气流槽聚型紧密集聚纺力矩传递分析

为了探讨气流槽聚型紧密集聚纺纱系统集聚区内的力矩传递,首先分析了集聚区内纺纱张力矩和气流力矩的传递过程,然后分析了纱线自身回转产生的扭矩与纺纱张力矩和气流力矩的关系.研究结果表明:影响力矩传递的主要参数有纺纱张力、吸气负压值等;纺纱张力矩与气流力矩决定捻度是否会越过纤维束与凹槽底部的初始接触点上传至前钳口;适当提高吸气负压值可以缓解纺纱张力.     

一种跟踪和聚光的全新理论——陈应天在太阳能利用研究领域的重大创新

陈应天教授不久前提出的跟踪聚光理论已经引起我国国家领导部门和世界范围内专家的重视.为回答对该理论的普遍存在的疑问,从光学的基本知识出发,尽量深入浅出地讨论这一理论的核心内容,如:自主创新的自旋 仰角跟踪方式,行 列驱动从镜聚光及其精度不等的不同模式,并评述该理论的优势和应用前景.     

Effects of Viscosity Ratio on Morphological,Rheological and Mechanical Properties of PP/PBT Melt Spun Alloy Fibers

Phase morphology formation plays an important role in the mechanical properties of polymer alloy fibers. The development of the blend morphology depends not only on the intrinsic properties of the component polymers but also on extrinsic factors such as viscosity ratio, λ, in the melt spinning process. The effects of blend component viscosity ratio on the morphological, rheological, and mechanical properties of polypropylene/poly(butylene terephthalate) (PP/PBT) melt spun alloy fibers were investigated. Accordingly, two kinds of PP as matrix phase and two kinds of PBT as dispersed phase, with various melt viscosity, were physically mixed and then blended during the extrusion step of melt spinning. SEM micrographs and rheological and mechanical properties evaluations showed that the morphology of PP/PBT alloy fibers strongly depend on the viscosity ratio, λ. Finer diameter PBT fibrils were observed for Viscosity ratios less than 1 (λ < 1) compared to samples with λ > 1. The best mechanical properties in alloy fiber samples were obtained for the viscosity ratio closest to unity (sample with λ = 0.9). The lowest differences among measured complex viscosities at various shear rates (0.1, 10, and 100 s^?1) were also observed in samples with λ = 0.9. The results showed that the mechanical properties of alloy fiber samples are affected not only by morphological properties observed at different viscosity ratios but also by the properties of the individual polymer components.     

Proton-detected scalar coupling based assignment strategies in MAS solid-state NMR spectroscopy applied to perdeuterated proteins

Assignment of proteins in MAS (magic angle spinning) solid-state NMR relies so far on correlations among heteronuclei. This strategy is based on well dispersed resonances in the ¹⁵N dimension. In many complex cases like membrane proteins or amyloid fibrils, an additional frequency dimension is desirable in order to spread the amide resonances. We show here that proton detected HNCO, HNCA, and HNCACB type experiments can successfully be implemented in the solid-state. Coherences are sufficiently long lived to allow pulse schemes of a duration greater than 70 ms before incrementation of the first indirect dimension. The achieved resolution is comparable to the resolution obtained in solution-state NMR experiments. We demonstrate the experiments using a triply labeled sample of the SH3 domain of chicken α-spectrin, which was re-crystallized in H₂O/D₂O using a ratio of 1/9. We employ paramagnetic relaxation enhancement (PRE) using EDTA chelated Cu^II to enable rapid data acquisition.     

