全文获取类型
收费全文 | 96994篇 |
免费 | 6481篇 |
国内免费 | 5159篇 |
专业分类
化学 | 25192篇 |
晶体学 | 451篇 |
力学 | 6810篇 |
综合类 | 681篇 |
数学 | 9372篇 |
物理学 | 15380篇 |
综合类 | 50748篇 |
出版年
2024年 | 329篇 |
2023年 | 953篇 |
2022年 | 1944篇 |
2021年 | 2272篇 |
2020年 | 2207篇 |
2019年 | 2013篇 |
2018年 | 1850篇 |
2017年 | 2425篇 |
2016年 | 2977篇 |
2015年 | 3031篇 |
2014年 | 4778篇 |
2013年 | 5706篇 |
2012年 | 5955篇 |
2011年 | 5839篇 |
2010年 | 4654篇 |
2009年 | 5438篇 |
2008年 | 5322篇 |
2007年 | 6529篇 |
2006年 | 5557篇 |
2005年 | 5081篇 |
2004年 | 4582篇 |
2003年 | 3941篇 |
2002年 | 3205篇 |
2001年 | 2763篇 |
2000年 | 2491篇 |
1999年 | 2237篇 |
1998年 | 1936篇 |
1997年 | 1723篇 |
1996年 | 1558篇 |
1995年 | 1400篇 |
1994年 | 1351篇 |
1993年 | 1104篇 |
1992年 | 1011篇 |
1991年 | 870篇 |
1990年 | 825篇 |
1989年 | 641篇 |
1988年 | 618篇 |
1987年 | 416篇 |
1986年 | 262篇 |
1985年 | 205篇 |
1984年 | 133篇 |
1983年 | 64篇 |
1982年 | 107篇 |
1981年 | 56篇 |
1980年 | 49篇 |
1979年 | 79篇 |
1978年 | 36篇 |
1977年 | 14篇 |
1976年 | 26篇 |
1955年 | 12篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
A fundamental question in random matrix theory is to quantify the optimal rate of convergence to universal laws. We take up this problem for the Laguerre β ensemble, characterized by the Dyson parameter β, and the Laguerre weight , in the hard edge limit. The latter relates to the eigenvalues in the vicinity of the origin in the scaled variable . Previous work has established the corresponding functional form of various statistical quantities—for example, the distribution of the smallest eigenvalue, provided that . We show, using the theory of multidimensional hypergeometric functions based on Jack polynomials, that with the modified hard edge scaling , the rate of convergence to the limiting distribution is , which is optimal. In the case , general the explicit functional form of the distribution of the smallest eigenvalue at this order can be computed, as it can for and general . An iterative scheme is presented to numerically approximate the functional form for general . 相似文献
22.
23.
24.
《Journal of separation science》2018,41(10):2288-2295
New psychoactive substances represent serious social and health problem as tens of new compounds are detected in Europe annually. They often show structural proximity or even isomerism, which complicates their analysis. Two methods based on ultra high performance supercritical fluid chromatography and ultra high performance liquid chromatography with mass spectrometric detection were validated and compared. A simple dilute‐filter‐and‐shoot protocol utilizing propan‐2‐ol or methanol for supercritical fluid or liquid chromatography, respectively, was proposed to detect and quantify 15 cathinones and phenethylamines in human urine. Both methods offered fast separation (<3 min) and short total analysis time. Precision was well <15% with a few exceptions in liquid chromatography. Limits of detection in urine ranged from 0.01 to 2.3 ng/mL, except for cathinone (5 ng/mL) in supercritical fluid chromatography. Nevertheless, this technique distinguished all analytes including four pairs of isomers, while liquid chromatography was unable to resolve fluoromethcathinone regioisomers. Concerning matrix effects and recoveries, supercritical fluid chromatography produced more uniform results for different compounds and at different concentration levels. This work demonstrates the performance and reliability of supercritical fluid chromatography and corroborates its applicability as an alternative tool for analysis of new psychoactive substances in biological matrixes. 相似文献
25.
