硅酸盐熔体粘度理论计算模式的研究

对高温硅酸盐熔体粘度的估算一直是国际地学界热点问题之一。在研究高温硅酸盐熔体网络分数维值的基础上，建立了估算熔体粘度的新模式(简称FD模式)；阐明了熔体粘度值除了与温度成反比外，还与分子网络的分数维值D相关。即与分子网络(纳米尺度以上)中的桥氧数M成正比(Ni=ri^-D)、与单位硅氧四面体中的非桥氧数成反比。经对四个硅酸盐系列高温熔体的粘度测定证实，FD模式的理论计算值与实测值吻合，为探索岩浆迁移演化规律和完善新型低维材料的性能提供了新的理论依据。     

AlMnCa合金脱氧和非金属夹杂物控制技术

在1873K下,MoSi2电阻炉内用70mm×100mmMgO坩埚和AlMnCa合金开展了3炉低碳低硅钢脱氧实验.结果表明,用1#AlMnCa脱氧后,钢中溶解氧和全氧含量均较低,终点全氧质量分数为37×10-6.用AlMnCa脱氧后钢中夹杂物大部分为球形的含有CaO的复合夹杂物.用AlMnFe脱氧后,钢中主要是Al2O3或Al2O3-MnO等构成的复合夹杂物,其形状仅有少量为球形.实验终点钢中89.1%的夹杂物尺寸小于10μm,无大于50μm的夹杂物.用1#AlMnCa在25t转炉上进行了6炉TGD07钢脱氧工业试验,脱氧后钢中氧质量分数平均为23.8×10-6,最低达到8×10-6.与未用...     

一类新的集值非线性变分包含问题解的存在性及其算法

在Hilbert空间中利用与H-单调映象相联系的预解算子的性质,讨论了一类新的集值非线性变分包含问题解的存在性,并给出了逼近解的迭代算法．     

Pullback Attractors of Nonautonomous and Stochastic Multivalued Dynamical Systems

In this paper we study the existence of pullback global attractors for multivalued processes generated by differential inclusions. First, we define multivalued dynamical processes, prove abstract results on the existence of -limit sets and global attractors, and study their topological properties (compactness, connectedness). Further, we apply the abstract results to nonautonomous differential inclusions of the reaction–diffusion type in which the forcing term can grow polynomially in time, and to stochastic differential inclusions as well.     

Supramolecular Control of Ester Hydrolysis in Poly(ethylene glycol)‐Interlocked Hydrogels

Poly(ethylene glycol) (PEG)‐interlocked hydrogels were prepared by linking the PEG with α‐cyclodextrins (α‐CDs) threaded onto a PEG chain having ester linkages at the terminals (hydrolyzable polyrotaxane). These hydrogels were examined to clarify the effect of ionic strength of phosphate buffers, pH, and the addition of ethanol on erosion time in relation to inclusion states of α‐CDs with the ester linkages. The most characteristic phenomenon of the hydrogel erosion was observed in an ethanol/PBS cosolvent system: the time to reach the complete erosion time was shortened with decreasing water content. NMR analysis revealed that the ester linkages were exposed to the aqueous environment due to the aggregation of α‐CDs. These results suggest that the movement of α‐CDs in the polyrotaxanes from the terminal ester region to the another region gives the ester linkages a chance to interact with water.

     

Unusual regioselective acylation of the primary hydroxy groups of β-cyclodextrin

The reaction of -cyclodextrin (1) with palmitoyl (2) and valeryl (4) chlorides in DMF or Py, unlike previously studied acetylation of 1, involves only the primary hydroxy groups of 1. The outcome of the reaction depends on the reaction conditions and the nature of the acid scavenger used (Et₃N, Prⁱ ₂NEt, PhNMe₂, Py). ¹³C NMR spectroscopy was shown to be an effective tool in determining the number and position of aliphatic carboxylic acid residues introduced into 1. A hypothesis stating that preliminary formation of a reactive inclusion complex (acid chloride1) is required for the acylation of 1 to occur is proposed and substantiated. This hypothesis provides a unified explanation for a variety of unusual facts observed in the acylation of 1 and its derivatives.     

Eclogites and their country gneisses: Studies on inclusions in the accessory minerals of country gneisses

The mineral inclusions in accessory minerals of the country gneisses have been studied in order to interpret relation between eclogites and their country gneissic rocks. Omphacite inclusions have been identified in titanite and zircon, which indicates that the present mineral assemblages of country gneisses are the last retrograded assemblages and eclogites and their country gneissic rocks probably have a same metamorphic history.     

集值映象迭合度及对微分包含的应用

应用集值映象的Ｌｅｒａｙ－Ｓｃｈａｕｄｅｒ度建立了集值映象的迭合度。作为应用,讨论了一类微分包含ｍ－点边值问题的可解性,这是对Ｇｕｐｔａ等人工作的完善和发展