with α-halocarbonyl compounds

N-Acylalkylation of neutral and anionic N-nucleophiles with α-halocarbonyl compounds was investigated by quantum chemical methods in terms of the density functional theory and by experimental methods for 2,3-dihydroimidazo[2,1-b]quinazolin-1(10)H-5-one, its N-anion, and simpler model structures. High reactivity of these reagents is determined primarily by stabilization of transition states (TS) by bridge bonds involving halogen or nitrogen atoms rather than by conjugation, as has been commonly accepted. Bridged TS are formed by both the substitution mechanism S _N 2 and the addition-elimination mechanism. α-Haloalkyl-substituted zwitterions, which are potential intermediates of stepwise N-acylalkylation of neutral N-nucleophiles, do not exist in the isolated state, but they are rather efficiently stabilized upon solvation. These zwitterions, as well as analogous O-anions generated from anionic N-nucleophiles, can serve as intermediates of N-acylalkylation, as was demonstrated by localization of the corresponding TS. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1150–1164, June, 2007.     

基于单片机控制的实验线路故障诊断系统

介绍了基于单片机控制技术的强电实验线路故障自动诊断系统的结构及功能,阐述了系统硬件设计、软件设计的基本原理．     

具有完整性的控制系统设计方法

该文研究线性连续系统的容错控制问题，即设计反馈控制器，使闭环系统对可能的执行器失效具有完整性。该文利用代数方法，直接证明了期望的容错控制器的存在性，并导出了其解析表达式。最后，用数值例子说明这种方法的直接性与简单性。     

断裂带中岩石硅化的微束研究

断裂带中岩石的硅化现象,通常称之为硅化岩或硅化破碎带,即经动力变质作用的断层岩,通过微束技术对其观察,它们显示出下列特征:在扫描电镜(SEM)下,硅化物质表现为细脉状,而在偏光里微镜下则表现为浸染状;对硅化岩进行组构观察,可见压扁 S 面和剪切 S 面;在透射电镜(TEM)下,可进一步区别不同的位错现象;断裂带岩石的硅化现象是受组成岩石的化学元素的构造地球化学作用所制约的,包括动力分异和化学亲和作用,动热变质作用和退化变质作用,氧化和还原作用以及脱水和水解作用。     

专家系统技术在注塑模故障诊断中的应用

论述了用人工智能技术对模具故障进行诊断和确定对策的原理和方法。对模具在工作中常遇到的与模具制造、工艺条件及塑料材料有关的问题及相应对策进行了归纳整理，组成了模具诊断与维修知识库。收集了常用工程塑料的各种有关成型工艺条件和主要性能，建立了塑料材料数据库。采用正向推理控制策略搜索知识库，并将推理结果与理论计算结果进行对比校验，最后确定出模具工作中出现故障的原因，并输出相应的解决办法和建议．     

综采工作面过超大断层的技术应用

介绍了杜儿坪矿68214工作面大断层,提出了通过大断层时采取的技术措施和打注高分子材料（马丽散N）的技术措施。     

Precise synthesis of porphyrin array scaffolding polyisocyanides

Aryl isocyanides bearing free‐base and metallo‐porphyrins were prepared and polymerized with a Pd–Pt μ‐ethynediyl complex as the initiator to give polymers with narrow polydispersity indices. The molecular weights of the resulting polymers were precisely controlled by the initial feed ratio of the porphyrin monomer to the initiator. The UV–VIS spectra suggested that the porphyrin pendants are regularly arranged to form stacked columns. Metallo‐porphyrin polymers were also prepared by reacting free‐base porphyrin polymers with metal salts. The successive reactions of free‐base and zinc‐porphyrin monomers resulted in the formation of diblock polymers. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 585–595, 2006