微介孔复合分子筛合成及其在汽车冷启动尾气控制中的应用

分别采用稀溶液和浓溶液双模板剂两步水热合成法,以二氧化硅微硅粉和铝酸钠为硅源和铝源,第一步获得β分子筛晶种,第二步以β分子筛晶种为结构单元组装形成兼具MCM-41分子筛和β分子筛结构特点的复合型分子筛β/M(其中β是指β分子筛,M是指MCM-41介孔分子筛).采用X射线衍射(XRD)、傅里叶变换红外(FT-IR)光谱、氮气吸附(BET)和高分辨透射电镜(HRTEM)对样品的物相结构和微观形貌进行了表征,并对复合分子筛的合成过程进行了分析.结果表明:复合分子筛β/M的形成是微孔β结构和介孔MCM-41结构的竞争生长过程,β分子筛晶种的晶化时间和晶粒度大小对β/M复合分子筛的结构有重要影响.此外,我们以甲苯为探针分子,比较研究了三类分子筛β/M、MCM-41和β的原样以及经高温水热处理后样品的吸附性能,结果表明:β/M复合分子筛的热稳定性优于介孔分子筛MCM-41,其甲苯吸附容量比MCM-41和β分子筛的高,其中以浓溶液法合成的复合分子筛吸附容量最高.     

带有反射腔的相对论返波管的数值模拟

 阐述了带有反射腔的相对论返波管的数值模拟研究。利用线性理论[1]设计了返波管的慢波结构，应用SUPERFISH软件设计了谐振反射器。用KARAT软件对谐振反射腔返波管进行了宏观粒子模拟，得到了优化的返波管结构参数，并研究了外加磁场对输出效率的影响。模拟结果表明：谐振反射腔不仅起到截止颈的作用，还有预调制的作用；在低外加磁场条件下，该返波管也能输出较高功率的微波。显示了其在重复频率工作方面的重要意义。     

Local properties of Lévy processes on a totally disconnected group

This paper is the first study of the sample path behavior of processes with stationary independent increments taking values in a nondiscrete, locally compact, metrizable, totally disconnected Abelian group. After some preparatory results of independent interest we give a general integral criterion for a deterministic function to be a local modulus of right-continuity for the paths of the process and then study the sets of fast and slow points where the local growth of the process is anomalously large or small. We establish the lim sup behavior for the sequence of first exit times from a collection of concentric balls for an arbitrary process and show that no deterministic function can act as an exact lower envelope. Under appropriate conditions similar results hold for the related sojourn time sequence. We consider various candidates for measuring the variation of the paths of the process, show that they exist and coincide in our situation, and then determine the common value for a general process. Using earlier results we calculate the Hausdorff and packing dimensions of the image of an interval, exhibit the correct Hausdorff measure for this set, and establish a dichotomy that classifies measure functions into those that lead to a zero packing measure for the image and those that lead to an infinite packing measure. Lastly, we prove some uniform dimension results, which bound the dimension of the image of a set in terms of the dimension of the set itself. These results hold almost surely for all sets simultaneously.     

18Mn5Cr护环钢的应力腐蚀开裂

用慢应变速率拉伸试验方法研究了１８Ｍｎ５Ｃｒ护环钢在９０℃去离子水和２２％ＮａＣｌ水溶液以及饱和和ＮａＮＯ３水溶液中的应力腐蚀开裂行为。结果表明，１８Ｍｎ５Ｃｒ钢在三种介质中对ＳＣＣ都较敏感，电位对该钢的ＳＣＣ抗力有明显影响，溶液的ｐＨ值对影响不大。     

