全文获取类型
收费全文 | 8908篇 |
免费 | 1604篇 |
国内免费 | 928篇 |
专业分类
化学 | 6523篇 |
晶体学 | 47篇 |
力学 | 94篇 |
综合类 | 41篇 |
数学 | 339篇 |
物理学 | 2418篇 |
综合类 | 1978篇 |
出版年
2024年 | 26篇 |
2023年 | 124篇 |
2022年 | 218篇 |
2021年 | 264篇 |
2020年 | 410篇 |
2019年 | 336篇 |
2018年 | 327篇 |
2017年 | 279篇 |
2016年 | 441篇 |
2015年 | 453篇 |
2014年 | 616篇 |
2013年 | 755篇 |
2012年 | 552篇 |
2011年 | 550篇 |
2010年 | 488篇 |
2009年 | 521篇 |
2008年 | 565篇 |
2007年 | 544篇 |
2006年 | 486篇 |
2005年 | 424篇 |
2004年 | 413篇 |
2003年 | 352篇 |
2002年 | 279篇 |
2001年 | 222篇 |
2000年 | 251篇 |
1999年 | 209篇 |
1998年 | 184篇 |
1997年 | 168篇 |
1996年 | 156篇 |
1995年 | 144篇 |
1994年 | 94篇 |
1993年 | 89篇 |
1992年 | 95篇 |
1991年 | 86篇 |
1990年 | 55篇 |
1989年 | 70篇 |
1988年 | 51篇 |
1987年 | 33篇 |
1986年 | 20篇 |
1985年 | 24篇 |
1984年 | 20篇 |
1983年 | 11篇 |
1982年 | 8篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1975年 | 3篇 |
1974年 | 4篇 |
1973年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
991.
从平面波的角谱表示出发,得到了超短脉冲光束由分层介质表面反射的频谱特性,数值计算给出了飞秒高斯脉冲经自由空间中介质薄膜反射的远场谱分布.由于光与介质的相互作用,反射谱呈现谱线变窄、红移、蓝移以及出现旁瓣而分裂成多重谱线的现象. 相似文献
992.
用 R T P C R技术从 C S F V H C L V 株 F482 代感染兔脾的细胞总 R N A 中分段扩增出了 C S F V E2 基因特异的3 个部分重叠的 D N A 片段(大小分别为 499 bp、572 bp 和 245 bp),并将之分别克隆到p G E M T 载体上 经核苷酸序列测定和片段重叠完成了包含 E2 全长基因的 1 144 bp 序列的测定,其 G C含量为49.0% :核苷酸序列与国外报道的各株病毒的 E2 基因同源性分别为83.5% ~97.5% ;其推导的氨基酸序列的同源性也分别为89.3%~96.2% ,变异主要分布在 E2 蛋白的 N 半部分 相似文献
993.
Antonia Mielgo Dr. Irene Velilla Claudio Palomo Prof. Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(25):7496-7502
In the presence of p‐nitrobenzoic acid, the O‐nitroso aldol reaction of nitrosobenzene with enolisable aldehydes may be promoted by commercially available α,α‐diphenylprolinol trimethylsilyl ether. The reaction proceeds with good yields and essentially complete enantioselectivity, with catalyst loadings in the 5–10 mol % range. The resulting α‐oxyaldehyde adducts may be transformed in situ into α‐oxyimines, which provide 1,2‐amino alcohols upon treatment with Grignard reagents, in good overall yield (45–59 %) and with typical diastereomeric ratios ≥95:5. 相似文献
994.
《Physics and Chemistry of Liquids》2012,50(6):712-734
Excess molar volumes and viscosity deviations in N,N-dimethylacetamide?+?dimethylformamide binary mixtures at 298.15, 308.15 and 318.15?K were calculated from experimental density and viscosity data presented in the previous work. Here these experimental values were used to test the applicability of the correlative reduced Redlich–Kister equation and the recently proposed Herráez equation. Their correlation ability at different temperatures, and the use of different number of parameters, is discussed for the case of limited experimental data. These relative functions are important to reduce the effect of temperature and, consequently, to reveal the effects of different types of interactions. Limiting excess partial molar volumes at infinite dilution were deduced from different methods, parameters of molar Gibbs energy of activation of viscous flow against compositions were investigated. The results of these observations have been interpreted in terms of structural effects of the solvents. 1H-NMR studies of these mixtures are also reported. 相似文献
995.
A number of novel acid-sensitive Schiff bases derived from p-aminobenzyl alcohol and various benzaldehyde derivatives were synthesized and were subsequently shown to trigger benzyl elimination reactions. The kinetics of acid-catalyzed hydrolysis at pH 5.0 as well as stability at pH 7.4 were studied using fluorogenic model compounds. Two fluoro-substituted Schiff bases showed efficient hydrolysis at pH 5.0 combined with a long-term stability at pH 7.4 and are considered suitable candidates for the development of anticancer prodrugs. 相似文献
996.
997.
摘要. 设 E 是满足强分离条件的迭代函数系统 的吸引子, 定义连续映射
设 是一个概率向量, 是对应的不变测度. 本文研究了上述映射,得到如下结果: (1) 对映射 , 存在一个有限混沌集 , 满足 ; (2) 映射 存在Li-Yorke意义下混沌的极小子系统, 该子系统具有零拓扑熵, 从而推广了一些已知的结果. 相似文献
998.
Apparent correlations are found between the N-H chemical shifts of congeneric series of compounds and the dipole moments of the molecules, such as lactams and thiolactams, cyclic ureas and thioureas. When there is a high degree of correlation, either the N-H chemical shift or the dipole moment of the molecule can be used as an electronic parameter in correlating the biological activity with the chemical structure. In a series of substituted salicylaldehydes the Hammett σ constant gives better correlation with the biological activity than the O-H chemical shift. This is probably due to the anisotropic effect of the substituent besides the electronic effect. Other factors affecting the N-H chemical shift, e.g. intramolecular hydrogen-bonding of nitrosoureas and the deshielding effect of a benzene ring, in o-phenyleneureas are also presented. In spite of the limitations, the chemical shifts of many compounds can be obtained very easily, therefore, their uses in structure-activity correlations deserve further investigation. 相似文献
999.
1000.