Immiscibility,upper critical solution temperature,and miscibility in blends of poly(vinyl ether)s with polyacrylics: Effects of pendant groups

Various phase behavior of blends of poly(vinyl ether)s with homologous acrylic polymers (polymethacrylates or polyacrylates) were examined using differential scanning calorimetry, optical microscopy (OM), and Fourier‐transformed infrared spectroscopy. Effects of varying the pendant groups of either of constituent polymers on the phase behavior of the blends were analyzed. A series of interestingly different phase behavior in the blends has been revealed in that as the pendant group in the acrylic polymer series gets longer, polymethacrylate/poly(vinyl methyl ether) (PVME) blends exhibit immiscibility, upper critical solution temperature (UCST), and miscibility, respectively. This study found that the true phase behavior of poly(propyl methacrylate)/PVME [and poly(isopropyl methacrylate)/PVME)] blend systems, though immiscible at ambient, actually displayed a rare UCST upon heating to higher temperatures. Similarly, as the methyl pendant group in PVE is lengthened to ethyl (i.e., PVME replaced by PVEE), phase behavior of its blends with series of polymethacrylates or polyacrylates changes correspondingly. Analyses and quantitative comparisons on four series of blends of PVE/acrylic polymer were performed to thoroughly understand the effects of pendant groups in either polyethers (PVE's) or acrylic polymers on the phase behavior of the blends of these two constituents. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1521–1534, 2007     

经部科技文献述要

中国古代留下了大量的典籍，其中保存了极为丰富的科技史料．这里介绍了经部类著作的源流及类型，着重归纳分析了《周易》、《尚书》和《诗经》中的科技史料及其价值．     

丁香矮化的技术研究

采取不同的试验方法,明确适宜盆栽的丁香品种为蓝丁香、什锦丁香和紫叶重瓣丁香,通过研究确定丁香盆栽矮化的技术要点,同时对盆栽矮化的进一步研究提出建议。     

Cationic poly(methacryl oxyethyl trimethylammonium) and its poly(ethylene glycol)‐grafted analogue as capillary coating materials in electrophoresis

Cationic polyelectrolytes were synthesized and used as semipermanent coating materials for capillaries in electrophoresis. The polyelectrolytes used were a homopolymer of poly(methacryl oxyethyl trimethylammonium chloride) (PMOTAC) and its poly(ethylene glycol) (PEG)‐grafted analogue. Two PMOTAC polyelectrolytes, with molar masses of 85,000 and 300,000 g/mol, and PEG‐grafted PMOTAC with a molar mass of 280,000 g/mol were synthesized and then characterized by size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR) spectroscopy. Attachment of the polyelectrolytes to the wall of the fused silica capillary for electrophoresis caused the electroosmotic flow (EOF) to reverse. The polyelectrolyte coatings were tested over the pH range 2–11 at different buffer ionic strengths, and the most stable and strongest anodic EOFs were obtained at acidic pH values with low ionic strength buffers. Between runs the capillary is merely rinsed for 2 or 3 min with the background electrolyte solution. With the PMOTAC coatings at pH values ≤5, the RSDs of the EOFs were less than 2.9% after 60 injections. The effects of the molar mass of the polycation and of PEGylation of PMOTAC on the interactions between the polycations and basic proteins were studied at acidic pH values. The differences in the effective electrophoretic mobilities, resolution values, and plate numbers of the proteins with the different coatings were due to the EOF, as demonstrated through calculations of reduced mobilities, relative resolution values, and relative plate numbers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2655–2663, 2007     

神经网络在成组技术方面的应用

阐述了成组技术及其在高级制造技术中的作用，在此基础上描述了神经网络在零件编码分类系统中的应用以及用神经网络设计制造单元的方法。     

提高学生科技能力,培养信息技术创新人才

培养计算机与电子信息技术的创新人才是信息产业发展的需要．本文介绍我们在培养学生的创新精神 和科技能力,提高学生分析问题和实际解决问题能力等方面的一些思考和具体的做法．     

AECT教育技术2004新定义的理解与启示

美国教育传播与技术协会(AECT)在2004年6月1日的文件中发表了关于教育技术的新定义.通过对AECT2004新定义的理解,以期能对我国的教育技术理论和实践有所启发.     

低频声波定向技术研究

应用声呐基阵的设计理论，设计了一种圆柱形组合脉动球源阵。对此声源阵低频声波声场的远场进行了理论分析与仿真研究，表明此声源阵对低频声波具有指向性，通过调整此组合声源阵的结构，可改善对低频声波的指向性。     

赛博空间技术及其在虚拟旅游规划中的应用前景初探

结合赛博空间技术的发展和旅游规划的现状，提出和讨论了虚拟旅游规划的概念。并对赛博空间技术在虚拟旅游规划中的应用前景作了进一步的思考。     

流媒体技术在继续教育平台中的应用

在阐述了流媒体技术的基本原理的基础上，通过对主流技术的分析比较提出了以WindowsMedia为技术支撑，基于组播和点播的流媒体继续教育平台解决方案，并对资源的同步控制和安全策略作简要分析，实现一个功能丰富的继续教育平台．