The interaction of ditoluenetitanium with CO{in2} has been studied. Based on hydrolysis, thermolysis, and IR spectral data, the conclusion is drawn that a low-valent titanium oxalate is formed.This study was financially supported by the Russian Foundation for Basic Research (Project No. 93-03-5538).Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2241–2242, December, 1994. 相似文献
The thermal dehydration of copper(II) acetate hydrate has been studied between 353 and 406 K, over a range of humidities.
The dehydration is controlled by nucleation-and-growth kinetics at low temperatures, with an activation energy of 154 kJ·mol−1, which changes to contracting-disc kinetics at higher temperatures with a lower activation energy of 76 kJ·mol−1. Frequency factors have also been derived; the value for the high temperature process is low (107s−1) and that for the low temperature step is high (1017s−1). Optical microscopy has been used to clarify the bulk kinetics; there is evidence for a reactive layer at the surface of
the decomposing solid.
In celebration of the 60th birthday of Dr Andrew K. Galwey 相似文献
X-ray photoelectron spectroscopy (XPS) was adopted for the analytical characterization of composite titanium dioxide–poly(vinylidenefluoride) (TiO2–PVDF) films developed for applications in the photocatalytic degradation of pollutants.
The composites were deposited on glass substrates by casting or spin coating from TiO2–PVDF suspensions in dimethylformamide (DMF). XPS data on the TiO2–PVDF surface composition were used to optimize preparation conditions (composition of the TiO2/PVDF suspension, deposition technique) in terms of titanium dioxide surface amount and film stability.
The use of spin-coating deposition and the increase of TiO2 amount in the DMF suspensions were found to improve the titanium surface content, although high TiO2/PVDF ratios led to film instability. PVDF–TiO2 films were also used in preliminary photocatalytic degradation tests on isoproturon, a phenylurea herbicide, under solar UV irradiation; the results were compared to direct photolysis to evaluate the catalytic efficiency of immobilized TiO2 and the role played by the PVDF film during the degradation process. 相似文献