聚双环戊二烯反应注射成型

本文介绍了国外有关聚双环戊二烯反应注射成型的研究进展，讨论了国内进行聚双环戊二烯反应注射成型开发研究的现实意义，并对这一领域的发展进行了展望     

集成滤波器在谱图信号除噪中的应用

本文提出了一种由神经元网络与线性自适应滤波器组成的集成滤波器的实现方法，用于谱图信号除噪处理。     

Fabrication of PbTiO3 Ceramic Fibers by Sol-Gel Processing

The sol-gel processing was applied to the fabrication of PbTiO₃ fibers. Pb(CH₃COO)₂·3H₂O and Ti(OC₃H ₇ ⁱ )₄ were refluxed with stirring in 2-methoxyethanol to form Pb-methoxyethoxide and Ti-methoxyethoxide, respectively, followed by mixing with stirring in 2-methoxyethanol to form Pb−Ti double alkoxide. The hydrolysis and polycondensation reaction of this double alkoxide gave polymerized products, and as a result the viscosity of the solution increased, suggesting that linear polymers were produced through the hydrolysis and polycondensation reaction. Homogeneous PbTiO₃ gel fibers were drawn from the spinnable viscous solutions, which were wellcrystallized into perovskite type PbTiO₃ at 650°C. The heat-treated fibers were a few centimeters long and from 10 to 100 μm in diameter. The fiber was made up of extremely uniform grains. Electron diffraction revealed a preferred growth of (101) planes along the fiber axis, which might be due to the linear molecular characteristics of the alkoxide.     

High modulus polyimide/polyimide molecular composite films that utilize acetylene unit as a crosslink site

Polyimide/polyimide molecular composite (MC) films comprised of a rigid polyimide derived from biphenyltetracarboxylic dianhydride (BPDA) and p-phenylenediamine (PDA) and a flexible polyimide derived from BPDA and bis (3,3'-diaminodiphenyl) acetylene (intA) and/or oxydianiline (ODA) were prepared by blending the polyamic acid solutions in 7 : 3 weight ratio, and then imidizing the blend films. Acetylene content in the flexible polyimide backbone was controlled by the ratio of intA and ODA. Cold-drawing of the blend polyamic acid films, followed by imidization, gives high modulus polyimide/polyimide MC films. The modulus of the MC films increased almost linearly with the draw ratio, reaching 25.5 GPa for the 40% drawn film. Acetylene groups in the flexible polyimide can be thermally cured to crosslink. The onset of exotherm appeared at 340°C on DSC, reaching maximum at 398°C. After the thermal crosslinking, the MC films maintained the high modulus, though elongation became small. Taking advantage of the crosslinkable acetylene units, two MC films were laminated and processed at 400°C for 20 min under 100 kg/cm² to give a good-quality laminate film. The interface of the two films was strongly bonded through the crosslinking of acetylene groups. Laminate films maintained the high modulus afforded by the cold-drawing. © 1994 John Wiley & Sons, Inc.     

Steroid Cyclophanes as Artificial Cell-surface Receptors. Molecular Recognition and its Consequence in Signal Transduction Behavior

Steroid cyclophanes, bearing four bile acid moieties covalently placed on a tetraazaparacyclophane skeleton, were designed and synthesized as artificial cell-surface receptors. Guest-binding behavior of the steroid cyclophanes embedded in a bilayer membrane formed with a synthetic peptide lipid was clarified by means of fluorescence and circular dichroism spectroscopy. We found that the steroid cyclophane effectively bound aromatic guests in both bilayer membranes and aqueous solution. In addition, copper(II) ions acted as a guest species for the steroid cyclophane and a competitive inhibitor toward a NADH-dependent lactate dehydrogenase (LDH). On these grounds, we constituted a supramolecular assembly as an artificial signaling system in combination with the steroid cyclophane, a cationic peptide lipid, and LDH. As a consequence, the steroid cyclophane acted as an effective artificial cell-surface receptor being capable of transmitting an external signal to the enzyme in collaboration with copper(II) ions as a signal transmitter.     

