Surfactant effects on pH-controlled synthesis of nickel hydroxides

The aim of the present work is to determine at 60 °C, the influence of the specific nature of nickel salt and pH on nickel hydroxide features such as crystallographic structure and morphology. Within the range 8 ≤ pH ≤ 11.5, a home-made nickel functionalized surfactant, nickel di-dodecylsulfate Ni(C₁₂H₂₅SO₄)₂ is compared to usual salts (nickel nitrate Ni(NO₃)₂ and nickel sulfate NiSO₄). In both cases, a sharp transition appears for pH about 10. In the classic salt case, the transition mainly affects morphology, that could be evidenced by the crosschecking of complementary techniques as SEM and nitrogen gas adsorption. For pH < 10, β-Ni(OH)₂ platelets are yielded, whereas more basic conditions lead to randomly aggregated nano-grains of badly crystallized β hydroxide. Inversely, by employing the functionalized surfactant, 2D morphology is maintained in the whole pH-range, but the crystal structure is pH-controlled ( phase with interlamellar dodecylsulfate for pH ≤ 9.5, and β phase for pH ≥ 10.5).     

A Mixed Solvothermal Route to Synthesis of Dice‐Like PbS

The authors developed a simple solvothermal route to synthesis of PbS nanocrystals in the mild binary mixed solvent made of diethylenetriamine (DETA) and water. Two kinds of PbS nanostructures (dice‐like and cubic) have been successfully synthesized in the binary mixed solvothermal system at 150 °C by changing the sulfur source. The products were characterized by X‐ray diffraction (XRD), field emission scanning electron microscope (FESEM) and transmission electron microscope (TEM). The results show that the as‐prepared dice‐like PbS crystals have a hole on each of their faces. To elucidate the relationship between reaction systems and the morphologies of the final products, the authors also investigated the crystal growth by using different sulfur source. Based on the experimental results, the possible growth mechanism of the dice‐like PbS crystals was proposed.     

An Injectable Integration of Autologous Bioactive Concentrated Growth Factor and Gelatin Methacrylate Hydrogel with Efficient Growth Factor Release and 3D Spatial Structure for Accelerated Wound Healing

Growth factors are essential for wound healing owing to their multiple reparative effects. Concentrated growth factor (CGF) is a third-generation platelet extract containing various endogenous growth factors. Herein, a CGF extract solution is combined with gelatin methacrylate (GM) by physical blending to produce GM@CGF hydrogels for wound repair. The GM@CGF hydrogels show no immune rejection during autologous transplantation. Compared to CGF, GM@CGF hydrogels not only exhibit excellent plasticity and adhesivity but also prevent rapid release and degradation of growth factors. The GM@CGF hydrogels display good injectability, self-healing, swelling, and degradability along with outstanding cytocompatibility, angiogenic functions, chemotactic functions, and cell migration-promoting capabilities in vitro. The GM@CGF hydrogel can release various effective molecules to rapidly initiate wound repair, stimulate the expressions of type I collagen, transform growth factor β1, epidermal growth factor, and vascular endothelial growth factor, promote the production of granulation tissues, vascular regeneration and reconstruction, collagen deposition, and epidermal cell migration, as well as prevent excessive scar formation. In conclusion, the injectable GM@CGF hydrogel can release various growth factors and provide a 3D spatial structure to accelerate wound repair, thereby providing a foundation for the clinical application and translation of CGF.     