通过采用机器学习算法,提出了高温作用后砂岩物理力学性质变化的阈值温度的确定方法。基于Python语言,利用K-Means、SVM算法,实现了对样本数据的分类和聚类,确定了阈值温度区间,验证了二分类法的合理性和准确性.结果表明,砂岩样本的阈值温度区间为400~600 ℃,阈值温度上下砂岩的物理力学性质存在显著差异,体现为阈值温度区间以下的岩样物理力学性质较为分散,而阈值温度区间以上的岩样物理力学性质较为集中. 相似文献
26.
针对高离散精度模型与刀具包围体进行切削计算的情况,由于三维图像重建的计算量大,基于传统CPU实现的数控加工仿真系统不能满足实时性的三维绘制。本文利用GPU的并行性特点,提出并行方式数控仿真切削面显示算法:通过线程并行处理基于MC算法的实体构造模型中体素与刀具包围体的切削计算,根据切削后体素角点信息和边的状态查找建立的构型索引表和交点数目索引表,加速数控仿真切削面的提取,从而提高三维图像的绘制速度,满足实时性显示要求。 相似文献
27.
Effect of additive length and chemistry on the morphology of blends of conjugated thiophenes and fullerene derivative acceptor molecules
下载免费PDF全文
![点击此处可从《Journal of Polymer Science.Polymer Physics》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Small molecule additives have been shown to increase the device efficiency of conjugated polymer (donor) and fullerene derivative (acceptor) based organic solar cells by modifying the morphology of the device active layer. In this paper we conduct a systematic study of how additives affect the donor‐acceptor morphology using molecular dynamics simulations of blends of thiophene‐based oligomers, mimicking poly(3‐dodecylthiophene) (P3DDT) or poly(2,2′:5′,2”‐3,3”‐didocyl‐terthiophene) (PTTT), and fullerene derivatives with additives of varying length and chemical functionalization, mimicking experimentally used additives like methyl ester additives, diiodooctane, and alkanedithiols. We find that functionalization of additives with end groups that are attracted to acceptor molecules are necessary to induce increased donor‐acceptor macrophase separation. In blends where acceptors intercalate between oligomer alkyl side chains, functionalized additives decrease acceptor intercalation. Functionalized additives with shorter alkyl segments increase acceptor macrophase separation more than additives with same chemical functionalization but longer alkyl segments. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1046–1057 相似文献
28.
对高速电主轴温度场分布随转速的变化规律进行了研究。通过在外壳上布置一定数量的温度传感器,对不同转速下的外壳温度进行实时测量,并将实验结果与ANSYS的模拟结果进行对比,验证了采用在电主轴外壳上布置多个测点测量与仿真相结合的方法来预测电主轴内部温度场分布的可行性;另外还分析了在不同转速下,高速电主轴关键部位的温升,仿真结果表明:主轴在6000~10000 r/min时,温升呈线性增加,在大于10000 r/min后,温升以指数规律增加。 相似文献
29.
Riboflavin was covalently linked to mesoporous SBA-15 silica surface via grafting technique. Then fluorescence properties of the system obtained were analyzed in the presence of several metal and organic cations. Both quenching and strengthening of fluorescence as well as significant changes in the maximum fluorescence wavelength were observed. The results were compared with absorption and fluorescence data obtained for riboflavin water solutions. 相似文献
30.
Yuta Yamamoto Shogo Nakano Fumio Seki Yasuteru Shigeta Sohei Ito Hiroaki Tokiwa Makoto Takeda 《Molecules (Basel, Switzerland)》2021,26(5)
Infection of hosts by morbilliviruses is facilitated by the interaction between viral hemagglutinin (H-protein) and the signaling lymphocytic activation molecule (SLAM). Recently, the functional importance of the n-terminal region of human SLAM as a measles virus receptor was demonstrated. However, the functional roles of this region in the infection process by other morbilliviruses and host range determination remain unknown, partly because this region is highly flexible, which has hampered accurate structure determination of this region by X-ray crystallography. In this study, we analyzed the interaction between the H-protein from canine distemper virus (CDV-H) and SLAMs by a computational chemistry approach. Molecular dynamics simulations and fragment molecular orbital analysis demonstrated that the unique His28 in the N-terminal region of SLAM from Macaca is a key determinant that enables the formation of a stable interaction with CDV-H, providing a basis for CDV infection in Macaca. The computational chemistry approach presented should enable the determination of molecular interactions involving regions of proteins that are difficult to predict from crystal structures because of their high flexibility. 相似文献