谈工民建毕业设计中的一些问题

毕业设计是学生对所学基础知识和专业知识进行一次综合应用的体现。设计中常常出现错误．甚至全部设计麦政,非常值得引起师生的共同重视。     

任意实数圈涡旋压缩机的几何分析

通过对非整数圈涡旋压缩机进行几何分析,确定了涡旋压缩机的排气角及开始吸气角．给出了任意实数圈涡旋压缩机在吸气、压缩及排气各个不同阶段腔内容积的计算公式和压缩腔个数的计算公式,并应用这些公式推导了程序化计算任意实数圈涡旋盘所受轴向气体力和切向气体力的计算公式．     

暖通CAD信息流分析和公用数据库的研究

分析了暖通ＣＡＤ信息流的特点,提出了交互式,集成化,智能化暖通ＣＡＤ的开发构想,同时从暖通设计过程的信息流入手,开发了基于图形用户界面思想的公用数据库及其管理繁育 及基于谐波反应法的负荷计算软件。     

The first crystal structure of a Meisenheimer complex with organic cation

The structure of the Meisenheimer complex 2′,4′,6′-trinitro-3′,5′-dihydrospiro(1,3-dioxolane-2,8′-cyclohexadienide) C₈H₆N₃O₈(?) 1^? with tetra-n-butyl-ammonium C₁₆H₃₆ N(+) has been determined by X-ray crystallography. The compound 1 crystallizes in the space group P2₁ with two molecules (Z′ = 2) in the asymmetric unit. The unit cell parameters are a = 8.728(3) Å, b = 13.760(4) Å, c = 22.882(7) Å, β = 96.17(3)^°. Interactions between the Meisenheimer complex and organic cation in 1 involve only a number of weak to moderate C–H?sO bonds. Thus, it has been concluded that the structure 1 represents the geometry of the Meisenheimer complex minimally influenced by the cation. Comparison the structure 1 and the compound 2 (1^? K⁺?H₂O) studied previously reveals an interesting structural effect attributed to coordination of potassium cations with the nitro groups of 1^?. It leads to notable shortening of the C–N bond lengths of the nitro groups only, while changes of other bond lengths in the Meisenheimer complex are not significant.     

基于双目视觉技术的物体深度信息的提取

传统的双目匹配算法得到的数据是左右视图匹配点的二维坐标;但二维坐标将丢失物体的三维深度信息。提出一种利用视差原理在世界坐标系内计算该物点在现实中所对应点的三维坐标的新方法。该方法分为三部分:第一部分为双目相机的标定,包括内参(主点、焦距、径向畸变、不垂直因子)以及两相机之间的外参(旋转矩阵和平移矩阵)。第二部分为特征点的提取与匹配,特征点的提取则是利用SIFT算子提取左右视图的特征点,匹配则是将两视图中的对应点(现实中为同一点)利用SIFT算法进行匹配。第三部分为物体深度信息的计算,利用双目相机的视差原理和已经得出的双目相机的参数进行空间还原得到相应的左右视图投影投射矩阵,结合空间几何线性关系计算出该点在世界坐标系的三维坐标,从而得出其深度信息。     

垂直分层土壤模型下输电杆塔接地电阻的拟合算法

当前垂直分层土壤电性模型下输电线路杆塔接地电阻的精确计算方法过于复杂,不易为普通工程技术人员掌握.基于格林函数的精确算法,对垂直双层土壤电性模型下的典型输电杆塔接地装置的接地电阻值进行了求解.采用最小二乘曲线拟合方法,研究并选取双曲线函数作为拟合函数,对分层土壤电阻率及接地电阻值进行拟合,从而推导出拟合函数表达式,最终得到分层土壤模型下杆塔接地电阻拟合计算公式.对该算法的精度进行了分析,认为其精度与算法中的初值计算有关,但最大误差不超过10%.     

基于灵敏度阻抗矩阵修正法的分层前推回代潮流算法

分布式电源(DG)接入配电网对潮流产生重要影响.本文分析了潮流计算中各种分布式电源模型及处理方法,引入灵敏度阻抗矩阵修正法更新PV节点的注入无功功率,结合辐射型配电网的特点,提出一种基于灵敏度阻抗矩阵修正法的分层前推回代潮流算法.该算法解决了前推回代潮流算法处理PV节点失效的问题,同时适用于含各类分布式电源的潮流计算.最后对含各种类型分布式电源的IEEE 33节点配电网进行潮流计算仿真,仿真结果验证了提出算法的有效性和快速性,并通过不同算例验证了算法的稳定性.     

煤粉富氧燃烧锅炉改造的热力计算研究

以四种不同容量锅炉为研究对象,分析了空气气氛锅炉进行富氧燃烧改造的可行性,以及改造前后热力性能参数的变化情况.研究表明:在结构不改变的条件下,空气气氛锅炉可以通过调整循环倍率实现富氧燃烧,但是由于CO2的高热容,因此导致受热面吸热不均匀和烟气流速大幅度降低,影响整个锅炉的安全运行;有针对性地提高烟气流速和减小受热面面积可以达到实现富氧燃烧锅炉改造的目的.结果表明:锅炉经富氧燃烧改造后各参数达到与空气近似的热力性能,其容积热负荷和截面热负荷与空气气氛相比降低了0.7%~2.5%,烟气量降低20%左右,而锅炉热效率可增加0.42%~4.10%.     

基于云计算的智能交通信号灯控制系统设计与实现

本文阐述了基于云计算的交通信号灯控制系统设计与实现。通过地感线圈来检测车流量,GPRS进行交通量数据的实时数据上传,综合运用STM32F103芯片、云计算机技术等技术实时反馈交通流量、流向,即时调整信号灯配时,实现交通信号灯智能控制。     

Effect of ancillary ligands on the electronic structures, DNA-binding and spectral properties of [Co(L)2(pip)] (L = phen, bpy, en, tap)

Studies on the electronic structures and related properties of a series of Co(Ш) complexes have been carried out, using the density functional theory (DFT) at the B3LYP/LanL2DZ level. The effect of the ancillary ligands on their electronic structures, DNA-binding affinities and spectra was revealed. The results show that an ancillary ligand has quite important effect on electronic structures and DNA-binding properties of these Co(Ш) complexes. The ancillary ligand possessing a great conjugated structure can effectively improve the DNA-binding affinity of the complex. Meanwhile, introducing a stronger electronegative N atom on the skeleton of ancillary ligand can obviously reduce the LUMO energy of the complex. Based on these findings, a designed complex 4 can be expected to have the greatest K_b value in complexes 1–4. So it may be able to control the interaction between the complex and DNA-base-pairs via varying ancillary ligands. In addition, the electronic absorption spectra of these complexes were calculated and simulated in aqueous solution using the time-dependent DFT (TDDFT) method and the effect of the ancillary ligands on the spectra was also explored. The calculated absorption spectra of these complexes in aqueous solution are in a satisfying agreement with the experimental results, and the properties of experimental absorption bands were theoretically explained in detail.