Quality assessment of Astragali Radix based on pseudo-targeted metabolomics and chemometric approach

Astragali Radix is widely used because of its dual use in medicine and food, and its quality evaluation is of great importance. In this study, a pseudo-targeted metabolomics approach based on scheduled multiple reaction monitoring was developed, and a total of 114 compounds with good linearity, sensitivity, and reproducibility were selected for relative quantification, and the chemical differences between Astragali Radix of different growth patterns were further compared by chemometric analysis. With the help of multivariate and univariate analysis, 26 differential compounds between wild/semi-wild Astragali Radix and cultivated Astragali Radix were determined. Then five marker compounds were screened out by lasso regression, and further verified by systematic clustering, random forest, support vector machine, and logistic regression. In addition, malonyl-substituted flavonoids showed relatively higher content in wild/semi-wild Astragali Radix. Thus, the malonyl substitution was characteristic for flavonoids in wild/semi-wild Astragali Radix. In conclusion, the application of pseudo-targeted metabolomics and various statistical methods could offer multi-dimensional information for the holistic quality evaluation of Astragali Radix.     

后进地区经济发展战略研究

提出将落后地区划分为后进地区、贫困地区、极贫困地区等三种不同类型的观点;通过对渭南地区的研究,探讨了后进地区“工业增长极建设与农村发展建设有机结合”的经济发展战略。     

一类带消费的随机动态投入产出模型

对时滞为1且带随机消费的动态投入产出模型,研究了投入产出消耗系数矩阵、投资系数矩阵均为随机矩阵时,稳定增长解的存在性问题.利用现代概率分析及马氏过程等工具,证明不存在随机动态投入产出模型的稳定增长解.即投入产出模型反映的经济系统必须经常进行调整,其崩溃时间为无穷大的概率为零.     

锌钼微肥对鲜食油菜生长及品质的影响

通过盆栽试验,研究了土壤栽培条件下不同的锌钼微肥处理对鲜食油菜鲜重、干重、叶绿素、Vc、可溶性固形物含量及硝酸盐含量的变化情况.结果表明,锌钼微肥各处理均能不同程度地促进鲜食油菜的生长,提高产量和改善品质,并且以单施钼肥对降低硝酸盐的积累最有利.以锌钼微肥配施对增加鲜食油菜的干重、鲜重、叶绿素、Vc及可溶性固性物含量最有效.同时表明,在试验时期内油菜移栽后25～32天生长和品质达到最优.     

钼肥浸种对鲜食油菜生长、Vc含量及全氮含量的影响

在室内盆栽条件下,研究了不同质量浓度钼酸铵浸种对鲜食油菜生长、Vc含量及全氮含量的影响。结果表明,不同质量浓度的钼酸铵溶液浸种均能提高油菜整个营养生长阶段的鲜重、干重、叶绿素含量、Vc含量和全氮含量。其中钼酸铵质量浓度为0.5～1.5g/L范围内,油菜鲜重、干重、叶绿素含量、Vc含量和全氮含量随钼浓度的升高而增加。尤其以钼酸铵质量浓度为1.0～1.5g/L溶液浸种效果较好,与对照相比,油菜鲜重、干重、叶绿素含量、Vc含量和全氮含量分别增加16.86%～40.36%,10.00%～24.76%,23.09%～42.89%,11.82%～32.82%,10.60%～18.24%。显著性测验分析表明,质量浓度为1.0g/L和1.5g/L钼酸铵溶液处理油菜种子与对照相比差异均达显著水平;质量浓度为2.0g/L钼酸铵溶液处理油菜种子的鲜重、干重、叶绿素含量、Vc含量及全氮含量均低于质量浓度为1.5g/L钼酸铵溶液处理,但高于对照。     

科技投入与区域经济增长的关联分析

通过对我国2003—2012年31省份的R&D经费投入、R&D人员投入与其GDP的灰色关联分析,结果发现:科技投入对我国经济增长有很大的促进作用,相比而言R&D经费对于经济的促进作用要大于R&D人员;科技的促进作用在不同区域之间呈现阶梯态势,东部地区最高,中部次之,西部最低;在不同省份之间并不相同,而且打破东中西的区域界限。为此我国政府制定科技政策时,不仅要确保量与质的双重提高,而且要因地制宜,从当地实际情况出发,采取各种措施提高科技经费投入、完善科技人才政策,以便促进经济发展与社会进步。