Synthesis of intrinsically flame‐retardant copolyamides and their employment in PA6‐fibers

Flame‐retarded polyamide 6.6 (FR‐PA6.6) was prepared by the cocondensation of hexamethylene diammonium adipate (AH‐salt) with the corresponding salts of hexamethylene diamine and two different organophosphorus compounds, namely, 3‐hydroxyphenylphosphinylpropanoic acid (3‐HPP, 1) and 9,10‐dihydro‐10‐[2,3‐di (hydroxycarbonylpropyl]‐10‐phosphaphenanthrene‐10‐oxide (DDP, 2). The incorporation of the phosphorus comonomers and the thermal and physical properties of the resulting copolyamides have been studied. The phosphorus‐modified FR‐PA6.6 possesses high relative viscosities of 2.0 to 2.4, good thermal stability, and was used for the production of polyamide blends by merging FR‐PA6.6 with commercial PA6. This offered access to flame‐retarded PA6 multifilaments, which possess tensile strengths up to 0.7 GPa and elastic moduli up to 6.2 GPa. Knitted fabrics of FR‐PA6 exhibit high limiting oxygen index (LOI) values between 36 and 38 and executed burning tests demonstrate that the incorporation of phosphorus‐based comonomers improve flame retardancy significantly. The approach presented here offers a straightforward access to effective flame retardancy in nylon 6.     

Central neurocytoma: typical magnetic resonance spectroscopy findings and atypical ventricular dissemination

PURPOSE: Central neurocytomas (CNCs) are rare neuronal tumors that have a favorable prognosis and lower rate of recurrence compared with other intraventricular neoplasms. Although it may be difficult to distinguish CNC on conventional neuroimaging, typical MR spectroscopy (MRS) features have been reported. We describe the MRI and MRS features of CNC. MATERIALS AND METHODS: Eight patients with CNC were reviewed. Three patients underwent presurgical in vivo single-voxel MRS at short echo time (TE, 35 ms) and multi-voxel MR spectroscopic imaging at long TE (144 ms). The surgically resected tumor specimen of one of these patients was also studied ex vivo using high-resolution magic angle spinning (HRMAS) nuclear magnetic resonance. RESULTS: All eight tumors were located in the lateral ventricles. In six patients, CNC extended into the third ventricle, and in two patients the tumor showed further contiguous intraventricular dissemination into the fourth ventricle. In all three patients who underwent MRS, a characteristic metabolite peak was detected at 3.55 parts per million (ppm) at both long and short TE. HRMAS confirmed the presence of elevated glycine (Gly) at 3.55 ppm, without increase in the concentration of myo-inositol found at the same chemical shift. Elevated choline (at 3.2 ppm) was also seen in all three patients. CONCLUSION: On MRS, CNCs have a typical appearance with a metabolite peak at 3.55 ppm due to increased Gly, and this feature may be helpful in presurgical diagnosis. Although they are rare benign intraventricular tumors, in atypical cases, CNCs can show extensive intraventricular dissemination into the fourth ventricle.     

Role of humidity on the structures and properties of regenerated silk fibers

Silk fiber was processed from highly concentrated spinning dope to solid fibers along with water removal. To understand the mechanism of water removal during silk fiber spinning process, a microfluidic chip was designed and applied to investigate the structures and mechanical properties of two kinds of regenerated silk fibroin fibers dry-spun at different relative humidity. The experimental results showed that the diameters of the fibers spun at 40% RH are always larger than the fibers spun at 50% RH due to different removal rates of water. The fibers spun at low humidity contain more β-sheet structure and lower degree of chain orientation and crystalline orientation. These results indicate that the fast phase transition of silk fibroin from sol–gel to silk fiber undergoes with rapid water removal and higher fiber orientation relates to more residue water and drawing force.     

基于EMD算法的空间自旋目标平动补偿与微动特征提取

针对微多普勒频率附加在空间目标高速轨道运动产生的多普勒频移上使微动特征提取更加困难这一问题,提出了一种利用EMD算法对空间目标进行精确平动补偿和微多普勒特征提取的方法。对空间自旋目标进行建模,推导了窄带雷达条件下空间目标的微多普勒效应,并分析了平动分量对微多普勒的影响;把目标回波分解成一系列本征模态函数(IMF),然后求出瞬时频率,利用经验模型分解(EMD)算法对瞬时频率进行分解,分析各分量的能量百分比判别平动频移分量,实现回波信号的平动补偿;对平动补偿后的信号利用 EMD算法分离出微多普勒曲线,提取微动特征。仿真实验验证了该方法的可行性与有效性。