Determination of ultra-trace gold in natural water by graphite furnace atomic absorption spectrophotometry after in situ enrichment with thiol cotton fiber

A simple method of determining ultra-trace Au in natural water was presented by using graphite furnace atomic absorption spectrophotometry (GFAAS) after in situ enrichment with thiol cotton fiber (TCF). The sample solution was adjusted to pH 1.5-2.0 with HCl, then the water sample was passed through a column packed with 0.10-0.20 g TCF and the flow rate was controlled at 20-40 ml min⁻¹. The effects of interferences, such as complexing and oxidizing agents and other elements adsorbed on TCF were overcome by chemical treatments prior to the desorption of Au. The adsorbed Au was adsorbed with 2.0 ml hot acid, then it was extracted with 1.00 ml methyl isobutylketone (MIBK). For a 5 l water sample, the detection limit of Au is 0.02 ng l⁻¹. The relative standard deviation (R.S.D.) for the determination of 1.44 ng l⁻¹ Au was 9.4%.The method was applied to determine ultra-trace Au both in suspended phase and soluble phase in natural water, the concentrations of total Au in natural water samples range from 0.51 to 67.82 ng l⁻¹. The recovery of added 0.50-6.00 ng l⁻¹ Au was 80-95%. The method is useful in prospecting for Au deposits by means of hydrogeochemical methods. The enrichment is carried out in the field, and then the determination of Au is completed later in the laboratory.     

用反射法自动测量大尺寸样品的折射率分布

针对大尺寸样品的折射率分布测量,引入自动扫描装置和适时数据处理系统,研究出一种高灵敏度的智能化反射法折射率分布测量仪,可进行快速、自动、准确的折射率分布测量.经理论分析和实验研究提出了一套合理的实验数据处理方法.并具体介绍和详尽分析了实验装置,讨论了有关理论和实验误差,给出了消除各种误差的有效方法,最终得出较为理想的实验结果.     

利用弧形光栅尺测量大型转轴扭矩的原理研究

利用弧形光栅尺的旋转微位移测量功能,组建一组测量体系,用于测量巨型转轴的扭矩。采用四组相同的弧形光栅尺同时测量两截面的相对转角,通过多点测量实现误差均化,得出了消除转轴直径对测量影响的公式,使仪器的环境适应能力得到了极大地提高。根据不同的工作情况,提出了相应的动态测量扭矩的计算方程。实现了大型机械设备主传动的动力监测,为设备自动化、智能化奠定了基础。     

F-H实验仪与光栅光谱仪连用观测253.7nm谱线

通过F-H实验仪和光栅光谱仪的连用，可实时观测汞原子从6s6s1So态激发到6s6sSP1态，退激时，辐射出能量为4．9eV的光量子，其波长为253．7nm．     

摄像型等厚干涉实验仪器的研究

介绍了“摄像型等厚干涉实验仪”的构造及等厚干涉实验新的测量方法。     

多自由度测试技术的发展

介绍目前较常用的多种多自由度测试技术，给出每种测试技术的测试原理和应用场合，比较各种技术的优缺点和适用范围，讨论该技术发展的方向。     

Tensor Products of Quantum Structures and Their Applications in Quantum Measurements

Tensor products of quantum logics and effect algebras with some known problems are reviewed. It is noticed that although tensor products of effect algebras having at least one state exist, in the category of complex Hilbert space effect algebras similar problems as with tensor products of projection lattices occur. Nevertheless, if one of the two coupled physical systems is classical, tensor product exists and can be considered as a Boolean power. Some applications of tensor products (in the form of Boolean powers) to quantum measurements are reviewed.     

计算机画法几何的研究与应用

以AutoCAD2000i为图形支撑平台，构建一种计算机辅助画法几何方法以直观、精确、高效地求解三维空间几何度量与定位问题，该方法适合于传统画法几何求解，也可用于曲柄滑块机构的行程、运动轨迹等内容的设计。     

On‐line Determination of Particle Size Distributions in Flowing Dispersions

Emulsions are of great importance to industry. They are involved in many engineering operations, including chemical reactions, extraction, emulsification and suspension polymerization, etc. However, an important problem for these processes is how to control the size distribution of the dispersed phase. Indeed, off‐line analysis of the emulsion may generate uncertainties due to sampling and dilution of the product, which are likely to change the dispersion state and physico‐chemical properties. In this work, an on‐line optical method is proposed to characterize dispersed media in real flowing conditions. This method is based on the time‐analysis of back‐scattered light fluctuations. The present paper deals with the development of this method and its application to dispersions of alumina in water. The results obtained with the on‐line optical method are compared with those acquired by classical laser light scattering and microscopy.     

同轴双无衍射光的理论与实验

提出同轴双无衍射光的概念。如果两束汇聚角略有不同的同轴无衍射光同时存在，则它们相互之间叠加干涉后产生一种纵向呈周期变化的光场结构，这是一种新的光束空间分布，这种光束在横向仍是一种同心环光斑，可用于精密对准。而在不同纵向位置，这些同心环的强度分布是不同的，且是周期性变化的。同轴双无衍射光的轴向周期性可用于沿光束传播方向的定位。文中提出了双环缝法、分段圆锥透镜法、正弦相位环光栅法等实现同轴双无衍射光的理论与实验方法，分析了同轴双无衍射光的横向与纵向传播的衍射光斑特性，理论计算与实验测量的结果基本相符合。