分析信号处理方法的比较研究

研究了高效液相色谱－火焰原子吸收光谱联用系统分析信号处理方法，比较了各种处理方法的优缺点，用积分与适应平滑法综合处理色谱峰分析信号，不仅能有效地消除噪声，而且能使分析信号得到加强，以测定镍为例，经积分与适应平滑法综合处理后，检出限改善了２．７倍。     

Crystallization Temperature Limit of (Ba,Sr)TiO<Subscript>3</Subscript> Thin Films Prepared by a Non Oxocarbonate Phase Forming CSD Route

A new chemical solution deposition (CSD) route for the fabrication of Ba_0.7Sr_0.3TiO₃ (BST) thin films has been developed which completely prevents the formation of an intermediate oxo-carbonate phase. The latter has been reported previously by several authors to be responsible for increased crystallization temperatures. Barium and strontium diaminoethoxides were synthesized starting from pure barium and strontium metal and aminoethanol. These alkoxides were found to be readily soluble in a wide range of solvents and thus were excellent candidates for the CSD process. To prepare a stable precursor solution the aminoalkoxides were dissolved in 2-butoxyethanol and then used for the deposition of BST thin films. We conclude that the minimum crystallization temperature of 600C to be independent of the formation of the oxo-carbonate phase. DTA-TGA were performed on the precursors and their solutions to study their decomposition behaviour. All films annealed at different temperatures were physically characterized by XRD, IR, and SEM. The films prepared by this route at 650C were found to have high dielectric constant and the leakage currents were comparable to BST films prepared by normal carboxylate based routes at 750C.     

Thermal degradation of vinylidene chloride/vinyl chloride copolymers in the presence of N-substituted maleimides

As a consequence of their excellent barrier properties vinyl chloride/vinylidene chloride copolymers have long been prominent in the flexible packaging market. While these polymers possess a number of superior characteristics, they tend to undergo thermally- induced degradative dehydrochlorination at process temperatures. This degradation must be controlled to permit processing of the polymers. Three series of N-substituted maleimides (N-alkyl-, N-aralkyl, and N-aryl) have been synthesized, characterized spectroscopically, and evaluated as potential stabilizers for a standard vinyl chloride/vinylidene chloride (85 mass%) copolymer. As surface blends with the polymer, these compounds are ineffective as stabilizers. However, significant stabilization may be achieved by pretreatment of the polymer with N-substituted maleimides. The most effective stabilization of the polymer is afforded by N-aralkyl- or N-arylmaleimides, most notably, N-benzylmaleimide and N-p-methoxyphenylmaleimide.     

基于卷积模型的核信号仿真

NaI(Tl)探测器因具有探测效率高和成本低等优点,常被用于核辐射能谱测量和核辐射监管等领域．由于实验条件等的限制,研究人员往往较难获取理想的实验核信号,虽然可以借助探测器的仿真信号来实现研究目的,但是常规的探测器单指数或双指数模型和实际采集到的核信号模型存在一定的差异,需要一种更为精准的数学模型对探测器输出信号进行描述．我们通过对探测器信号形成过程分析,将探测器视为线性时不变系统,探测器各个部分响应的总卷积即为输出的核信号模型．本文建立的探测器输出信号卷积模型,结合实测伽玛源的幅度分布规律和相邻脉冲时间间隔分布规律,可以提供更精确的NaI(Tl)探测器输出信号,以便用于伽玛能谱测量算法研究;通过调节脉冲间隔时间大小,可以仿真不同计数下探测器输出信号的堆积情形,以便用于堆积信号还原算法研究．经过与伽玛辐射源的对比测试,该仿真信号与真实探测器输出信号一致,既避免了研究人员接触放射源,提高辐射防护安全性,又为开展数字化核信号处理算法研究及能谱算法研究提供了极大的便利性．     

基于Bert股吧舆情分析的特征融合股价走势预测研究

传统股价预测模型往往只考虑时序性数据且局限于模型自身机制,而忽略舆情对股价的影响,导致预测精度不高,针对该问题,提出基于 Bert 股吧舆情分析的特征融合预测模型对股价收盘价进行涨跌幅预测。 首先,采用Bert 自然语言处理对股吧舆情以及公司公告政策进行情感分类,并转化为虚拟变量,构建金融舆情情感特征库;然后将金融舆情特征库和时序性数据合并构建特征融合矩阵;最后输入长短期记忆网络模型(LSTM)进行股价收盘价预测,并得出股价的涨跌结果。 以华银电力(600744. SH)为例进行实证分析,实验结果表明:引入股票情感特征后的模型,得到的股价走势准确率上升了 8. 63%,预测收盘价的回归指标 FMAPE FRMSE 分别下降了 23. 59%、22. 9%,R2 提高了 8. 11%,证明引入新的舆情情感特征在实际预测中能提高股价预测的准确率,可以作为精准预测股价走势的手段。