关于失独家庭法律扶助机制的思考

独生子女家庭为我国人口政策和国家可持续发展做出了突出贡献。风险社会中,失独家庭的产生无法避免。大多数失独家庭面临着严峻的经济、养老、医疗等问题。虽然这一现象已逐渐引起了政府和社会的关注,但是目前有关失独家庭的扶助法规存在滞后性和局限性,将失独老人比照三无老人进行扶助的做法也值得商榷。国家、政府以及全社会应强化自身责任和义务,多层次、全方位地及时对失独家庭给予扶助,失独家庭也应努力进行自我调适,以实现自我救助。     

高职院校学生实践能力培养路径研究--以高职市场营销专业学生为例

如何帮助学生提高实践能力，如何提升他们的竞争力，是高职教育实践中的一个重要课题。以就业为导向，改变教学模式，大力推进实践教学、工学结合，无疑是增强其实践能力的利器。但是，目前我国的高职教学资源及经验有限，教学模式的彻底转变不可能在一朝一夕之间完成。结合高职市场营销学生特点，充分利用现有教学资源，从培养目标转变、课程设计改革、教学手段改进与教学模式的大胆创新等方面着手，有助于教学工作者摸索出一条切实可行的培养路径。     

Initial guess by improved population-based intelligent algorithms for large inter-frame deformation measurement using digital image correlation

Digital image correlation (DIC) has received a widespread research and application in experimental mechanics. In DIC, the performance of subpixel registration algorithm (e.g., Newton-Raphson method, quasi-Newton method) relies heavily on the initial guess of deformation. In the case of small inter-frame deformation, the initial guess could be found by simple search scheme, the coarse-fine search for instance. While for large inter-frame deformation, it is difficult for simple search scheme to robustly estimate displacement parameters and deformation parameters simultaneously with low computational cost. In this paper, we proposed three improving strategies, i.e. Q-stage evolutionary strategy (T), parameter control strategy (C) and space expanding strategy (E), and then combined them into three population-based intelligent algorithms (PIAs), i.e. genetic algorithm (GA), differential evolution (DE) and particle swarm optimization (PSO), and finally derived eighteen different algorithms to calculate the initial guess for qN. The eighteen algorithms were compared in three sets of experiments including large rigid body translation, finite uniaxial strain and large rigid body rotation, and the results showed the effectiveness of proposed improving strategies. Among all compared algorithms, DE-TCE is the best which is robust, convenient and efficient for large inter-frame deformation measurement.     

Nanoscratch-induced deformation behaviour in B4C particle reinforced ultrafine grained Al alloy composites: a novel diagnostic approach

We report on the novel application of nanoscratch characterization to provide insight into the plasticity mechanisms responsible for the behaviour of composites. Accordingly, we conduct deformation characterization with nanoscratch testing (DCNT) to study the deformation behaviour of two B₄C reinforced ultrafine grained Al alloy tri-modal composites with average B₄C particle sizes of ~1–6?μm and ~500?nm, respectively. To highlight the type of mechanistic information revealed in a DCNT study of composites, we concentrate on the influence of B₄C particle size on deformation mechanisms.     

Synthesis,structure, and biological properties of a Co(II) complex with tridentate Schiff base ligand

A new Co(II) complex of general formula [Co(L)₂] has been synthesized from a NNO tridentate Schiff base ligand, 2-[(piperidin-2-ylmethylimino)-methyl]-phenol (L). The title complex is characterized by elemental, spectroscopic, antibacterial, and single crystal X-ray structural studies. X-Ray crystallography reveals that the complex shows a distorted octahedral geometry around the Co(II) ion. The complex was tested against several bacteria and shows good antibacterial activities against almost all of the bacteria. The interactions of the title complex with calf thymus deoxyribonucleic acid (CT-DNA) have been investigated by electronic absorption and fluorescence spectroscopy, showing that the complex interacts with CT-DNA via partial intercalation. Thermogravimetric analysis (TGA) of the complex has also been reported and the result shows that the complex is thermally stable up to 134 °C.     

Open Chain Chiral Macrolide Building Blocks by Opening of Deoxygenated 1,6-Anhydrosugars with 1,3-Propanedithiol

Chiral building blocks for macrolides and related natural products are obtained from 1,6-anhydrosugars by conversion of the bicyclic acetals 2 or 12 into the open chain chiral 1,3-dithianes 6 and 13. Branched precursors can be obtained by opening of the ?erný epoxide 1 with the 1,3-dithiane anion to yield 7, followed by ring opening with 1,3-propanedithiol to the bis-1,3-dithiane 8.     

Comparison of the growth and degradation of poly(glycolic acid) and poly(ε‐caprolactone) brushes

The growth and degradation of poly(glycolic acid) (PGA) and poly(ε‐caprolactone) (PCL) brushes were compared. Using tin (octanoate) as the catalyst, optimal conditions were found for growth of each polyester brush from the hydroxy‐terminated silicon surface via ring‐opening polymerization. PCL brushes grew thicker at elevated temperatures but the thickest PGA brushes grew at room temperature. Unlike bulk polyesters that can degrade under both acidic and basic conditions, the confined surface polyester brushes only degraded under neutral or basic conditions. The degradation mechanism of grafted polyester brushes was probed through a blocking test. It was shown that the terminal hydroxy groups of these polyester brushes were essential to the degradation process indicating a preferential backbiting mechanism. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 4643–4649     

Conduction of Strongly Coupled Electrons Through Narrow Channels on Liquid Helium Surface: Simulation

The conduction of electrons through narrow channels formed on the surface of liquid helium is analyzed by numerical simulations. It is shown that, when electrons are strongly coupled, we have nonlinear and even negative dependence of conductance on the width of the constriction which is controlled by the gate voltage (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Synthesis and ring‐opening polymerizations of novel S‐glycooxazolines

A new 2‐oxazolines containing S‐galactosyl substituents linked to alkyl chains of different lengths; (S‐glycooxazoline) were prepared relatively in high yields. By using a 1:1 adduct of 2‐methyl‐2‐oxazoline and methyl triflate, as the initiator, the monomer was polymerized via ring‐opening polymerization (ROP) to give products with relatively narrow molecular weight distributions. Homo‐ and copolymerization were performed, and the kinetics of these new S‐glycooxazolines in the ROP are investigated. After a quantitative deprotection, poly(2‐oxazoline)s having pendant carbohydrate were obtained. The interaction of the poly(S‐glycooxazoline) with RCA₁₂₀ lectin was investigated, the binding constant between glycopolymer and lectin was increased by 10² times compared with that of the monosaccharide (D ‐galactose). The in vivo expression of green fluorescent protein using the synthesized poly(S‐glycooxazoline)s as polymeric inducers in Escherichia coli host were performed. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010     

Chromatographic characterization of proanthocyanidins after thiolysis with cysteamine

Summary Cysteamine is proposed as a user-friendly thiol donor with application to the analysis of proanthocyanidins by thiolysis. Oligomeric proanthocyanidins are potent antioxidants and disease-preventing agents. The efficiency of which depends on their composition and size. The degree of polymerization of proanthocyanidins is usually estimated by thiolysis then reversedphase high-performance liquid chromatography. The new derivatization procedure is an alternative to the use of toluene-α-thiol as thiol donor. In addition to enabling the direct chromatographic analysis of curude material, the amino function introduced facilitates prior discrimination between terminal and extension flavanoid moieties by means of cation-exchange chromatography.