全文获取类型
收费全文 | 3609篇 |
免费 | 275篇 |
国内免费 | 277篇 |
专业分类
化学 | 1187篇 |
晶体学 | 35篇 |
力学 | 76篇 |
综合类 | 43篇 |
数学 | 218篇 |
物理学 | 752篇 |
综合类 | 1850篇 |
出版年
2024年 | 14篇 |
2023年 | 33篇 |
2022年 | 76篇 |
2021年 | 93篇 |
2020年 | 72篇 |
2019年 | 76篇 |
2018年 | 72篇 |
2017年 | 102篇 |
2016年 | 119篇 |
2015年 | 103篇 |
2014年 | 123篇 |
2013年 | 243篇 |
2012年 | 182篇 |
2011年 | 200篇 |
2010年 | 146篇 |
2009年 | 188篇 |
2008年 | 168篇 |
2007年 | 220篇 |
2006年 | 205篇 |
2005年 | 161篇 |
2004年 | 170篇 |
2003年 | 179篇 |
2002年 | 129篇 |
2001年 | 123篇 |
2000年 | 125篇 |
1999年 | 96篇 |
1998年 | 84篇 |
1997年 | 69篇 |
1996年 | 63篇 |
1995年 | 68篇 |
1994年 | 50篇 |
1993年 | 66篇 |
1992年 | 47篇 |
1991年 | 42篇 |
1990年 | 35篇 |
1989年 | 45篇 |
1988年 | 45篇 |
1987年 | 29篇 |
1986年 | 18篇 |
1985年 | 15篇 |
1984年 | 15篇 |
1983年 | 9篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 7篇 |
1979年 | 12篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1974年 | 2篇 |
1972年 | 1篇 |
排序方式: 共有4161条查询结果,搜索用时 250 毫秒
61.
秦安大地湾高分辨率全新世植被演变与气候变迁初步研究 总被引:32,自引:3,他引:29
主要根据孢粉分析结果,并结合磁化率,碳酸钙恢复了陇西黄土高原地区全新世期间植被气候的变化过程。结果表明全新世气候存在3个大的阶段,全新世早期气候以寒冷为主要特点,中全新世气候温暖湿润,晚全新世气候以干旱为主要特征。 相似文献
62.
陈南祥 《河海大学学报(自然科学版)》1998,26(4):111-114
通过对给水度与饱和差的理论分析,明确了给水度与饱和差在基本概念上的差别;得出了饱和差通常是大于给水度而小于孔隙度,以及只有岩土体积含水率达到持水度时饱和差与给水度才相等的结论;给出了饱和差与给水度之间的定量关系式。这些结果得到了室内试验的验证。 相似文献
63.
作者研制了一种以石油沥青基碳纤维为电极材料的微电极,基于此种材料的特殊性能,经氧化处理后可获得较一般微电极为大的比表面积,因而其电流响应亦较一般微电极为大。且由于其表面在一定条件下可生成大量的碳氧基团,故其电极电位会随溶液pH值而线性变化,以至该电极亦可用作测量pH值的微电极。 相似文献
64.
江汉平原洪涝灾害遥感监测方法 总被引:3,自引:1,他引:2
邹尚辉 《华中师范大学学报(自然科学版)》1996,30(1):96-100
用遥感数据及常规气水文数据获取涝灾信息,用DEM(数字高程模型)或微等高距地形图及其导出的高程-面积-容积模型作涝灾淹没损失估算的基本技术手段,用植被指数作主要方法对江汉平原“1991.07”暴雨涝灾作了灾情评价及减产估算。 相似文献
65.
Thermal solid-phase decomposition of anhydrous copper(ii) formate has been studied at 120–180 ° The rate of gas evolution during the decomposition depends on the depth of conversion and can be presented as the sum of first-order reaction rates and the rate of the autocatalytic process (a second-order reaction). The evolution of the solid phase during thermolysis has been observed by optical microscopy. The decomposition of copper formate is a complex topochemical process, a combination of homogeneous and heterogeneous transformations and dispersion of large crystals.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. l, pp. 72–76, January, 1996. 相似文献
66.
Summary Methylbenzenes, pyridines and pyrazines were investigated on fused-silica and glass capillary columns coated with SE-30 and
PEG-40M/KF liquid phases, at two temperatures, 80° and 110°C. The contribution of the methylene groups to the partial molar
free sorption energy was determined for methylpyridines and pyrazines. Equations are proposed for the calculation of the retention
indices of methyl pyridines and pyrazines. These equations are based on the ortho- and α-effects of the methyl groups. The
predicted indices have been experimentally tested for six dimethyl- and trimethylpyridines, and four methylpyrazines. Good
accuracy of the calculation permits to use this method for the identification of methylpyridines and pyrazines in complex
mixtures.
Enlarged text of the paper presented at the Eighth International Symposium on Capillary Chromatography, Riva del Garda, Italy,
May 19–21, 1987. 相似文献
67.
The selectivity of a column system, S, defined by equation 28, includes a variation coefficient (β) of plate number with capacity ratio which has a large influence on the peak capacity, as shown in Fig. 18. Some typical chromatograms are given. In order to predict S for a column system from Kovat's Index, equations 40 and 41 are given to calculate the constant of the carbon number rule for squalane at different temperatures or for different stationary phases. The specific retention value of heptane on squalane at different temperatures can be calculated from equation 42. The nonpolarity index, defined by equation 43, was used to calculate the retention value of heptane on various stationary phases. In liquid chromatography, the order of elution may be reversed by changing the composition of the eluent on the same chemically bonded silica (manufactured in China). The linear relations between the log retention values of different kinds of solutes or of a single solute on the silicas of different surface areas when using the same eluent are given. 相似文献
68.
Alessandro D'Aprano Ines Dorina Donato Vincenzo Turco Liveri 《Journal of solution chemistry》1989,18(8):785-793
Static dielectric constants, refractive indices and viscosities of 1-pentanol +2-methyl-2-butanol mixtures were measured at 5, 25 and 45°C. The results show that the mixing of the two isomers modifies the polarizability and the resistence of viscous flow of the system depending on the composition and temperature. Short range intermolecular interactions producing hetero-alcohol open dimers are considered. 相似文献
69.
The effects of adding millimolar quantities of a series of compounds containing the carbonyl function on the conductances of solutions (0.2 mM) of tri-n-butylammonium picrate ino-dichlorobenzene solvent at 25°C have been measured. Values of the complex formation constants K
1
+
for 1:1 cation-ligand complexes are derived from these data. The corresponding values of –G
1
0
at 25°C are (in kcal-mole
–1
): 4-butyrolactone, 4.29; propylene carbonate, 3.87; ethylene carbonate, 3.59; cyclopentanone, 3.42; ethyl acetate, 2.84; and diethyl carbonate, 2.78. These results together with earlier results from this laboratory are discussed in terms of the effects of structure on cation-ligand affinity. 相似文献
70.
1 INTRODUCTION The reactivity of activated alumina adsorbent is closely related to its specific surface area: the larger the specific surface area, the better its activity and adsorbent capability are. However, in reality, the prac- tically available specific surface area or effective spe- cific area has relationship with its pore structure[1]. Since many reactant molecules are difficult to enter the pores to react with whose radius is shorter than certain critical value, the increase of p… 相似文献