STUDY ON INTERMITTENT SHEAR FLOW AND RELAXATION BEHAVIOR OF THERMOTROPIC LIQUID CRYSTALLINE POLYMER

Intermittent shear flow including start-up flow and small oscillatory amplitude time sweep or stress relaxation after cessation of shear flow was used to study the rheological behavior and internal structure of thermotropic liquid crystalline polymer (TLCP). There are two kinds of intermittent shear flow: all start-up flows are in the same direction (intermittent flow forward: IFF) and start-up flows change their directions alternately (intermittent flow reversal: IFR). The results show that the stress of start-up flow of IFF and IFR in the test process is not superposed, indicating different changes of internal structure of thermotropic LCP (TLCP). Two main factors affect structure changes in the experimental time scale. One relates to long-term texture relaxation process, the other is an interchain reaction that becomes important after 30 min. The two factors raise the stress of IFF, but express complex effects for the stress of IFR. The latter factor becomes very important at long time annealing process. The relaxation behavior was also studied by the application of wide range relaxation spectrum calculated from the combined dynamic modulus, which gave three characteristic relaxation times (0.3, 10 and 600 s) ascribable to the relaxations of less-phase orientation, domain orientation, and domain deformation, respectively. The result also shows that the domain coalescence (texture relaxation), a long relaxation time, is a much slow process and lasts beyond 2400 s of the test time.     

INVESTIGATION OF POLYDL-LACTIDE-b-POLY（ETHYLENE GLYCOL）-b-POLYDL-LACTIDE MICROSPHERES CONTAINING PLASMID DNA

PolyDL-lactide (PDLLA) and the block copolymer, polyDL-lactide-b-poly(ethylene glycol)-b-polyDL-lactide (PELA) were used as the microsphere matrix to encapsulate plasmid DNA. The PDLLA, PELA, pBR322-1oaded PDLLA and pBR322-1oaded PELA microspheres were prepared by solvent extraction method based on the formation of multiple w1/o/w2 emulsion. The microspheres were characterized by surface morphology, mean particle size, particle size distribution and loading efficiency. The integrity of DNA molecules after being extracted from microspheres was determined by agarose gel electrophoresis. The result suggested that plasmid DNA molecules could retain their integrity after being encapsulated by PELA. The PELA microspheres could prevent plasmid DNA from being digested by DNase. The in vitro degradation and release profiles of plasmid DNA-loaded microspheres were measured in pH - 7.4 buffer solution at 37℃. The in vitro degradation profiles of the microspheres were evaluated by the deterioration in microspheres surface morphology, the molecular weight reduction of polymer, the mass loss of microspheres, the changes of pH values of degradation medium, and the changes of particle size. The in vitro release profiles of the microspheres were assessed by measurement of the amount of DNA presented in the release medium at determined intervals. The release profiles were correlation with the degradation profiles. The release of plasmid DNA from PELA microspheres showed a similar biphasic trend, that is, an initial burst release was followed by a slow, but sustained release.     

One-sided limit theorems for sums of multidimensional indexed random variables

Let {X,X _n,nZ ₊ ^d } be a sequence of independent and identically distributed random variables and {a _n ,n Z ₊ ^d } be a sequence of constants. We examine the almost sure limiting behavior of weighted partial sums of the form _|n|N a _n X _n . Suppose further that eitherEX=0 orE|X|=. In most situations these normalized partial sums fail to have a limit, no matter which normalizing sequence we choose. Thus, the investigation lends itself to the study of the limit inferior and limit superior of these sequences. On the way to proving results of this type we first establish several weak laws. These weak laws prove to be of great value in establishing generalized laws of the iterated logarithm.     

加工时间依赖于开工时间的单机排序问题

讨论了加工时间依赖于开工时间的单机排序问题．在这一模型中每个工件具有一个基本加工时间，当工件的开工时间超过某个共同的工期后，工件会有一个时间惩罚．本文就目标函数为极小化最大完工时间和总完工时间的问题进行了讨论，对某些特殊情况给出了多项式算法.     

FM-DCSK在非平坦衰落信道下的系统设计与仿真

调频-差分混沌键移(FM—DCSK)是一种以混沌信号作为载波的非相干的调制解调技术，其输出信号具有固有的宽频特性。由于其在对抗多径衰落方面具有显著的效果，它适合于在无线移动通信信道下使用，因而得到广泛的研究。给出了FM-DCSK在非平坦衰落信道下的原理结构图，并做了性能分析，通过仿真发现：在两径瑞利(非平坦慢衰落)信道下，FM-DCSK的误码性能优于传统的调制解调技术QDPSK和QPSK。为了进一步提高FM-DCSK的误码性能，建议结合使用一些有效的技术，如分集、Rake接收机等。这些结论和建议对于促进FM-DCSK在无线通信环境下的研究与应用具有重要的意义。